Abstract
The Fe–B amorphous nano-particle with reduced graphene oxide (FeB@RGO) has been successfully prepared as a novel absorbing material of light-weight broadband electromagnetic wave (EW). This paper studied the influence of the thickness of the sample and the paraffin amount on absorption properties of the composite to EW. According to the research results, the absorption peak occurred in a low frequency region as the thickness increased, and only 5 wt% FeB@RGO added to the paraffin 2.2 mm thick has the optimal EW absorption property. Compared to Fe–B particles and RGO, the FeB@RGO as EW absorbing materials have better absorbing properties with higher reflectivity (− 49.13 dB), wider bandwidth (6.64 GHz) and smaller addition concentration (5 wt%), which is more suitable as an efficient and light-weight EW absorber.
Similar content being viewed by others
References
C.C. Wang, Y. Jiao, T.G. Qiang, J. Li, Cellulose-derived carbon aerogels supported goethite (α-FeOOH) nanoneedles and nanoflowers for electromagnetic interference shielding. Carbohydr. Polym. 156, 427–434 (2017)
D. Micheli, A. Vricella, R. Pastore, M. Marchetti, Synthesis and electromagnetic characterization of frequency selective radar absorbing materials using carbon nanopowders. Carbon 77, 756–774 (2014)
R.W. Shu, H.L. Xing, X.L. Ji, D.X. Tan, Y. Gan, Preparation, microwave absorption and infrared emissivity of Ni-doped ZnO/Al powders by coprecipitation method in the GHz range. Nano 11(4), 1650047 (2016)
L. Kong, X.W. Yin, X.Y. Yuan, Y.J. Zhang, X.M. Liu, L.F. Cheng, L.T. Zhang, Electromagnetic wave absorption properties of graphene modified with carbon nanotube/poly(dimethyl siloxane) composites. Carbon 73, 185–193 (2014)
S.C. Chiu, H.C. Yu, Y.Y. Li, High electromagnetic wave absorption performance of silicon carbide nanowires in the GHz range. J. Phys. Chem. C 114(4), 1947–1952 (2010)
G. Li, T.S. Xie, S.L. Yang, J.H. Jin, J.M. Jiang, Microwave absorption enhancement of porous carbon fibers compared with carbon nanofibers. J. Phys. Chem. C 116(16), 9196–9201 (2012)
Y.B. Li, R. Yi, A.G. Yan, L.W. Deng, K.C. Zhou, X.H. Liu, Facile synthesis and properties of ZnFe2O4 and ZnFe2O4/polypyrrole core-shell nanoparticles. Solid State Sci. 11(8), 1319–1324 (2009)
W.Y. Fu, S.K. Liu, W.H. Fan, H.B. Yang, X.F. Pang, J. Xu, G.T. Zou, Hollow glass microspheres coated with CoFe2O4 and its microwave absorption property. J. Magn. Magn. Mater. 316(1), 54–58 (2007)
X.A. Li, B. Zhang, C.H. Ju, X.J. Han, Y.C. Du, P. Xu, Morphology-controlled synthesis and electromagnetic properties of porous Fe3O4 nanostructures from iron alkoxide precursors. J. Phys. Chem. C 115(25), 12350–12357 (2011)
S.S. Kim, S.T. Kim, J.M. Ahn, K.H. Kim, Magnetic and microwave absorbing properties of Co-Fe thin films plated on hollow ceramic microspheres of low density. J. Magn. Magn. Mater. 271(1), 39–45 (2004)
Y.N. Jiang, Y. Wang, D.B. Ge, S.M. Li, W.P. Cao, X. Gao, X.H. Yu, An ultra-wideband absorber based on graphene. Acta Phys. Sin. 65(5), 054101 (2016)
W. Li, T.L. Wu, W. Wang, J.G. Guan, P.C. Zhai, Integrating non-planar metamaterials with magnetic absorbing materials to yield ultra-broadband microwave hybrid absorbers. Appl. Phys. Lett. 104(2), 022903 (2014)
P. Liu, Y. Huang, X. Sun, Excellent electromagnetic absorption properties of poly(3,4-ethylenedioxythiophene)-reduced graphene oxide-Co3O4 composites prepared by a hydrothermal method. ACS Appl. Mater. Interfaces 5(23), 12355–12360 (2013)
X.L. Li, X.R. Wang, L. Zhang, S.W. Lee, H.J. Dai, Chemically derived, ultrasmooth graphene nanoribbon semiconductors. Science 319(5867), 1229–1232 (2008)
K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric field effect in atomically thin carbon films. Science 306(5696), 666–669 (2004)
Y.B. Zhang, Y.W. Tan, H.L. Stormer, P. Kim, Experimental observation of the quantum Hall effect and Berry’s phase in graphene. Nature 438(7065), 201–204 (2005)
S.Y. Huang, B. Zhao, K. Zhang, M.M.F. Yuen, J.B. Xu, X.Z. Fu, R. Sun, C.P. Wong, Enhanced reduction of graphene oxide on recyclable Cu foils to fabricate graphene films with superior thermal conductivity. Sci. Rep. 5, 14260 (2015)
F. Wu, A.M. Xie, M.X. Sun, Y. Wang, M.Y. Wang, Reduced graphene oxide (RGO) modified spongelike polypyrrole (PPy) aerogel for excellent electromagnetic absorption. J. Mater. Chem. A 3(27), 14358–14369 (2015)
Y. Wang, H.T. Guan, C.J. Dong, X.C. Xiao, S.F. Du, Y.D. Wang, Reduced graphene oxide (RGO)/Mn3O4 nanocomposites for dielectric loss properties and electromagnetic interference shielding effectiveness at high frequency. Ceram. Int. 42(1A), 936–942 (2016)
Y. Ding, L. Zhang, Q.L. Liao, G.J. Zhang, S. Liu, Y. Zhang, Electromagnetic wave absorption in reduced graphene oxide functionalized with Fe3O4/Fe nanorings. Nano Res. 9(7), 2018–2025 (2016)
Y. Ding, Z. Zhang, B.H. Luo, Q.L. Liao, S. Liu, Y.C. Liu, Y. Zhang, Investigation on the broadband electromagnetic wave absorption properties and mechanism of Co3O4-nanosheets/reduced-graphene-oxide composite. Nano Res. 10(3), 980–990 (2017)
Y. Ding, Q.L. Liao, S. Liu, H.J. Guo, Y.H. Sun, G.J. Zhang, Y. Zhang, Reduced graphene oxide functionalized with cobalt ferrite nanocomposites for enhanced efficient and lightweight electromagnetic wave absorption. Sci. Rep. 6, 32381 (2016)
G.Y. Lee, S.K. Kwon, J.S. Lee, Annealing effect on microstructure and magnetic properties of flake-shaped agglomerates of Ni-20 wt%Fe nanopowder. J. Alloys Compd. 613, 164–169 (2014)
P.P. Yang, Y. Liu, X.C. Zhao, J.W. Cheng, H. Li, Electromagnetic wave absorption properties of FeCoNiCrAl0.8 high entropy alloy powders and its amorphous structure prepared by high-energy ball milling. J. Mater. Res. 31(16), 2398–2406 (2016)
P.P. Yang, Y. Liu, X.C. Zhao, J.W. Cheng, H. Li, Electromagnetic wave absorption properties of mechanically alloyed FeCoNiCrAl high entropy alloy powders. Adv. Powder Technol. 27(4), 1128–1133 (2016)
S.L. Guo, L.D. Wang, H.J. Wu, Facile synthesis and enhanced electromagnetic wave absorption of thorny-like Fe-Ni alloy/ordered mesoporous carbon composite. Adv. Powder Technol. 26(4), 1250–1255 (2015)
J. Xiang, J.L. Li, X.H. Zhang, Q. Ye, J.H. Xu, X.Q. Shen, Magnetic carbon nanofibers containing uniformly dispersed Fe/Co/Ni nanoparticles as stable and high-performance electromagnetic wave absorbers. J. Mater. Res. A 2(40), 16905–16914 (2014)
X. Zhong, J.W. Cheng, Y. Liu, X.C. Zhao, Effect of annealing temperature on structure, magnetic and microwave absorption properties of Fe–B submicrometer particles. J. Mater. Res. 31(22), 3619–3628 (2016)
D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z.Z. Sun, A. Slesarev, L.B. Almant, W. Lu, J.M. Tour, Improved synthesis of graphene oxide. ACS Nano. 4(8), 4806–4814 (2010)
N. Zhang, Y. Huang, M. Wang, 3D ferromagnetic graphene nanocomposites with ZnO nanorods and Fe3O4 nanoparticles co-decorated for efficient electromagnetic wave absorption. Composites B. 136, 135–1429 (2018)
J. Li et al., Flexible electromagnetic wave absorbing composite based on 3D rGO-CNT-Fe3O4 ternary films. Carbon 129, 76–84 (2018)
D.F. Liang, M.G. Han, B. Yan, L.J. Deng, Effect of annealing treatments on the microwave electromagnetic properties of amorphous FeCuNbSiB microwires. Chin Phys. 16(2), 542–547 (2007)
R.L. Ji, C.B. Cao, Z. Chen, H.Z. Zhai, J. Bai, Solvothermal synthesis of CoxFe3–xO4 spheres and their microwave absorption properties. J. Mater. Chem. C 2(29), 5944–5953 (2014)
B. Lu, H. Huang, X.L. Dong, X.F. Zhang, J.P. Lei, J.P. Sun, C. Dong, Influence of alloy components on electromagnetic characteristics of core/shell-type Fe–Ni nanoparticles. J. Appl. Phys. 104(11), 114313 (2008)
H.J. Wu, L.D. Wang, Y.M. Wang, S.L. Guo, H. Wu, Flower-like alpha-Fe2O3/ordered mesoporous carbon nanocomposite and its enhanced microwave absorption property. Mater. Res. Innov. 18(4), 273–279 (2014)
X.A. Li, M.J. Li, H.Y. Wang, One-pot synthesis of FeCo alloy and iron borate composite nanorods with excellent electromagnetic wave absorption properties. RSC Adv. 6(111), 109346–109353 (2016)
M.K. Han, X.W. Yin, L. Kong, M. Li, W.Y. Duan, L.T. Zhang, L.F. Cheng, Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties. J. Mater. Chem. A 2(39), 16403–16409 (2014)
P.B. Liu, Y. Huang, L. Wang, M. Zong, W. Zhang, Hydrothermal synthesis of reduced graphene oxide–Co3O4 composites and the excellent microwave electromagnetic properties. Mater. Lett. 107, 166–169 (2013)
M. Zong, Y. Huang, H.W. Wu, Y. Zhao, Q.F. Wang, X. Sun, One-pot hydrothermal synthesis of RGO/CoFe2O4 composite and its excellent microwave absorption properties. Mater. Lett. 114, 52–55 (2014)
T. Chen, J.H. Qiu, K.J. Zhu, Y.C. Che, Y. Zhang, J.M. Zhang, H. Lim, F. Wang, Z.Z. Wang, Enhanced electromagnetic wave absorption properties of polyaniline-coated Fe3O4/reduced graphene oxide nanocomposites. J. Mater. Sci. Mater. Electron. 25(9), 3664–3673 (2014)
Y.N. Li, T. Wu, K.T. Jin, Y. Qian, N.X. Qian, K.D. Jiang, W.H. Wu, G.X. Tong, Controllable synthesis and enhanced microwave absorbing properties of Fe3O4/NiFe2O4/Ni heterostructure porous rods. Appl. Surf. Sci. 387, 190–201 (2016)
W. Feng, Y.M. Wang, J.C. Chen, L. Wang, L.X. Guo, J.H. Ouyang, D.C. Jia, Y. Zhou, Reduced graphene oxide decorated with in-situ growing ZnO nanocrystals: facile synthesis and enhanced microwave absorption properties. Carbon 108, 52–60 (2016)
P.B. Liu, Y. Huang, J. Yan, Y.W. Yang, Y. Zhao, Construction of CuS nanoflakes vertically aligned on magnetically decorated graphene and their enhanced microwave absorption properties. ACS Appl. Mater. Interfaces 8(8), 5536–5546 (2016)
H.L. Yu, T.S. Wang, B. Wen, M.M. Lu, Z. Xu, C.L. Zhu, Y.J. Chen, X.Y. Xue, C.W. Sun, M.S. Cao, Graphene/polyaniline nanorod arrays: synthesis and excellent electromagnetic absorption properties. J. Mater. Chem. 22(40), 21679 (2012)
M.K. Han, X.W. Yin, L. Kong, M. Li, W.Y. Duan, L.T. Zhang, L.F. Cheng, Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties. J. Mater. Chem. A 2, 16403 (2014)
Acknowledgements
The authors express gratitude to the support received from China Aerospace Science and Technology Innovation Fund.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wen, G., Zhao, X., Liu, Y. et al. Influence of Fe–B addition on electromagnetic wave absorption properties of RGO composite. J Mater Sci: Mater Electron 29, 10044–10053 (2018). https://doi.org/10.1007/s10854-018-9048-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-018-9048-6