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Three-dimensional graphene network supported by poly phenylene sulfide with negative permittivity at radio-frequency

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Abstract

Percolative composites with negative permittivity can be promising candidates for metamaterials, but there is still a need about efficient method to adjust the permittivity value. Here graphene/poly phenylene sulfide composites were prepared and the dielectric property was studied. By gradually increasing the graphene content, three-dimensional conductive network could be constructed, accompanied by a change in the conductive mechanism from hopping conduction to metal-like conduction. Negative permittivity was achieved, and the Drude model indicated that negative permittivity came from the plasma oscillation in graphene network. The equivalent circuit analysis demonstrated that interconnection of graphene was the most crucial factor to adjust the negative permittivity value. That is, negative permittivity value can be effectively adjusted by graphene content. These findings may pave a way to simply and efficiently control negative permittivity and imply promising applications in modern electrical and electronic industries.

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Acknowledgements

The authors acknowledge the support of the National Natural Science Foundation of China [Grant Nos. 51803119, 51871146 and U1832136].

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Authors and Affiliations

  1. School of Materials Science and Engineering, Hefei University of Technology, Hefei, 230002, China

    Dongxiao Han & Jiehua Liu

  2. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan, 250061, China

    Peitao Xie, Guohua Fan, Min Chen, Kai Sun & Zidong Zhang

Authors
  1. Dongxiao Han
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  2. Peitao Xie
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  3. Guohua Fan
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  4. Min Chen
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  5. Kai Sun
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  6. Zidong Zhang
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  7. Jiehua Liu
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Correspondence to Peitao Xie, Zidong Zhang or Jiehua Liu.

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Han, D., Xie, P., Fan, G. et al. Three-dimensional graphene network supported by poly phenylene sulfide with negative permittivity at radio-frequency. J Mater Sci: Mater Electron 29, 20768–20774 (2018). https://doi.org/10.1007/s10854-018-0218-3

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  • DOI: https://doi.org/10.1007/s10854-018-0218-3

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