Journal of Materials Science: Materials in Electronics

, Volume 29, Issue 24, pp 20595–20602 | Cite as

Magnetism in BiFe1−xNixO3: studied through electron spin resonance spectroscopy

  • M. R. Biswal
  • J. NandaEmail author
  • N. C. Mishra
  • S. S. Acharya
  • D. K. Mishra
  • V. V. Srinivasu


The effect of Ni doping in BiFe1−xNixO3 (BFNO) multiferroics are studied by X-ray diffraction (XRD), Fourier transmission infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), hysteresis loop (M–H), temperature dependent magnetization (FC-ZFC) measurements and electron spin resonance (ESR) techniques. The XRD and FTIR studies indicate that the BFNO compounds remain in rhombohedral (R3c) phase without appearance of any structural transformation due to Ni doping. The XPS studies show the oxidation states of Fe ions as 3+, whereas Bi is found to be in a mixed valence state of 2+ and 3+ in BFNO. The Ni ion doping enhances the saturation magnetization from 0.179 emu/g (x = 0.025) to 2.38 emu/g (x = 0.20), which is higher than the reported values found in literature. The FC-ZFC magnetization studies suggest the presence of a magnetic phase transition from a weak ferromagnetic to a spin glass state at low temperature. The ESR studies confirm the ferromagnetic state of BFNO samples.


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • M. R. Biswal
    • 1
  • J. Nanda
    • 2
    Email author
  • N. C. Mishra
    • 3
  • S. S. Acharya
    • 4
  • D. K. Mishra
    • 2
  • V. V. Srinivasu
    • 5
  1. 1.Department of PhysicsHi-Tech Engineering CollegeBhubaneswarIndia
  2. 2.Department of Physics, Faculty of Engineering and Technology (ITER)Siksha ‘O’ Anusandhan (Deemed to be University)BhubaneswarIndia
  3. 3.Department of PhysicsUtkal UniversityBhubaneswarIndia
  4. 4.Institute of PhysicsSachivalaya MargBhubaneswarIndia
  5. 5.Department of Physics, College of Science, Engineering and TechnologyUniversity of South AfricaJohannesburgSouth Africa

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