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Synthesis and characterization of Fe2O3/Mn2O3/FeMn2O4 nano composite alloy coated glass for photo-catalytic degradation of Reactive Blue 222

  • Mohammad Hossein Habibi
  • Vala Mosavi
Article

Abstract

Fe2O3/Mn2O3/FeMn2O4 nano-composite coated glass was synthesised by a one step method and applied for the photo-catalytic degradation of Reactive Blue 222 as a diazo textile dye from aquatic environment. The product was characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDX), and UV–Vis diffuse reflectance spectroscopy (UV–Vis DRS). XRD pattern confirmed the spinel structure of FeMn2O4 and bixbyite structure for (Mn,Fe)2O3. FESEM results showed an average size of the Fe2O3/Mn2O3/FeMn2O4 nano-composite at about 15 nm. UV–Vis DRS spectrum showed absorptions between 392–495 nm with strong absorption at visible region of solar light. The band gap energy of nano-composite was about 3.1 eV. The photcatalytic activity of Fe2O3/Mn2O3/FeMn2O4 nano-composite coated glass were best described by a pseudo first order model and showed an excellect activity in degradation of Reactive Blue 222 with 82% efficiency and 78% TOC removal. The results showed that Fe2O3/Mn2O3/FeMn2O4 nano-composite coated glass is a promising low cost photo-catalyst for the mineralization of Reactive Blue 222 as a diazo textile dye from aquatic environment.

Keywords

Photocatalytic Activity Manganese Oxide Selective Catalytic Reduction Field Emission Scanning Electron Microscopy Image Composite Alloy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

The authors wish to thank the University of Isfahan for financial support of this work.

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.Nanotechnology Laboratory, Department of ChemistryUniversity of IsfahanIsfahanIslamic Republic of Iran

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