Abstract
In this study, biopolymer nanocomposites of cellulose acetate (CA) and Al2O3 nanoparticles (Al2O3 NPs) were successfully obtained using solution blending method. The effect of Al2O3 NPs loading on the microstructure, morphology, thermal and dielectric properties of CA/Al2O3 nanocomposites was investigated using FTIR, XRD, TGA, optical microscopy, SEM, AFM and impedance spectroscopy technique. The FTIR results infer good interaction between CA and Al2O3 NPs. The XRD and microscopic studies demonstrated that Al2O3 nanoparticles were homogeneously dispersed in the CA matrix. The TGA results indicate that the onset degradation temperature of CA/Al2O3 nanocomposites is shifted towards higher temperature in the presence of Al2O3 NPs. The contact angle measurements infer reduction in the wettability of CA matrix with increasing Al2O3 NPs loading. On the other hand, the dielectric properties of CA were improved due to an incorporation of Al2O3 NPs. The dielectric constant increases from 8.63 (50 Hz, 30 °C) for neat CA matrix to 27.57 (50 Hz, 30 °C) for CA/Al2O3 nanocomposites with 25 wt% Al2O3 loading. Similarly, the dielectric loss also increases from 0.26 (50 Hz, 30 °C) for neat CA matrix to 0.64 (50 Hz, 30 °C) for CA/Al2O3 nanocomposites with 25 wt% Al2O3 NPs loading. However, very low values of tan δ (below 1) were observed for all the samples. These results suggest that CA/Al2O3 nanocomposites with improved dielectric properties seem to be a promising candidate for designing electronic devices such as embedded passives.
Similar content being viewed by others
References
P.A. Wilbon, F. Chu, C. Tang, Macromol. Rapid Commun. 34, 8–37 (2013)
C.K. Williams, M.A. Hillmyer, Polym. Rev. 48, 1–10 (2008)
K.M. Nampoothiri, N.R. Nair, R.P. John, Bioresour. Technol. 101, 8493–8501 (2010)
L. Yu, S. Petinakis, K. Dean, A. Bilyk, D. Wu, Macromol. Symp. 249–250, 535–539 (2007)
H. Namazi, S. Jafarirad, J. Appl. Polym. Sci. 110, 4034–4039 (2008)
Y. Habibi, L.A. Lucia, O.J. Rojas, Chem. Rev. 110, 3479–3500 (2010)
Y. Nishiyama, P. Langan, M. Wada, V.T. Forsyth, Acta Crystallogr. D Biol. Crystallogr. 66, 1172–1177 (2010)
J.C. Jansen, R. Cassano, S. Trombino, A. Cilea, N. Picci, E. Drioli, L. Giorno, Cellulose 18, 359–370 (2011)
Z. Li, D. Zhang, J. Weng, B. Chen, H. Liu, Carbohydr. Polym. 99, 748–754 (2014)
S. Barkhordari, M. Yadollah, H. Namazi, J. Polym. Res. 21, 1–9 (2014)
L. Yan, K. Ishihara, J. Polym. Sci. A Polym. Chem. 46, 3306–3313 (2008)
C. Yan, J. Zhang, Y. Lv, J. Yu, J. Wu, J. Zhang, J. He, Biomacromolecules 10, 2013–2018 (2009)
V. Tserki, N.E. Zafeiropoulus, F. Simon, C. Panayiotou, Compos. A. Appl. Sci. Manuf. 36, 1110–1118 (2005)
K.J. Edgar, C.M. Buchanan, J.S. Debenham, P.A. Rundquist, B.D. Seiler, M.C. Shelton, D. Tindall, Prog. Polym. Sci. 26, 1605–1688 (2001)
A. Biswas, R.L. Shogren, J.L. Willet, Biomacromolecules 6, 1843–1845 (2005)
F.C. Kung, W.L. Chou, M.C. Yang, Polym. Adv. Technol. 17, 6–11 (2006)
N. Hoenich, Bioresources 1, 270–280 (2006)
M. Alexandre, P. Dubois, Mater. Sci. Eng. R Rep. 28, 1–63 (2000)
Y. Dong, D. Chaudhary, C. Ploumis, K.T. Lau, Compos. A Appl. Sci. Manuf. 42, 1483–1492 (2011)
J. E. Lemons, Aluminum oxide ceramics as biomaterials. In Materials Science Monographs, vol 17 (Elsevier Science Publisher, Ligano Sabbiadoro, 1983), pp.117–126
D. Mishra, S. Anand, R.K. Panda, R.P. Das, Mater. Lett. 42, 38–45 (2000)
A. Laachachi, M. Ferriol, M. Cochez, J.M. Lopez Cuesta, D. Ruch, Polym. Degrad. Stab. 94, 1373–1378 (2009)
Z. Guo, P. Tony, C. Oyoung, Y. Wang, H.T. Hahn, J. Mater. Chem. 16, 2800–2808 (2006)
M. Schinicro, S. Yoshio, Suharyanto, Y. Yamano, K. Shinichi, Vacuum 81, 762–765 (2007)
Y. Cao, P.C. Irwin, K. Younsi, IEEE Trans. Dielectr. Electr. Insul. 11, 797–807 (2007)
J.K. Nelsen, Y. Hu, J. Phys. D Appl. Phys. 38, 213–222 (2005)
E. Tuncer, I. Sauers, D.R. James, A.R. Ellis, M.P. Paranthaman, T. Aytug, S. Sathyamurthy, K.L. More, J. Li, A. Goyal, Nanotechnology 18, 025703 (2007)
M.K. Mohanapriya, K. Deshmukh, M.B. Ahamed, K. Chidambaram, S.K.K. Pasha, Mater. Today 3, 1864–1873 (2016)
S.K.K. Pasha, K. Deshmukh, M.B. Ahamed, K. Chidambaram, M.K. Mohanapriya, N.A.N. Raj, Adv. Polym. Tech. (2015). doi:10.1002/adv.21616
K. Deshmukh, M.B. Ahamed, R.R. Deshmukh, S.K.K. Pasha, K. Chidambaram, K.K. Sadasivuni, D. Ponnamma, M.A.A. AlMaadeed, Polym. Plast. Technol. Eng. 55, 1240–1253 (2016)
Q.M. Zhang, H. Li, M. Poh, C. Huang, Nature 419, 284–287 (2002)
Y. Zhang, Y. Wang, M. Li, J. Bai, ACS Appl. Mater. Phys. Interfaces 4, 65–68 (2012)
A.C. Balazs, T. Emrick, T.P. Russel, Science 314, 1107–1110 (2006)
A. Kafy, K.K. Sadasivuni, H.C. Kim, A. Akther, J. Kim, Phys. Chem. Chem. Phys. 17, 5923–5931 (2015)
R.B. Romero, C.A.P. Leite, M.D.C. Goncalves, Polymer 50, 161–170 (2009)
R. Abedini, S.M. Mousavi, R. Aminizadeh, Desalination 277, 40–45 (2011)
S. Anita, B. Brabu, D.J. Thiruvadigal, C. Gopalkrishnan, T.S. Natarajan, Carbohydr. Polym. 87, 1065–1072 (2012)
A.S. Figueiriedo, M.G. Sanchez-Loredo, A. Mauricio, M.F.C. Pereira, M. Minhalma, M.N. De Pinho, J. Appl. Polym. Sci. 132, 1–11 (2015)
M. Li, I.H. Kim, Y.G. Jeong, J. Appl. Polym. Sci. 118, 2475–2481 (2010)
L. Liu, Z. Shen, S. Liang, M. Yi, X. Zhang, S. Ma, J. Mater. Sci. 49, 321–328 (2014)
M.E. Uddin, R.K. Layek, H.K. Kim, N.H. Kim, D. Hui, J.H. Lee, Compos. B 90, 223–231 (2016)
J. Xu, C.P. Wong, in Proceedings of International Symposium on Advanced Packing Materials: Processes, Properties and Interfaces, (Atlanta, 2004), pp. 158–170
C. Zhang, R. Mason, G.C. Stevens, in Annual Report-Conference on Electrical Insulation and Dielectric Phenomena, pp. 721–724 (2005)
P. Murugaraj, D. Mainwarning, N. Mora-Huertas, J. Appl. Phys. 98, 054304 (2005)
S. Singha, M.J. Thomas, IEEE Trans. Compon. Packag. Technol. 33, 373–385 (2010)
H. Li, G. Liu, B. Liu, W. Chen, S. Chen, Mater. Lett. 61, 1507–1511 (2007)
S. Sathish, S.B. Chandar, N. Manivannan, Iran. Polym. J. 24, 63–74 (2015)
A. Mishra, M. Bajpai, J. Hazard. Mater. 118, 213–217 (2005)
M. Farahmanddjou, N. Golabiyan, J. Ceram. Process. Res. 16, 237–240 (2015)
H.S. Kim, N.K. Park, T.J. Lee, M.H. Um, M. Kang, Adv. Mater. Sci. Eng. 2012, 920105–920110 (2012)
J. Wang, H. Jiang, N. Jiang, Thermochim. Acta 496, 136–142 (2009)
G. Arthanareeswaran, P. Thanikairelan, K. Srinivasn, D. Mohan, M. Rajendran, Eur. Polym. J. 40, 2153–2159 (2004)
G.M. Raghavendra, T. Jayaramudu, K. Varaprasad, R. Sadiku, S.S. Ray, K.M. Raju, Carbohydr Polym. 93, 553–560 (2013)
B.K. Kim, Y.S. Oh, Y.M. Lee, L.K. Yoon, S. Lee, Polymer 41, 385–390 (2000)
S.M. Pawde, K. Deshmukh, Polym. Eng. Sci. 49, 808–818 (2009)
K. Deshmukh, M.B. Ahamed, R.R. Deshmukh, S.K.K. Pasha, K.K. Sadasivuni, D. Ponnamma, K. Chidambaram, Eur. Polym. J. 76, 14–27 (2016)
J. Lu, K.-S. Moon, J. Xu, C.P. Wong, J. Mater. Chem. 16, 1543–1548 (2006)
K. Deshmukh, M.B. Ahamed, R.R. Deshmukh, P.R. Bhagat, S.K.K. Pasha, A. Bhagat, R. Shirbhate, F. Telare, C. Lakhani, Polym. Plast. Technol. Eng. 55, 231–241 (2016)
K. Deshmukh, M.B. Ahamed, K.K. Sadasivuni, D. Ponnamma, R.R. Deshmukh, S.K.K. Pasha, M.A.A. AlMaadeed, K. Chidambaram, J. Polym. Res. 23, 159 (2016)
K.K. Sadasivuni, D. Ponnamma, B. Kumar, M. Strankowski, R. Cardinaels, P. Moldenaers, S. Thomas, Y. Grohens, Compos. Sci. Technol. 104, 18–25 (2014)
K. Deshmukh, M.B. Ahamed, S.K.K. Pasha, R.R. Deshmukh, P.R. Bhagat, RSC Adv. 5, 61933–61945 (2015)
K. Deshmukh, M.B. Ahamed, A.R. Polu, K.K. Sadasivuni, S.K.K. Pasha, D. Ponnamma, M.A.A. AlMaadeed, R.R. Deshmukh, K. Chidambaram, J. Mater. Sci.: Mater. Electron. (2016). doi:10.1007/s10854-016-5267-x
M.K. Mohanapriya, K. Deshmukh, M.B. Ahamed, K. Chidambaram, S.K. Pasha, Adv. Mater. Lett. (2016). doi:10.5185/amlett.2016.6555
F. He, S. Lau, H.L. Chen, J.T. Fan, Adv. Mater. 21, 710–715 (2009)
V.S. Puli, D.K. Pradhan, D.B. Chrisey, M. Tomozawa, J.F. Scott, G.L. Sharma, J. Mater. Sci. 48, 2151–2157 (2013)
L.Y. Xie, X.Y. Huang, C. Wu, P.K. Jiang, J. Mater. Chem. 21, 5897–5906 (2011)
M.K. Mohanapriya, K. Deshmukh, M.B. Ahamed, K. Chidambaram, S.K.K. Pasha, Int. J. Chem. Tech. Res. 5, 32–41 (2015)
S.M. Pawde, K. Deshmukh, J. Appl. Polym. Sci. 110, 2569–2578 (2008)
G. Sui, B. Li, G. Bratzel, L. Baker, W.H. Zhong, X.P. Yang, Soft Matter 5, 3593–3598 (2009)
Acknowledgments
One of the authors, Kalim Deshmukh would like to acknowledge the financial support from the management of B. S. Abdur Rahman University, Chennai - 600048, TN, India in terms of Junior Research Fellowship (JRF) to carry out this research work.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Deshmukh, K., Ahamed, M.B., Deshmukh, R.R. et al. Newly developed biodegradable polymer nanocomposites of cellulose acetate and Al2O3 nanoparticles with enhanced dielectric performance for embedded passive applications. J Mater Sci: Mater Electron 28, 973–986 (2017). https://doi.org/10.1007/s10854-016-5616-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-016-5616-9