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Novelty characterization and enhancement of magnetic properties of Co and Cu nanoferrites

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Abstract

Cobalt and copper nano ferrites synthesized by citrate technique were characterized by X-ray diffraction technique, field emission scanning electron microscopy, transmission electron micrographs, energy dispersive X-ray spectroscopy and atomic force microscope. The average crystallite sizes of Cu and Co were 24.7 and 37.7 nm respectively. The magnetic properties were studied by carrying out the hysteresis of MFe2O4 (M-Cu2+, Co2+) at room temperature and at 77 K. The data showed that CuFe2O4 has the lower saturation magnetization. While CoFe2O4 has the larger coercive field due to the high anisotropy of Co2+ ions. The variation in saturation magnetization and coercivity for the investigated samples were explained on the bases of exchange interactions. The magnetic properties of the investigated samples changed at low temperature (77 K) which were observed in shape of the magnetic hysteresis M(H) loops as well as the coercivity and the squareness values. Co samples will be hopeful for technological applications at or below room temperature.

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References

  1. C. Buzea, I.I. Pacheco, K. Robbie, Nanomaterials and nanoparticles: sources and toxicity. Biointerphases 2(4), MR17–MR172 (2007)

    Article  Google Scholar 

  2. S.M. Hosseinpour-Mashkani, M. Ramezani, A. Sobhani-Nasab, M. Esmaeili-Zare, Synthesis, characterization and morphological control of CaCu3Ti4O12 through modify sol–gel method. J. Mater. Sci. Mater. Electron. 26, 6086–6091 (2015)

    Article  Google Scholar 

  3. S.M. Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, Precipitation synthesis, characterization, morphological, control, and photocatalyst application of ZnWO4 nanoparticles. J. Electron. Mater. 45, 3612 (2016)

    Article  Google Scholar 

  4. S.M. Hosseinpour-Mashkani, M. Maddahfar, A. Sobhani-Nasab, Novel silver-doped CdMoO4: synthesis, characterization, and its photocatalytic performance for methyl orange degradation through the sonochemical method. J. Mater. Sci. Mater. Electron. 27, 474–480 (2016)

    Article  Google Scholar 

  5. D. Erdem, N.S. Bingham, F.J. Heiligtag, N. Pilet, P. Warnicke, L.J. Heyderman, M. Niederberger, CoFe2O4 and CoFe2O4–SiO2 nanoparticle thin films with perpendicular magnetic anisotropy for magnetic and magneto-optical applications. Adv. Funct. Mater. 26(12), 1954–1963 (2016)

    Article  Google Scholar 

  6. Z. Huai-Wu, L. Jie, S. Hua, Z. Ting-Chuan, L. Yang, Z. Zong-Liang, Development and application of ferrite materials for low temperature co-fired ceramic technology. Chin. Phys. B 22(11), 117504 (2013)

    Article  Google Scholar 

  7. M. Rahimi-Nasrabadi, M. Behpour, A. Sobhani-Nasab, S. Mostafa Hosseinpour-Mashkani, ZnFe2−xLaxO4 nanostructure: synthesis, characterization, and its magnetic properties. J. Mater. Sci. Mater. Electron. 26, 9776–9781 (2015)

    Article  Google Scholar 

  8. M. Ramezani, S.M. Hosseinpour-Mashkani, A. Sobhani-Nasab, H.G. Estarki, Synthesis, characterization, and morphological control of ZnMoO4 nanostructures through precipitation method and its photocatalyst application. J. Mater. Sci. Mater. Electron. 26, 7588–7594 (2015)

    Article  Google Scholar 

  9. K. Nejati, R. Zabihi, Preparation and magnetic properties of nano size nickel ferrite particles using hydrothermal method. Chem. Cent. J. 6, 23 (2012)

    Article  Google Scholar 

  10. A.S. Padampalle, A.D. Suryawanshi, V.M. Navarkhele, D.S. Birajdar, Structural and magnetic properties of nanocrystalline copper ferrites synthesized by sol–gel autocombustion method. Int. J. Rec. Technol. Eng. 2, 2277–3878 (2013)

    Google Scholar 

  11. S. Krupicka, P. Novak, in Ferromagnetic Materials, vol. 3, ed. by E.P. Wohlfarth (North-Holland, Amsterdam, 1982)

    Google Scholar 

  12. H. Shenker, Magnetic anisotropy of cobalt ferrite and nickel cobalt ferrite. Phys. Rev. 107, 1246–1248 (1957)

    Article  Google Scholar 

  13. T. Hyeon, Chemical synthesis of magnetic nanoparticles. Chem. Commun. 8, 927–932 (2003)

    Article  Google Scholar 

  14. M. Walker, P.I. Mayo, K.O. Grady, S.W. Charles, R.W. Chantrell, The magnetic properties of single-domain particles with cubic anisotropy Hysteresis. J. Phys. Condens. Matter 5, 2779–2783 (1993)

    Article  Google Scholar 

  15. R. Valenzuela, Magnetic Ceramics (Cambridge University Press, Cambridge, 1994)

    Book  Google Scholar 

  16. K. Haneda, A.H. Morrish, Noncollinear magnetic structure of CoFe2O4 small particles. J. Appl. Phys. 63, 4258–4262 (1988)

    Article  Google Scholar 

  17. T. Dippong, E.A. Levei, L. Diamandescu, I. Bibicu, C. Leostean, G. Borodi, L.B. Tudoran, Structural and magnetic properties of CoxFe3−xO4 versus Co/Fe molar ratio. J. Mag. Mag. Mater. 394, 111–116 (2015)

    Article  Google Scholar 

  18. F. Schüth, K.S.W. Sing, J. Weitkamp (eds.), Handbook of Porous Solids, vol. 1 (Wiley, Weinheim, 2002)

    Google Scholar 

  19. A.M. Wahba, M.B. Mohamed, Structural, magnetic, and dielectric properties of nanocrystalline Cr-substituted Co0.8Ni0.2Fe2O4 ferrite. Ceram. Int. 40, 6127–6135 (2014)

    Article  Google Scholar 

  20. S. Amiri, H. Shokrollahi, Magnetic and structural properties of RE doped Co-ferrite (RE = Nd, Eu, and Gd) nano-particles synthesized by co-precipitation. J. Mag. Mag. 345, 18–23 (2013)

    Article  Google Scholar 

  21. M.A. Ahmed, E. Ateia, L.M. Salah, A.A. El-Gamal, Structural and electrical studies on La3+ substituted Ni–Zn ferrites. Mater. Chem. Phys. 92, 310–321 (2005)

    Article  Google Scholar 

  22. R.J. Hill, J.R. Craig, G.V. Gibbs, Systematics of the spinel structure type. Phys. Chem. Miner. 4, 317–339 (1979)

    Article  Google Scholar 

  23. Periodic Table, SARGENT-WELCH, Scientific Company, 7300 Linder Avenue, Skokie, Illinois 60076, Catalog Number 5-18806

  24. S. Lakshmi Reddy, T.R. Reddy, R. Nivya, P. Reji, O.A. Montero, T. Endo, R.L. Frost, Synthesis and spectroscopic characterization of copper zinc aluminium nanoferrite particles. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 127, 361–369 (2014)

    Article  Google Scholar 

  25. A.M. Elshahawy, M.H. Mahmoud, S.A. Makhlouf, H.H. Hamadeh, Role of Cu2+ substitution on the structural and magnetic properties of Ni-ferrite nanoparticles synthesized by microwave-combustion method. Ceram. Int. 41, 11264–11271 (2015)

    Article  Google Scholar 

  26. A.B. Nawale, N.S. Kanhe, K.R. Patil, S.V. Bhoraskar, V.L. Mathe, A.K. Das, Magnetic properties of thermal plasma synthesized nanocrystalline nickel ferrite NiFe2O4. J. Alloys Compd. 509, 4404–4413 (2011)

    Article  Google Scholar 

  27. U. Kurtan, R. Topkaya, A. Baykal, M.S. Toprak, Temperature dependent magnetic properties of CoFe2O4/CTAB nano composites synthesized by sol–gel auto-combustion technique. Ceram. Int. 39, 6551–6558 (2013)

    Article  Google Scholar 

  28. B.K. Rai, L. Wang, S.R. Mishra, V.V. Nguyen, J.P. Liu, Synthesis and magnetic properties of hard-soft SrFe10Al2O19/NiZnFe2O4 ferrite nanocomposites. J. Nanosci. Nanotechnol. 14, 5272–5277 (2014)

    Article  Google Scholar 

  29. G.Y. Kim, J.H. Jeon, M.H. Kim, D. Suvorov, S.Y. Choi, Microstructural development of cobalt ferrite ceramics and its influence on magnetic properties. Met. Mater. Int. 19, 1209–1213 (2013)

    Article  Google Scholar 

  30. S. Chakrabarty, A. Dutta, M. Pal, Enhanced magnetic properties of doped cobalt ferrites by virtue of cation distribution. J. Alloys Compd. 625, 216–223 (2015)

    Article  Google Scholar 

  31. E.E. Ateia, G. Abdelatif, M.A. Ahmed, M. AbdAlla Mahmoud, Effect of different Gd3+ ion content on the electric and magnetic properties of lithium antimony ferrite. J. Inorg. Organomet. Polym. Mater. 25, 81–90 (2015)

    Article  Google Scholar 

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Correspondence to Galila Abdelatif.

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Ateia, E.E., El-Bassuony, A.A., Abdelatif, G. et al. Novelty characterization and enhancement of magnetic properties of Co and Cu nanoferrites. J Mater Sci: Mater Electron 28, 241–249 (2017). https://doi.org/10.1007/s10854-016-5517-y

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  • DOI: https://doi.org/10.1007/s10854-016-5517-y

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