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Highly transparent conductive Ga doped ZnO films in the near-infrared wavelength range

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Abstract

Highly transparent Ga doped ZnO thin films were prepared on (0001) sapphire substrates by pulsed laser deposition. Hall-effect measurement reveals that electron concentration of the ZnO films can be controlled between 1018 and 1021 cm−3 by adjusting Ga contents in the targets. Optical measurements show the transmittance is above 60 % in the near-infrared wavelength region for all Ga doped ZnO films. Meanwhile, these films also have high crystal quality and smooth surface when the electron concentration up to 1021 cm−3, suggesting that the Ga doped ZnO is a promising material for using as transparent electrode for near infrared optoelectronic devices.

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References

  1. S.L. Chen, W.M. Chen, I.A. Buganova, Spin dynamics of isoelectronic bound excitons in ZnO. Phys. Rev. B 89, 235202 (2014)

    Article  Google Scholar 

  2. T. Tynell, M. Karppinen, Atomic layer deposition of ZnO: a review. Semicond. Sci. Technol. 29, 043001 (2014)

    Article  Google Scholar 

  3. T. Koida, M. Kondo, Comparative studies of transparent conductive Ti-, Zr-, and Sn-doped In2O3 using a combinatorial approach. J. Appl. Phys. 101, 063713 (2007)

    Article  Google Scholar 

  4. S. Calnan, A.N. Tiwari, High mobility transparent conducting oxides for thin film solar cells. Thin Solid Films 518, 1839–1849 (2010)

    Article  Google Scholar 

  5. L. Cao, L. Zhu, J. Jiang, Z. Ye, B. Zhao, Highly transparent and conducting fluorine-doped ZnO thin films prepared by pulsed laser deposition. Sol. Energy Mater. Sol. Cells 95, 894–898 (2011)

    Article  Google Scholar 

  6. Z.G. Zang, A. Nakamura, J. Temmyo, Single cuprous oxide films synthesized by radical oxidation at low temperature for PV application. Opt. Express 21, 11448–11456 (2013)

    Article  Google Scholar 

  7. S. Bethke, H. Pan, B.W. Wessels, Luminescence of heteroepitaxial zinc oxide. Appl. Phys. Lett. 52, 138–140 (1988)

    Article  Google Scholar 

  8. S. Choopun, R.D. Vispute, W. Noch, A. Balsamo, R.P. Sharma, T. Venkatesan, A. Iliadis, D.C. Look, Oxygen pressure-tuned epitaxy and optoelectronic properties of laser-deposited ZnO films on sapphire. Appl. Phys. Lett. 75, 3947–3949 (1999)

    Article  Google Scholar 

  9. Q. Nian, M.Y. Zhang, B.D. Schwartz, G.J. Cheng, Ultraviolet laser crystallized ZnO: Al films on sapphire with high Hall mobility for simultaneous enhancement of conductivity and transparency. Appl. Phys. Lett. 104, 201907 (2014)

    Article  Google Scholar 

  10. S.D. Shinde, A.V. Deshmukh, S.K. Date, V.G. Sathe, K.P. Adhi, Effect of Ga doping on micro/structural electrical and optical properties of pulsed laser deposited ZnO thin films. Thin Solid Films 520, 1212–1217 (2011)

    Article  Google Scholar 

  11. J.L. Zhao, X.W. Sun, H. Ryu, Y.B. Moon, Thermally stable transparent conducting and highly infrared reflective Ga-doped ZnO thin films by metal organic chemical vapor deposition. Opt. Mater. 33, 768–772 (2011)

    Article  Google Scholar 

  12. L. Ding, S. Nicolay, J. Steinhauser, U. Kroll, C. Ballif, Relaxing the conductivity/transparency trade-off in MOCVD ZnO thin films by hydrogen plasma. Adv. Funct. Mater. 23, 5177–5182 (2013)

    Article  Google Scholar 

  13. Z.W. Chen, X. Wang, S. Noda, K. Saito, T. Tanaka, M. Nishio, M. Arita, Q.X. Guo, Effects of dopant contents on structure, morphological and optical properties of Er doped Ga2O3 films. Superlattices Microstruct. 90, 207–214 (2016)

    Article  Google Scholar 

  14. H. Mahdhi, Z.B. Ayadi, S. Alaya, J.L. Gauffier, K. Djessas, The effects of dopant concentration and deposition temperature on the structural, optical and electrical properties of Ga-doped ZnO thin films. Superlattices Microstruct. 72, 60–71 (2014)

    Article  Google Scholar 

  15. Q.X. Guo, T. Yamamura, A. Yoshida, N. Itoh, Structural properties of InN films grown on sapphire substrates by microwave-excited metalorganic vapor-phase epitaxy. J. Appl. Phys. 75, 4927–4932 (1994)

    Article  Google Scholar 

  16. J.D. Ye, S.L. Gu, S.M. Zhu, S.M. Liu, Y.D. Zheng, R. Zhang, Y. Shi, H.Q. Yu, Y.D. Ye, Gallium doping dependence of single-crystal n-type ZnO grown by metal organic chemical vapor deposition. J. Cryst. Growth 283, 279–285 (2005)

    Article  Google Scholar 

  17. Z.G. Qian, W.Z. Shen, H. Ogawa, Q.X. Guo, Experimental studies of lattice dynamical properties in indium nitride. J. Phys. Condens. Matter 16, R381–R414 (2004)

    Article  Google Scholar 

  18. J. Ding, D. Zhang, T. Konomi, K. Saito, Q.X. Guo, Epitaxial growth of ZnO layers on (111) GaAs substrates by laser molecular beam epitaxy. Thin Solid Films 520, 2663–2666 (2012)

    Article  Google Scholar 

  19. Y. Yang, J.J. Qi, Q.L. Liao, Y. Zhang, X.Q. Yan, Y.H. Huang, L.D. Tang, Fabrication, structural characterization, and photoluminescence of Ga-doped ZnO nanobelts. Appl. Phys. A 94, 799–803 (2009)

    Article  Google Scholar 

  20. J. Nomoto, M. Konagai, K. Okada, T. Ito, T. Miyata, T. Minami, Comparative study of resistivity characteristics between transparent conducting AZO and GZO thin films for use at high temperatures. Thin Solid Films 518, 2937–2940 (2010)

    Article  Google Scholar 

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Acknowledgments

This work was partially supported by the Partnership Project for Fundamental Technology Research of Ministry of Education, Culture, Sports, Science, and Technology, Japan.

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Correspondence to Qixin Guo.

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Chen, Z., Saito, K., Tanaka, T. et al. Highly transparent conductive Ga doped ZnO films in the near-infrared wavelength range. J Mater Sci: Mater Electron 27, 9291–9296 (2016). https://doi.org/10.1007/s10854-016-4968-5

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  • DOI: https://doi.org/10.1007/s10854-016-4968-5

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