Skip to main content
Log in

Fabrication and characterization of fast response pyroelectric sensors based on Fe-doped PZT thin films

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Pyroelectric IR-detectors based on Pb(1−y)Fey(Zrx,Ti(1−x))O3 thin film have been successfully fabricated via ex situ oxidization annealing of DC magnetron sputtered conductive Fe doped lead-zirconium-titanium thin film on Au/SiO2/Si substrates. Structural as well as electro-optical properties were characterized. The results indicate that Fe-doping has had a remarkable structural effect namely, grain-size reduction, enhanced device voltage responsivity, 67.23 mV/mJ, and current-sensitivity, 5.16 × 10−6 mA/mJ. Moreover the pyroelectric coefficient, 609 μC m−2 °C−1, and merit figure, 1.43 × 10−6 μC m J−1, were significantly enhanced in comparison to previous reports on composite thick and thin film PZT and non-PZT based device structures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. T.N. Koltunowicz, P. Zukowski, O. Boiko, K. Czarnacka, V. Bondariev, A. Saad, A.V. Larkin, A.K. Fedotov, Capacitive properties of nanocomposite (FeCoZr)x(PZT)(1002x) produced by sputtering with the use of argon and oxygen ions beam. J. Mater. Sci: Mater. Electron. 27(2), 1171–1176 (2016)

    Google Scholar 

  2. T. Stevenson, D.G. Martin, P.I. Cowin, A. Blumfield, A.J. Bell, T.P. Comyn, P.M. Weaver, Piezoelectric materials for high temperature transducers and actuators. J. Mater. Sci.: Mater. Electron. 26(12), 9256–9267 (2015)

    Google Scholar 

  3. M. Molamohammadi, C. Luna, A. Arman, S. Solaymani, A. Boochani, A. Ahmadpourian, A. Shafiekhani, Preparation and magnetoresistance behavior of nickel nanoparticles embedded in hydrogenated carbon film. J. Mater. Sci.: Mater. Electron. 26(9), 6814–6818 (2015)

    Google Scholar 

  4. T.N. Koltunowicz, Inductive type properties of FeCoZr–CaF2 and FeCoZr–PZT nanocomposites. J. Mater. Sci: Mater. Electron. 26(9), 6450–6457 (2015)

    Google Scholar 

  5. D. Damjanovic, Ferroelectric dielectric and piezoelectric properties of ferroelectric thin films and ceramics. Rep. Prog. Phys. 61, 1267–1324 (1998)

    Article  Google Scholar 

  6. S.B. Lang, Pyroelectricity from ancient curiosity to modern imaging tool. Phys. Today 58(8), 31–36 (2005)

    Article  Google Scholar 

  7. R.L. Byer, C.B. Roundy, Pyroelectric coefficient direct measurement technique and application to NSEC time detector. Ferroelectrics 3, 333–338 (1972)

    Article  Google Scholar 

  8. L. Pintilie, M. Pereira, M.J.M. Gomes, I. Boerasu, Pyroelectric current spectroscopy example of application on Nb doped Pb(Zr0.92Ti0.08)O3 ceramics for infrared detection. Sens. Actuat. A 115, 185–190 (2004)

    Article  Google Scholar 

  9. Q. Zhang, R.W. Whatmore, Sol–gel PZT and Mn-doped PZT thin films for pyroelectric applications. J. Phys. D Appl. Phys. 34, 2296–2301 (2001)

    Article  Google Scholar 

  10. Y.Q. Xu, N.J. Wu, A. Ignatiev, (Mn, Sb) doped-Pb(Zr, Ti)O 3 infrared detector arrays. J. Appl. Phys. 88(2), 1004–1007 (2000)

    Article  Google Scholar 

  11. K.H. Hardtl, Defect structure of PLZT doped with Mn, Fe, and Al. J. Am. Ceram. Soc. 64(5), 283–288 (1981)

    Article  Google Scholar 

  12. C. Zhu, Z. Young, Y. Chentao, Y. Bangchao, Investigation the effects of the excess Pb content and annealing conditions on the microstructure and ferroelectric properties of PZT (52-48) films prepared by sol–gel method. Appl. Surf. Sci. 253, 1500–1505 (2006)

    Article  Google Scholar 

  13. C.C. Chang, P.C. Lu, The effect of annealing on improving the quality of lead zirconate titanate thin films on Pt/SiO2/Si substrates. J. Mater. Process. Technol. 95, 128–132 (1999)

    Article  Google Scholar 

  14. L.L. Sun, W.G. Liu, O.K. Tan, W. Zhou, Effect of annealing temperature on the sol/gel derived Pb(Zr0.3Ti0.7)O3 thin films for pyroelectric application. Mater. Sci. Eng. B 99, 173–178 (2003)

    Article  Google Scholar 

  15. M.A. Mohiddon, K.L. Yadav, Effect of Fe doping on dielectric, ferroelectric and pyroelectric properties of PLZT (8/65/35). J. Phys. D Appl. Phys. 40, 7540–7547 (2007)

    Article  Google Scholar 

  16. R. Takayama, Y. Tomita, K. Iijima, I. Ueda, Preparation and characteristics of pyroelectric infrared sensors made of c axis oriented La modified PbTi03 thin films. J. Appl. Phys. 61(1), 411–415 (1987)

    Article  Google Scholar 

  17. S. Satapathy, V.K. Wadhawan, Fabrication of pyroelectric laser-energy meters and their characterization using Nd-YAG laser of variable pulse-width. Sens. Actuat. A 121, 576–583 (2005)

    Article  Google Scholar 

  18. R.W. Astheimer, R.E. Buckley, Pyroelectric laser calorimeter. Rev. Sci. Instrum. 38(12), 1764–1768 (1967)

    Article  Google Scholar 

  19. Y. Yuan, A new pulse laser energy meter. Rev. Sci. Instrum. 61(6), 1743–1746 (1990)

    Article  Google Scholar 

  20. H. Schopf, W. Ruppel, P. Wurfel, Voltage responsivity of pyroelectric detectors on a heat-sink substrate. Ferroelectrics 118, 297–305 (1991)

    Article  Google Scholar 

  21. W.K. Sakamoto, S.T. Shibatta-Kagesawa, W.L.B. Melo, Voltage responsivity of pyroelectric sensor. Sens. Actuat. A 77, 28–33 (1999)

    Article  Google Scholar 

  22. J.S. Ko, W. Liu, W. Zhu, Substrate effects on the properties of the pyroelectric thin film IR detectors. Sens. Actuat. A 93, 117–122 (2001)

    Article  Google Scholar 

  23. S.F. Diaz, J.F. Zhu, N. Shamir, C.T. Campbell, Pyroelectric heat detector for measuring adsorption energies on thicker single crystals. Sens. Actuat. B 107, 454–460 (2005)

    Article  Google Scholar 

  24. N. Chong, H.L.W. Chan, C.L. Choy, Pyroelectric sensor array for in-line monitoring of infrared laser. Sens. Actuat. A 96, 231–238 (2002)

    Article  Google Scholar 

  25. B. Bhatia, J. Karthik, T. Tong, D.G. Cahill, L.W. Martin, W.P. King, Pyroelectric current measurements on PbZr0.2Ti0.8O3 epitaxial layers. J. Appl. Phys. 112, 1041061–1041066 (2012)

    Article  Google Scholar 

  26. C.B. Roundy, L. Byer, D.W. Phillion, D.J. Kuizenga, A 170 psec pyroelectric detector. Opt. Commun. 10(4), 374–377 (1974)

    Article  Google Scholar 

  27. A.M. Glazer, P. Groves, D.T. Smith, Automatic sampling circuit for ferroelectric hysteresis loops. J. Phys. E Sci. Instrum. 17, 95–97 (1984)

    Article  Google Scholar 

  28. E.G. Lee, D.J. Wouters, G. Willems, H.E. Maes, Voltage shift and deformation in the hysteresis loop of Pb(Zr, Ti)O3 thin film by defects. Appl. Phys. Lett. 69(9), 1223–1225 (1996)

    Article  Google Scholar 

  29. I. Kanno, H. Kotera, K. Wasa, T. Matsunaga, T. Kamada, R. Takayama, Crystallographic with different Zr/Ti ratio grown by radio-frequency-magnetron sputtering characterization of epitaxial Pb(Zr, Ti)O3 films. J. Appl. Phys. 93(7), 4091–4096 (2003)

    Article  Google Scholar 

  30. M.T. Kesim, J. Zhang, S. Trolier-McKinstry, J.V. Mantese, R.W. Whatmore, S.P. Alpay, Pyroelectric response of lead zirconate titanate thin films on silicon Effect of thermal stresses. J. Appl. Phys 114, 2041011–2041017 (2013)

    Article  Google Scholar 

  31. C.P. Shaw, S. Gupta, S.B. Stringfellow, A. Navarro, J.R. Alcock, R.W. Whatmore, Pyroelectric properties of Mn-doped lead zirconate–lead titanate–lead magnesium niobate ceramics. J. Eur. Ceram. Soc. 22, 2123–2132 (2002)

    Article  Google Scholar 

  32. C. Ye, T. Tamagawa, P. Schiller, D.L. Polla, Pyroelectric PbTiO3 thin films for microsensor applications. Sens. Actuat. A 35, 77–83 (1992)

    Article  Google Scholar 

  33. M. Es-Souni, S. Iakovlev, C.H. Solterbeck, Processing and characterization of PZFNT and PZFNT/PET thin films for pyroelectric applications. J. Eur. Ceram. Soc. 24, 985–988 (2004)

    Article  Google Scholar 

  34. P. Guggila, A.K. Batra, J.R. Currie, M.D. Aggarwal, M.A. Alim, R.B. Lal, Pyroelectric ceramics for infrared detection applications. Mater. Lett. 60, 1937–1942 (2006)

    Article  Google Scholar 

Download references

Acknowledgments

This work was carried out as Sheykh Bahaee’s Research projects. The authors would like to thank M. Tavvakoli for his useful advice with the electronics setup measurements.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Farhad Fouladi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fouladi, F., Javid, E. & Jalili, Y.S. Fabrication and characterization of fast response pyroelectric sensors based on Fe-doped PZT thin films. J Mater Sci: Mater Electron 27, 6578–6585 (2016). https://doi.org/10.1007/s10854-016-4603-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-016-4603-5

Keywords

Navigation