Skip to main content
Log in

Microstructure and electrical properties of Sm2O3-doped ZnO-based linear resistance ceramics

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

ZnO-based linear resistance ceramics were synthesized from ZnO–MgO–NiO–Al2O3–SiO2–Sm2O3 at 1320 °C for 3 h by the conventional ceramics method. The microstructure and electrical properties of the linear resistance ceramics have been systematically investigated in detail. The experimental result indicates that appropriate amounts of Sm2O3 addition can obviously improve the resistance temperature coefficient of ZnO-based linear resistance ceramics compared with the Sm2O3-free samples. The samples with the Sm2O3 content of 0.5 mol% exhibit excellent electrical properties with the resistivity of 209.8 Ω cm and the resistance temperature coefficient of 2.38 × 10−4/°C, which is improved by 46 and 92 %, respectively. Moreover, the nonlinear coefficient of voltage decreases to 1.15, decreased by 4.30 % and the relative density reaches to 96.43 %, increased by 4.91 %.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. S. Chu, T. Yan, S. Chen, Analysis of ZnO varistors prepared by the sol–gel method. Ceram. Int. 26, 733–737 (2000)

    Article  Google Scholar 

  2. S. Shirakawa, S. Owada, N. Iimura et al., Application and development of a ceramics desistor for use as a neutral grounding resistor (NGR). IEEE Trans. Power Deliv. 3, 183–186 (1988)

    Article  Google Scholar 

  3. T.K. Gupta, Application of zinc oxide varistors. J. Am. Ceram. Soc. 73, 1817–1840 (1990)

    Article  Google Scholar 

  4. S. Bernik, N. Daneu, Characteristics of ZnO based varistor ceramics doped with Al2O3. J. Eur. Ceram. Soc. 27, 3161–3170 (2007)

    Article  Google Scholar 

  5. E.R. Leite, M.A.L. Nobre, E. Longo, J.A. Varela, Reactive liquid phase sintering in zinc oxide varistor materials, Sintering Technology (Marcel Dekker, New York, 1996), p. 481

    Google Scholar 

  6. J.F. Zhu, Y. Zhou, H.B. Yang, F. Wang, Effect of TiO2 addition on the microstructure and electrical properties of ZnO-based linear resistance ceramics. J. Mater. Sci. Mater. Electron. 23, 445–450 (2012)

    Article  Google Scholar 

  7. L.M. Levinson, H.R. Philipp, Zinc oxide varistors. Am. Ceram. Soc. Bull. 65, 639–646 (1986)

    Google Scholar 

  8. M. Matbuaka, Nonohmic properties of zinc oxide ceramics. J. Appl. Phys. 10, 736–746 (1971)

    Article  Google Scholar 

  9. J.F. Zhu, J.J. Wang, Y. Zhu, F. Wang, Major effects on microstructure and electrical properties of ZnO-based linear resistance ceramics with MgO changes. J. Mater. Sci. Mater. Electron. 25, 2273–2278 (2014)

    Article  Google Scholar 

  10. J.J. Wang, J.F. Zhu, Y. Zhu, F. Wang, Microstructure and electrical properties of rare-earth oxides doped ZnO-based linear resistance ceramics. J. Mater. Sci. Mater. Electron. 25, 3301–3307 (2014)

    Article  Google Scholar 

  11. D. Lisjak, M. Drofenik, D. Kolar, Composite ceramics with a positive temperature coefficient of electrical resistivity effect. J. Mater. Res. 15, 417–428 (2000)

    Article  Google Scholar 

  12. M.A. Ashraf, A.H. Bhuiyan, M.A. Hakim, M.T. Hossain, Microstructure and electrical properties of Sm2O3 doped Bi2O3-based ZnO varistor ceramics. Mater. Sci. Eng. B 176, 855–860 (2011)

    Article  Google Scholar 

  13. H. Bastami, E. Taheri-Nassaj, Effect of Sm2O3 on the microstructure and electrical properties of SnO2-based varistors. Ceram. Int. 38, 265–270 (2012)

    Article  Google Scholar 

  14. M. Sida, S. Chun, N. Wakiya, K. Shinozaki, N. Mizutani, Effect of the sintering temperature and atmosphere on the grain growth and grain boundary phase formation of Pr-doped ZnO varistor. J. Ceram. Soc. Jpn. 104, 44–48 (1996)

    Article  Google Scholar 

  15. S. Bernik, S. Macek, B. Ai, Microstructural and electrical characteristics of Y2O3-doped ZnO–Bi2O3-based varistor ceramics. J. Eur. Ceram. Soc. 21, 1875–1878 (2001)

    Article  Google Scholar 

  16. Y.H. Zhang, J. Han, Microstructure and temperature coefficient of resistivity for ZnO ceramics doped with Al2O3. Mater. Lett. 60, 2522–2525 (2006)

    Article  Google Scholar 

  17. D. Lisjak, I. Zajc, M. Drofenik, J. Jamnik, Investigation of the PTCR effect in ZnO–NiO two-phase ceramics. Solid State Ion. 99, 125–135 (1997)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Key Project of Chinese Ministry of Education (No. 210218), Scientific and Technological Project of Wenzhou (H20100079, H20100087), and the Graduate Innovation Fund of Shaanxi University of Science and Technology.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jianfeng Zhu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhu, J., Liu, Q., Wang, J. et al. Microstructure and electrical properties of Sm2O3-doped ZnO-based linear resistance ceramics. J Mater Sci: Mater Electron 27, 818–824 (2016). https://doi.org/10.1007/s10854-015-3822-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-015-3822-5

Keywords

Navigation