Abstract
The polycrystalline sample of Bi2La3Ti3FeO15was synthesized using a solid-state reaction technique. The formation, basic crystal data and crystalline nature of the compound have been determined by an X-ray diffraction technique at room temperature. Some characteristics (i.e., distribution, size and shape of grains, etc.) of surface microstructure of a pellet (obtained at room temperature using scanning electron microscopy) exhibit the formation of high-density sample. Dielectric and Complex impedance spectroscopy method was used to study electrical characteristics of the material. The material was found to have temperature dependence of electrical relaxation phenomena. Impedance measurements carried out in a wide temperature (30–500 °C) and frequency (1–1000 kHz) ranges have provided many new and interesting results. The ac conductivity studied in the above ranges is found to obey Jonscher’s universal power law. The results of the conduction mechanism of the sample has been analysed in terms of resistive and capacitive components of complex plane formalism and suitable equivalent circuits have been proposed for different regions.
Similar content being viewed by others
References
W.S. Kim, T.H. Kim, E.S. Kim, J. Am. Ceram. Soc. 82, 2111 (1999)
W. Eerenstein, N.D. Mathur, J.F. Scott, Nature 442, 759 (2006)
N.A. Spaldin, M. Fiebig, Science 309, 391 (2005)
R.E. Newnham, R.W. Wole, J.F. Dorrian, Mater. Res. Bull. 6, 1029 (1971)
W. Eerenstein, N.D. Mathur, J.F. Scott, Multiferroic Magnetoelectr. Mater. Nat. (London) 442, 759 (2006)
N.A. Hill, J. Phys. Chem. B 104, 6694 (2000)
M. Fiebig, J. Phys. D Appl. Phys. 38, 123 (2005)
B. Yu, M. Li, J. Liu, D. Guo, L. Pei, X. Zhao, J. Phys. D Appl. Phys. 41, 065003 (2008)
P.C. Sati, M. Arora, S. Chauhan, S. Chhoker, M. Kumar, J. Appl. Phys. 112, 094102 (2012)
N.K. Verma, G.S. Lotey, J. Nanopart. Res. 14, 742 (2012)
D. Maurya, H. Thota, A. Garg, B. Pandey, H.C. Verma, J. Phys. Condens. Matter 21, 026007 (2009)
S. Zhang, L. Wang, Y. Chen, D. Wang, Y. Yao, Y. Ma, J. Appl. Phys. 111, 074105 (2012)
R.Z. Hou, X.M. Chen, J. Electroceram. 10, 203 (2003)
S.K. Patri, R.N.P. Choudhary, J. Mater. Sci. Mater. Electron. 19, 1240 (2008)
X.Y. Mao, W. Wang, X.B. Chen, Solid State Commun. 147, 186 (2008)
H.K. Jo, S.S. Kim, D. Do, J. Solgel Sci. Technol. 49, 336 (2009)
A. Mohapatra, P.R. Das, R.N.P. Choudhary, J. Mater. Sci. Mater. Electron. 25, 1348 (2014)
H. Zhao, H. Kimura, Z. Cheng, M. Osada, J. Wang, X. Wang, S. Dou, Y. Liu, J. Yu, T. Matsumoto, T. Tohei, N. Shibata, Y. Ikuhara, Sci. Rep. 4, 5255 (2014)
X.Q. Chen, X.B. Zeng, F.L. Yang, X.P. Kong, C. Wei, P. Su, Adv. Mater. 668, 762 (2013)
E.W. Powd, An interactive Powder diffraction data interpretation and indexing Program, Ver 2.1, School of Physical Science, Finders University of South Australia, Bedford Park, S.A. 5042, Australia
P.H. Borse, S.S. Yoon, J.S. Jang, J.S. Lee, T.E. Hong, E.D. Jeong, M.S. Won, O.S. Jung, Y.B. Shim, H.G. Kim, Bull. Korean Chem. Soc. 30, 3011 (2009)
M.G. Guaderrama, G.G.C. Arizaga, A. Durán, Ceram. Int. 40, 7459 (2014)
C.H. Hervoches et al., J. Solid Sate Chem. 164, 280 (2002)
H.B. Yang, H. Wang, L. He et al., J. Appl. Phys. 108, 074105 (2010)
J.R. Macdonald, Impedance Spectroscopy (Wiley, New York, 1987)
S. Pattanayak, R.N.P. Choudhary, P.R. Das, J. Mater. Sci. Mater. Electron. 24, 2767 (2013)
K. Lily, K. Kumari, R.N.P. Choudhary, K. Prasad, J. Alloys Compd. 453, 325 (2008)
S. Sen, R.N.P. Choudhary, Mater. Chem. Phys. 87, 256 (2004)
B. Yemu, ZSimpWin, Version 2.00 (Echem Software, AnnArbor, 1999)
M.A.L. Nobre, S.J. Lanfredi, Appl. Phys. 93, 5557 (2003)
V. Provenzano, L.P. Boesch, V. Volterra, C.T. Moynihan, P.B. Macedo, J. Am. Ceram. Soc. 55, 492 (1972)
H. Jain, C.H. Hsieh, J. Solids Non Cryst 172, 1408 (1994)
P.S. Das, P.K. Chakraborty, B. Behera, R.N.P. Choudhary, Phys. B 98, 39 (2007)
I.M. Hodge, M.D. Ingram, A.R. West, J. Electroanal. Chem. Interfacial Electrochem. 58, 429 (1975)
P.B. Macedo, C.T. Moynihan, R. Bose, Phys. Chem. Glasses 13, 171 (1972)
R.N.P. Choudhary, D.K. Pradhan, C.M. Tirado, G.E. Bonilla, R.S. Khatiyar, J. Mater. Sci. 42, 7423 (2007)
J.R. Macdonald, Solid State Ionics 13, 147 (1984)
S.K. Patri, R.N.P. Choudhary, J. Mater. Sci. Mater. Electron. 19, 1240 (2008)
S. Pattanayak, B.N. Parida, P.R. Das, R.N.P. Choudhary, Appl. Phys. A 112, 387 (2013)
M.A.L. Nobre, S. Lanfredi, J. Appl. Phys. 93, 5557 (2003)
D.K. Pradhan, R.N.P. Choudhary, C. Rinaldi, R.S. Katiyar, J. Appl. Phys. 106, 024102 (2009)
A.K. Jonscher, Nature 267, 673 (1977)
C.K. Suman, K. Prasad, R.N.P. Choudhary, J. Mater. Sci. 41, 369 (2006)
K. Funke, Solid State Chem. 22, 111 (1993)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mohapatra, A., Das, P.R. & Choudhary, R.N.P. Structural and electrical properties of Bi2La3Ti3FeO15 ceramics. J Mater Sci: Mater Electron 27, 436–443 (2016). https://doi.org/10.1007/s10854-015-3771-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-015-3771-z