Correlation between lattice distortion and magnetic and electrical properties of Fe-doped Bi4Ti3O12 ceramics

  • Yuwen Liu
  • Yongping Pu
  • Zixiong Sun


Aurivillius phase Bi4Ti3O12xFe2O3 (BIT–xFe, x = 0–0.08) ceramics were prepared by conventional solid-state method. The crystallographic evolution was determined via the X-ray diffraction patterns, by which the lattice parameters, a, b and c were also calculated. It was found that the increasing content of Fe2O3 reduced the lattice distortion of BIT-based ceramics, which led to a phase transition from orthorhombic to tetragonal. Ferroelectricity and magnetization data showed that BIT–xFe ceramics possess expected ferroelectric and ferromagnetic behaviors. Besides, the grain size decreased as structure changed from rod-like to sphere with increasing x, which can be observed in the SEM. The dielectric constant can be analyzed by a “brick-wall” model, the dielectric loss and dc conductivity had a tendency to decrease with increasing x.


Fe2O3 Bismuth Dielectric Loss BiFeO3 Lattice Distortion 
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This research was supported by the National Natural Science Foundation of China (51372144) and the Key Program of Innovative Research Team of Shaanxi Province (2014KCT-06).


  1. 1.
    Q. Lin, M. Jiang, D.M. Lin, Q.J. Zheng, X.C. Wu, X.M. Fan, Effects of La-doping on microstructure, dielectric and piezoelectric properties of Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free ceramics. J. Mater. Sci. Mater. Electron. 24, 734–739 (2013)CrossRefGoogle Scholar
  2. 2.
    O. Subohi, G.S. Kumar, M.M. Malik, R. Kurchania, Dielectric properties of bismuth titanate (Bi4Ti3O12) synthesized using solution combustion route. Phys. B 407, 3813–3817 (2012)CrossRefGoogle Scholar
  3. 3.
    M. Chen, Z.L. Liu, Y. Wang, C.C. Wang, X.S. Yang, K.L. Yao, Ferroelectric properties and microstructures of Sm-doped Bi4Ti3O12 ceramics. Phys. B 352, 61–65 (2004)CrossRefGoogle Scholar
  4. 4.
    S.E. Cummings, L.E. Cross, Electrical and optical properties of ferroelectric BIT single crystals. J. Appl. Phys. 39, 2268 (1968)CrossRefGoogle Scholar
  5. 5.
    B. Aurivillius, Mixed bismuth oxides with layer lattices, II. Structure of Bi4Ti3O12. Ark För Kemi 1, 499–512 (1949)Google Scholar
  6. 6.
    P. Xiang, Y. Kinemuchi, T. Nagaoka, K. Watari, Sintering behaviors of bismuth titanate synthesized by a coprecipitation method. Mater. Lett. 59, 3590–3594 (2005)CrossRefGoogle Scholar
  7. 7.
    Y. Kan, P. Wang, Y. Li, Y. Cheng, D. Yan, Fabrication of textured bismuth titanate by templated grain growth using aqueous tape casting. J. Eur. Ceram. Soc. 23, 2163–2169 (2003)CrossRefGoogle Scholar
  8. 8.
    S.R. Dhage, Y.B. Khollam, S.B. Dhespande, H.S. Potdar, V. Ravi, Synthesis of bismuth titanate by citrate method. Mater. Res. Bull. 39, 1993–1998 (2004)CrossRefGoogle Scholar
  9. 9.
    Y. Shi, C. Cao, S. Feng, Hydrothermal synthesis and characterization of Bi4Ti3O12. Mater. Lett. 46, 270–273 (2000)CrossRefGoogle Scholar
  10. 10.
    Q. Yang, Y. Li, Q. Yin, P. Wang, Y.B. Cheng, Bi4Ti3O12 nanoparticles prepared by hydrothermal synthesis. J. Eur. Ceram. Soc. 23, 161–166 (2003)CrossRefGoogle Scholar
  11. 11.
    P. Pookmanee, P. Uriwilast, S. Phanichpant, Hydrothermal synthesis of fine bismuth titanate powders. Ceram. Int. 30, 1913–1915 (2004)CrossRefGoogle Scholar
  12. 12.
    H.S. Shulman, M. Testorf, D. Damjanovic, N. Setter, Microstructure, electrical conductivity and piezoelectric properties of bismuth titanate. J. Am. Ceram. Soc. 79, 3124–3128 (1996)CrossRefGoogle Scholar
  13. 13.
    M. Villegas, A.C. Caballero, J.F. Fern, Modulation of electrical conductivity through microstructural control in Bi4Ti3O12-based piezoelectric ceramics. Ferroelectrics 267, 165–173 (2002)CrossRefGoogle Scholar
  14. 14.
    W. Wang, D. Shan, J. Sun, X. Mao, X. Chen, Aliovalent B-site modification on three- and four-layer Aurivillius intergrowth. J. Appl. Phys. 103, 044102 (2008)CrossRefGoogle Scholar
  15. 15.
    S. Hong, S. Trolier-mckinstry, G.L. Messing, Dielectric and electromechanical properties of textured niobium-doped bismuth titanate ceramics. J. Am. Ceram. Soc. 83, 113–118 (2000)CrossRefGoogle Scholar
  16. 16.
    J. Hou, R.V. Kumar, Y. Qu, D. Krsmanovic, B-site doping effect on electrical properties of Bi4Ti3−2xNbxTaxO12 ceramics. Scr. Mater. 61, 664–667 (2009)CrossRefGoogle Scholar
  17. 17.
    J.D. Bobić, M.M. Vijatović Petrović, J. Banys, B.D. Stojanović, Electrical properties of niobium doped barium bismuth-titanate ceramics. Mater. Res. Bull. 47, 1874–1880 (2012)CrossRefGoogle Scholar
  18. 18.
    R.D. Shannon, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A 32, 751–767 (1976)CrossRefGoogle Scholar
  19. 19.
    S.E. Cummins, L.E. Cross, Ferroelectric domains in Bi4Ti3O12 single crystals. J. Appl. Phys. 39, 2268–2274 (1986)CrossRefGoogle Scholar
  20. 20.
    Y. Shimakawa, Y. Kubo, Y. Nakagawa, S. Goto, T. Kamiyama, H. Asano, F. Izumi, Crystal structure and ferroelectric properties of ABi2Ta2O9(A = Ca, Sr, and Ba). Phys. Rev. B Condens. Matter 61, 6559–6564 (2000)CrossRefGoogle Scholar
  21. 21.
    S.M. Blake, M.J. Falconer, M. McCreedy, P. Lightfoot, Cation disorder in ferroelectric Aurivillius phases of the type Bi2ANb2O9(A = Ba, Sr, Ca). J. Mater. Chem. 7, 1609–1613 (1997)CrossRefGoogle Scholar
  22. 22.
    J.F. Scott, Ferroelectrics go bananas. J. Phys. Condens. Matter 20, 021001 (2008)CrossRefGoogle Scholar
  23. 23.
    J.R. Teague, R. Gerson, W.J. James, Dielectric hysteresis in single crystal BiFeO3. Solid State Commun. 8, 1073–1074 (1970)CrossRefGoogle Scholar
  24. 24.
    N.A. Hill, Why are there so few magnetic ferroelectrics? J. Phys. Chem. B 104, 6694–6709 (2000)CrossRefGoogle Scholar
  25. 25.
    V. Buscaglia, M.T. Buscaglia, M. Viviani, L. Mitoseriu, P. Nanni, V. Trefiletti, Grain size and grain boundary-related effects on the properties of nano-crystalline barium titanate ceramics. J. Eur. Ceram. Soc. 26, 2889–2898 (2006)CrossRefGoogle Scholar
  26. 26.
    M. Takahashi, Y. Nguchi, M. Miyayama, J. Jpn, Effects of V-doping on mixed conduction properties of bismuth titanate single crystals. Jpn. J. Appl. Phys. 42, 6222–6225 (2003)CrossRefGoogle Scholar

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© Springer Science+Business Media New York 2015

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringShaanxi University of Science and TechnologyXi’anPeople’s Republic of China

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