Abstract
Manganese doped zinc oxide (ZnO) thin films were synthesized for various wt% doping of Mn using sol–gel spin coating technique. The effects of Mn doping on the structural, morphological, compositional, photoluminescence (PL) and magnetic behaviour of ZnO thin films were investigated. Although, Mn doping did not change the lattice constants of the films, the texture coefficient is found to be improved for the films having higher percentage of Mn doping. PL studies reveal that as doping concentration of Mn increases, the intensity of emission peaks corresponding to violet and blue colour increases and the peak position shifts slightly. The saturated magnetic moments are found to decrease with the increase in Mn doping and the reason for such behavior is discussed.
Similar content being viewed by others
References
Y. Liu, T. Wang, X. Sun, Q. Fang, Q. Lv, X. Song, Z. Sun, Appl. Surf. Sci. 257, 6540–6545 (2011)
U. Ilyas, T.L. Tan, P. Lee, R.V. Ramanujan, L. Fengji, S. Zhang, R. Chen, H.D. Sun, R.S. Rawat, J. Magn. Magn. Mater. 344, 171–175 (2013)
X. Zhou, S. Ge, D. Yao, Y. Zuo, Y. Xiao, Phys. B 403, 3336–3339 (2008)
T. Dietl, H. Ohno, F. Matsukura, J. Cibert, D. Ferrand, Science 287, 1019–1022 (2000)
W. Liang, T. Hou, Y. Wang, Y. Zhao, Z. Guo, Y. Li, S.-T. Lee, J. Alloys Compd. 541, 250–255 (2012)
S. Deka, P.A. Joy, Solid State Commun. 142, 190–194 (2007)
X.L. Wang, Q. Shao, C.W. Leung, A. Ruotolo, J. Appl. Phys. 113, 17C301 (2013)
K. Sharda, K. Jayanthi, S. Chawla, Appl. Surf. Sci. 256, 2630–2635 (2010)
J. Elanchezhiyan, K.P. Bhuvana, N. Gopalakrishnan, T. Balasubramanian, Mater. Lett. 62, 3379–3381 (2008)
P. Thakur, K.H. Chae, M. Subramanain, R. Jayavel, K. Asokan, J. Korean Phys. Soc. 53, 2821–2825 (2008)
Y.Y. Song, K.S. Park, K.H. Park, S.K. Oh, S.C. Yu, H.J. Kang, K.W. Lee, J. Korean Phys. Soc. 52, 106–111 (2008)
R.N. Gayen, K. Sarkar, S. Hussain, R. Bhar, A.K. Pal, Indian J. Pure Appl. Phys. 49, 470–477 (2011)
G.-J. Huang, J.-B. Wang, X.-L. Zhong, G.-C. Zhou, H.-l. Yan, Optoelectron. Lett. 2, 439–442 (2006)
Z. Yang, Z. Zuo, H.M. Zhou, W.P. Beyermann, J.L. Liu, J. Cryst. Growth 314, 97–103 (2011)
J.S. Fang, W.H. Luo, C.H. Hsu, J.C. Yang, T.K. Tsai, J. Electron. Mater. 41, 122–129 (2012)
D. Shuang, J.B. Wang, X.L. Zhong, H.L. Yan, Mater. Sci. Semicond. Proc. 10, 97–102 (2007)
X. Yan, D. Hu, H. Li, L. Li, X. Chong, Y. Wang, Phys. B 406, 3956–3962 (2011)
T. Mahalingam, K.M. Lee, K.H. park, S. Lee, Y. Ahn, J.-Y. Park, K.H. Koh, Nanotechnology 18, 035606–035610 (2007)
K.C. Barick, M. Aslam, V.P. Dravid, D. Bahadur, J. Colloid Interface Sci. 349, 19 (2010)
C.D. Wagner, W.M. Riggs, L.E. Davis, J.F. Moulder, G.E. Muilenberg, Handbook of X-ray Photoelectron Spectroscopy (Perkin Elmer, Eden Prairie, 1979), pp. 80–84
I. Polat, S. Aksu, M. Altunbaş, S. Yılmaz, E. Bacaksız, J. Solid State Chem. 184, 2683–2689 (2011)
L.L. Yang, Q.X. Zhao, M. Willander, J.H. Yang, I. Ivanov, J. Appl. Phys. 105, 53503–53509 (2009)
N.S. Norberg, K.R. Kittilstved, J.E. Amonette, R.K. Kukkadapu, D.A. Schwartz, D.R. Gamelin, J. Am. Chem. Soc. 126, 9387–9398 (2004)
Y.S. Wang, P.J. Thomas, P.J. O’Brien, J. Phys. Chem. B 110, 21412–21415 (2006)
S.M. Abrarov, S.U. Yuldashev, T.W. Kim, Y.H. Kwon, T.W. Kang, Opt. Commun. 259, 378–384 (2006)
A. Jagannatha Reddya, M.K. Kokilab, H. Nagabhushanac, J.L. Raod, B.M. Nagabhushanae, O.D. Jayakumar, I.K. Gopalakrishnan, S.K. Kulshrestha, Phys. B 381, 194–198 (2006)
Y.-M. Hao, S.-Y. Lou, S.-M. Zhou, R.-J. Yuan, G.-Y. Zhu, N. Li, Nanoscale Res. Lett. 7(1), 100 (2012)
M.A. Ruderman, C. Kittel, Phys. Rev. 96, 99–102 (1954)
T. Kasuya, Prog. Theor. Phys. 16, 45–57 (1956)
K. Yoshida, Phys. Rev. 106, 893–898 (1957)
B. Babić-Stojić, D. Milivojević, J. Blanuša, V. Spasojević, N. Bibić, B. Simonović, D. Arandelović, J. Phys. Condens. Matter 20, 235217/1–235217/8 (2008)
L.B. Duan, G.H. Rao, Y.C. Wang, J. Yu, T. Wang, J. Appl. Phys. 104, 013909/1–013909/5 (2008)
J.M.D. Coey, M. Venkatesan, C.B. Fitzgerald, Nat. Mater. 4, 173–179 (2005)
T. Yang, Y. Li, M.Y. Zhu, Y.B. Li, J. Huang, H.M. Jin, Y.M. Hu, Mater. Sci. Eng. B. 170, 129–132 (2010)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ali Fatima, A., Devadason, S. & Mahalingam, T. Structural, luminescence and magnetic properties of Mn doped ZnO thin films using spin coating technique. J Mater Sci: Mater Electron 25, 3466–3472 (2014). https://doi.org/10.1007/s10854-014-2040-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-014-2040-x