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Bifacial illuminated PbS quantum dot-sensitized solar cells with translucent CuS counter electrodes

  • Yongguang Tu
  • Jihuai Wu
  • Zhang Lan
  • Yibing Lin
  • Qin Liu
  • Bingcheng Lin
  • Guozhang Liu
Article

Abstract

This paper reports the optimization of the TiO2 photoanode and the fabrication of bifacial illuminated PbS quantum dot-sensitized solar cells (QDSSCs) with translucent CuS counter electrodes. TiO2 photoanode is prepared by introducing a compact TiO2 layer between FTO substrate and TiO2 film with titanium diisopropoxide bis(acetylacetonate) in 1-butanol and post-treatment with TiCl4 aqueous solution; then, PbS quantum dots (QDs) are deposited on the surface of TiO2 film by successive ionic layer adsorption and reaction method; also, by means of control of the TiO2 surface charge, QD density of TiO2 film is improved by adding triethanolamine into the cationic precursor solution. Using this optimized TiO2 photoanode and a translucent CuS counter electrode, a bifacial illuminated PbS QDSSC is fabricated. The preparation conditions are optimized and the surface morphology and electrochemical properties of TiO2 photoanodes are characterized. The bifacial illuminated PbS QDSSC achieves a power conversion efficiency of 2.16 %, which is increased by 48.97 % compared with the single illuminated QDSSC.

Keywords

TiO2 TiO2 Film Power Conversion Efficiency Electrochemical Impedance Spectroscopic Mesoporous TiO2 Film 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

The authors acknowledge the financial joint support by the National Natural Science Foundation of China (Nos. 90922028, U1205112, 50842027, 61306077) and the specialized research fund for the doctoral program of Higher University, Ministry of Education, China (No. 20123501110001).

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Yongguang Tu
    • 1
  • Jihuai Wu
    • 1
  • Zhang Lan
    • 1
  • Yibing Lin
    • 1
  • Qin Liu
    • 1
  • Bingcheng Lin
    • 1
  • Guozhang Liu
    • 1
  1. 1.Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Institute of Materials Physical ChemistryHuaqiao UniversityXiamenPeople’s Republic of China

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