Enhanced photocatalytic activity of BiFeO3 particles by surface decoration with Ag nanoparticles

  • L. J. Di
  • H. Yang
  • G. Hu
  • T. Xian
  • J. Y. Ma
  • J. L. Jiang
  • R. S. Li
  • Z. Q. Wei


BiFeO3 particles with different morphologies and sizes were synthesized via a hydrothermal process, where the morphology and size was tailored by using different KOH concentrations in precursor solution. The samples prepared at n(KOH) = 3, 4.5, 6, and 7.5 M are composed, respectively, of octahedron-shaped particles (500–600 nm), cube-like particles (200–500 nm), irregular spherical agglomerates (9–16 μm) formed from disk-like grains with diameter of 1.4–2.8 μm and thickness of 0.2 μm, and cuboid-shaped particles with length-to-width ratio of 1.4:1–3.5:1 and width size ranging from 80 to 280 nm. Ag nanoparticles were deposited on the surface of BiFeO3 particles by a chemical reduction method to produce Ag@BiFeO3 nanocomposites. The photocatalytic activity of prepared samples was evaluated by degrading rhodamine B under simulated sunlight irradiation. It is demonstrated that Ag-decorated BiFeO3 particles exhibit an enhanced photocatalytic activity compared to bare BiFeO3 particles. This can be explained by the effective transfer of photogenerated electrons from the conduction band of BiFeO3 to Ag nanoparticles and hence increased availability of holes for the photocatalytic reaction. Hydroxyl radicals were detected by the photoluminescence technique using terephthalic acid as a probe molecule and are found to be produced over the irradiated BiFeO3 and Ag@BiFeO3 photocatalysts; especially, an enhanced yield is observed for the latter.


Photocatalytic Activity BiFeO3 Simulated Sunlight Visible Diffuse Reflectance Spectrum Simulated Sunlight Irradiation 
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This work was supported by the National Natural Science Foundation of China (Grant No. 51262018) and the Hongliu Outstanding Talents Foundation of Lanzhou University of Technology (Grant No. J201205).


  1. 1.
    A. Mills, R.H. Davies, D. Worsley, Chem. Soc. Rev. 22, 417 (1993)CrossRefGoogle Scholar
  2. 2.
    M.R. Hoffmann, S.T. Martin, W. Choi, D.W. Bahemann, Chem. Rev. 95, 69 (1995)CrossRefGoogle Scholar
  3. 3.
    C. Tabares-Munoz, J.P. Rivera, A. Monnier, H. Schmid, Jpn. J. Appl. Phys. 24, 1051 (1985)CrossRefGoogle Scholar
  4. 4.
    P. Fischer, M. Polomska, I. Sosnowska, M. Szymanski, J. Phys. C 13, 1931 (1980)CrossRefGoogle Scholar
  5. 5.
    J. Wang, J.B. Neaton, H. Zheng, V. Nagarajan, S.B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D.G. Schlom, U.V. Waghmare, N.A. Spaldin, K.M. Rabe, M. Wuttig, R. Ramesh, Science 299, 1719 (2003)CrossRefGoogle Scholar
  6. 6.
    T. Soltani, M.H. Entezari, Ultrason. Sonochem. 20, 1245 (2013)CrossRefGoogle Scholar
  7. 7.
    J. Wei, H.Y. Li, S.C. Mao, C. Zhang, Z. Xu, B. Dkhil, J. Mater. Sci. Mater. Electron. 23, 1869 (2012)CrossRefGoogle Scholar
  8. 8.
    J. He, R.Q. Guo, L. Fang, W. Dong, F.G. Zheng, M.R. Shen, Mater. Res. Bull. 48, 3017 (2013)CrossRefGoogle Scholar
  9. 9.
    S. Li, Y.H. Lin, B.P. Zhang, Y. Wang, C.W. Nan, J. Phys. Chem. C 114, 2903 (2010)CrossRefGoogle Scholar
  10. 10.
    F. Gao, X.Y. Chen, K.B. Yin, S.A. Dong, Z.F. Ren, F. Yuan, T. Yu, Z.G. Zou, J.M. Liu, Adv. Mater. 19, 2889 (2007)CrossRefGoogle Scholar
  11. 11.
    S. Li, J.M. Zhang, M.G. Kibria, Z. Mi, M. Chaker, D.L. Ma, R. Nechache, F. Rosei, Chem. Commun. 49, 5856 (2013)CrossRefGoogle Scholar
  12. 12.
    A.P. Zhang, J.Z. Zhang, J. Alloys Compd. 491, 631 (2010)CrossRefGoogle Scholar
  13. 13.
    R. Adhikari, S. Malla, G. Gyawali, T. Sekino, S.W. Lee, Mater. Res. Bull. 48, 3367 (2013)CrossRefGoogle Scholar
  14. 14.
    C.L. Yu, K. Yang, W.Q. Zhou, Q.Z. Fan, L.F. Wei, J.C. Yu, J. Phys. Chem. Solids 74, 1714 (2013)CrossRefGoogle Scholar
  15. 15.
    G.L. Newton, J.R. Milligan, Radiat. Phys. Chem. 75, 473 (2006)CrossRefGoogle Scholar
  16. 16.
    E. Shi, C.R. Cho, M.S. Jang, S.Y. Jeong, H.J. Kim, J. Mater. Res. 9, 2914 (1994)CrossRefGoogle Scholar
  17. 17.
    S.J. Clark, J. Robertson, Appl. Phys. Lett. 90, 132903 (2007)CrossRefGoogle Scholar
  18. 18.
    K. Takahashi, N. Kida, M. Tonouchi, Phys. Rev. Lett. 96, 117402 (2006)CrossRefGoogle Scholar
  19. 19.
    J. Zhang, M.A. Gondal, W. Wei, T.N. Zhang, Q.Y. Xu, K. Shen, J. Alloys Compd. 530, 107 (2012)CrossRefGoogle Scholar
  20. 20.
    J. He, R.Q. Guo, L.A. Fang, W. Dong, F.G. Zheng, M.R. Shen, Mater. Res. Bull. 48, 3017 (2013)CrossRefGoogle Scholar
  21. 21.
    P. Kamat, J. Phys. Chem. C 111, 2834 (2007)CrossRefGoogle Scholar
  22. 22.
    Y.L. Zhang, A.M. Schultz, P.A. Salvador, G.S. Rohrer, J. Mater. Chem. 21, 4168 (2011)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • L. J. Di
    • 2
  • H. Yang
    • 1
    • 2
  • G. Hu
    • 3
  • T. Xian
    • 1
    • 2
  • J. Y. Ma
    • 1
  • J. L. Jiang
    • 2
  • R. S. Li
    • 2
  • Z. Q. Wei
    • 1
    • 2
  1. 1.State Key Laboratory of Gansu Advanced Non-ferrous Metal MaterialsLanzhou University of TechnologyLanzhouPeople’s Republic of China
  2. 2.School of ScienceLanzhou University of TechnologyLanzhouPeople’s Republic of China
  3. 3.Chengdu Compressor PlantCNPC Jichai Power Equipment CompanyChengduPeople’s Republic of China

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