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Preparation, characterization and dielectric properties of Ba3−xSrxLiM3Ti5O21[M=Nb and Ta, x = 0 to 3] ceramics

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Abstract

The ceramic compositions Ba3−xSrxLiM3Ti5O21[M=Nb and Ta, x = 0 to 3] were prepared through conventional solid state ceramic route. A detailed study has been carried out to correlate the structure of Ba3−xSrxLiM3Ti5O21[M=Nb and Ta, x = 0 to 3] with respect to their dielectric properties. The structure and microstructure of ceramic samples were studied using powder X-ray diffractometer and Scanning Electron Microscopic techniques. The dielectric properties of the sintered ceramic compacts have been studied. The Ba-rich compositions were identified as promising candidates for high frequency applications whereas the Sr-rich compositions were excellent ionic conductors and can be commercially exploited for applications in solid-state batteries.

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References

  1. W.D. Kingery, Introduction to Ceramics, 227 (John Wiley, New York, 1976)

    Google Scholar 

  2. N. Ichinose, Introduction to Fine ceramics: applications in Engineering (John Wiley and sons Ltd, New York, 1987)

    Google Scholar 

  3. A.J. Moulson, M. Herbert, Electronics ceramics: Properties, Devices and Applications (Chapman and Hall, London, 1990)

    Google Scholar 

  4. R. Ratheesh, H. Sreemoolanadhan, M.T. Sebastian, P. Mohanan, Ferroelectrics 211, 1 (1998)

    Article  CAS  Google Scholar 

  5. S. Nomura, K.Toyama, K. Kaneta, Jpn. J. Appl. Phys. 21, L624 (1982)

  6. S.B. Desu, H.M.O. Bryan, J. Am. Cearm. Soc 68, 546 (1985)

    Article  CAS  Google Scholar 

  7. S. Kawashima, M. Nishida, I. Ueda, H. Ouchi, J. Am. Ceram. Soc. 66, 421 (1983)

    Article  CAS  Google Scholar 

  8. R. Ratheesh, M.T. Sebastian, M.E. Tobar, J. Harnett, D.G. Blair, J. Phys D32, 2821 (1999)

    Google Scholar 

  9. K. Wakino, M. Murata, H. Tamula, J. Am. Ceram. Soc. 69, 34 (1986)

    Article  CAS  Google Scholar 

  10. R.C. Kell, A.C. Greenham, G.C.S. Olds, J. Am. Cearm. Soc 56(7), 352 (1973)

    Article  CAS  Google Scholar 

  11. K. Mizumoto, S. Hayashi, J. Cera. Soc. Jap 127, 241 (2000)

    CAS  Google Scholar 

  12. V. Thangadurai, A.K. Shukla, J. Gopalakrishnan, Chem. Mater 11, 835 (1999)

    Article  CAS  Google Scholar 

  13. J.A. Alonso, J. Sanz, J. Santamaria, C. Leon, A. Varez, M.T. Fernandez-Diaz Angew. Chem., Int. Ed. Engl., 39, 619 (2000)

  14. B.W. Hakki, P.D. Coleman, IRE Trans. Microwave Theory & Tech 8, 402 (1960)

    Article  Google Scholar 

  15. L. Sebastian, A.K. Sukla, J. Gopalakrishnan, Proc. Indian Acad. Sci (Chem. Sci.) 113(5–6), 427 (2001)

    Google Scholar 

  16. J.L. Forqquet, H. Duroy, M.P. Crosnier-Lopez, J. Solid State Chem. 127, 283 (1996)

    Article  Google Scholar 

Download references

Acknowledgment

The authors are thankful to Dr. K.R.Dayas, Director, C-MET, Thrissur for extending the facilities to carry out this work.

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Correspondence to R. Ratheesh.

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Dhanya, T.P., Simna, P.S. & Ratheesh, R. Preparation, characterization and dielectric properties of Ba3−xSrxLiM3Ti5O21[M=Nb and Ta, x = 0 to 3] ceramics. J Mater Sci: Mater Electron 22, 974–977 (2011). https://doi.org/10.1007/s10854-010-0246-0

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  • DOI: https://doi.org/10.1007/s10854-010-0246-0

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