Abstract
We study the distributions of conduction band and valence band electronic states associated with hydrogenated amorphous silicon. We find that there are substantial deviations from square-root distributions of electronic states, particularly deep within the bands and within the gap region. We clearly identify where these distributions of electronic states exhibit square-root functional dependencies by fitting square-root functional forms to some experimental data. The corresponding DOS effective masses are determined, and are found to be about 2 to 4 times greater than the crystalline silicon case.
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References
R. A. Street, „Hydrogenated Amorphous Silicon“ (Cambridge, New York, 1991).
M. H. Cohen, H. Fritzsche and S. R. Ovshinsky, Phys. Rev. Lett. 22 (1969) 1065.
J. Tauc, R. Grigorovici and A. Vancu, Phys. Stat. Sol. 15 (1966) 627.
D. T. Pierce and W. E. Spicer, Phys. Rev. B 5 (1972) 3017.
L. Ley, S. Kowalczyk, R. Pollak and D. A. Shirley, Phys. Rev. Lett. 29 (1972) 1088.
W. B. Jackson, S.-J. Oh, C. C. Tsai and J. W. Allen, Phys. Rev. Lett. 53 (1984) 1481.
D. Redfield, Solid State Commun. 44 (1982) 1347.
S. Sherman, S. Wagner and R. A. Gottscho, Appl. Phys. Lett. 69 (1996) 3242.
T. Tiedje, J. M. Cebulka, D. L. Morel and B. Abeles, Phys. Rev. Lett. 46 (1981) 1425.
R. Brüggemann and G. H. Bauer, J. Non-Cryst. Solids 227–230 (1998) 197.
M. Brinza, G. J. Adriaenssens, K. Iakoubovskii, A. Stesmans, W. M. M. Kessels, A. H. M. Smets and M. C. M. van de Sanden, J. Non-Cryst. Solids. 299–302 (2002) 420.
K. Winer and L. Ley, Phys. Rev. B 36 (1987) 6072.
K. Winer, I. Hirabayashi and L. Ley, Phys. Rev. Lett. 60 (1988) 2697.
E. O. Kane, Phys. Rev. 131 (1963) 79.
B. I. Halperin and M. Lax, Phys. Rev. 148 (1966) 722.
S. John, C. Soukoulis, M. H. Cohen and E. N. Economou, Phys. Rev. Lett. 57 (1986) 1777.
S. K. O’Leary, S. Zukotynski and J. M. Perz, Phys. Rev. B 51 (1995) 4143.
S. K. O’Leary and P. K. Lim, J. Appl. Phys. 82 (1997) 3624.
D. P. Webb, X. C. Zou, Y. C. Chan, Y. W. Lam, S. H. Lin, X. Y. Lin, K. X. Lin, S. K. O’Leary and P. K. Lim, Solid State Commun. 105 (1998) 239.
W. B. Jackson, S. M. Kelso, C. C. Tsai, J. W. Allen and S.-J. Oh, Phys. Rev. B 31 (1985) 5187.
The data of Jackson et al.[20] is from Figure 8 of Jackson et al. [20].
S. M. Malik and S. K. O’Leary, J. Non-Cryst. Solids 336 (2004) 64.
S. K. O’Leary, Appl. Phys. Lett. 72 (1998) 1332.
L. Jiao, I. Chen, R. W. Collins, C. R. Wronski and N. Hata, Appl. Phys. Lett. 72 (1998) 1057.
While band structures, in the crystalline sense, do not exist for the case of amorphous semiconductors, the effects of non-parabolicity are still felt in amorphous semiconductors.
It should be noted, however, that Singh[20] has formulated an effective mass formalism for the case of amorphous semiconductors.
J. Singh, J. Mater. Sci.: Mater. Electron. 14 (2003) 171.
D. A. Neamen, „Semiconductor Physics and Devices“ (Irwin, Boston, 1992).
G. D. Cody, in „Hydrogenated Amorphous Silicon, Vol. 21B of Semiconductors and Semimetals,“ edited by J. I. Pankove (Academic, New York, 1984) p. 11.
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Malik, S.M., O’Leary, S.K. An analysis of the distributions of electronic states associated with hydrogenated amorphous silicon. J Mater Sci: Mater Electron 16, 177–181 (2005). https://doi.org/10.1007/s10854-005-6598-1
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DOI: https://doi.org/10.1007/s10854-005-6598-1