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EDTA-functionalized metal–organic framework of TMU-16-NH2 decorated with Pd nanoparticles as an efficient and effective nanocatalyst in the Suzuki – Miyaura coupling reaction

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Abstract

Strengthening the interaction between the substrate and the expensive transition metals such as palladium and increasing the capability of supporting in order to suppress the possibility of metal leaching from the surface is a very serious challenge in the design of a new heterogeneous catalyst. In this work, we develop the covalent functionalization of carboxylic ligand, ethylenediaminetetraacetic acid (EDTA), on the surface of the metal–organic framework of TMU-16-NH2, resulting in unparallel adsorptive ability for supporting Pd2+. The catalytic activity and stability of the synthesized catalyst named TMU-16-NH2-EDTA@Pd were studied in the Suzuki coupling reaction. We indicated that functionalization with EDTA plays a crucial role in boosting the adsorption capability of Pd and subsequently catalytic performance. The catalyst showed good reusability and has a nature truly heterogeneous due to the negligible leaching of palladium from the TMU-16-NH2-EDTA@Pd surface.

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The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Acknowledgements

We would like to thank the University of Mazandaran for financial support (Research Council Grant).

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Authors and Affiliations

  1. Faculty of Chemistry, University of Mazandaran, Babolsar, Mazandaran, Iran

    Afshin Amani Gharanjik, Heshmatollah Alinezhad & Ameneh Kiani

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  1. Afshin Amani Gharanjik
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HA supported the expenses including the preparation of materials and analysis in the article. HA, and AK conceived the presented idea and contributed to the data curation, methodology, and validation. AA carried out the experiment. All authors reviewed the results and approved the final version of the manuscript.

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Correspondence to Heshmatollah Alinezhad.

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Gharanjik, A.A., Alinezhad, H. & Kiani, A. EDTA-functionalized metal–organic framework of TMU-16-NH2 decorated with Pd nanoparticles as an efficient and effective nanocatalyst in the Suzuki – Miyaura coupling reaction. J Mater Sci 59, 8169–8185 (2024). https://doi.org/10.1007/s10853-024-09681-7

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