Abstract
Flame retardant is essential for cotton fabric because of the restrictions in applications caused by poor flammability. Herein, a novel flame-retardant coating assembled on the surface of cotton fabric consists of polyethyleneimine/g-C3N4 and polyethyleneimine/phytic acid as the underlying insulating coating and the upper intumescent coating, respectively. Different amounts of the composite coatings were deposited onto the fabric by the layer-by-layer self-assembled technique. The char residue of TGA over 20 wt% has indicated the significantly enhanced performance of the thermal stability of all the coated samples and the achievement of the samples with composite coatings in a self-extinguished level proving through vertical combustion test. The samples prepared with binary hybrid coatings exhibited a high limiting oxygen index value of 30.5%. From the MCC test, the peak heat release rate and total heat release of (P/G + P/PA)4+4 showed a significant decrease of 76.9% and 77.1%, respectively. All these results demonstrated that the composite coatings endowed the cotton fabric with outstanding thermal stability and flame retardancy.
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References
Alongi J, Carosio F, Malucelli G (2014) Polym Degrad Stab 106:138–149. https://doi.org/10.1016/j.polymdegradstab.2013.07.012
Ammayappan L, Nayak LK, Ray DP, Das S, Roy AK (2013) J Nat Fibers 10:390–413. https://doi.org/10.1080/15440478.2013.824849
Li SH, Huang JY, Chen Z, Chen GQ, Lai YK (2017) J Mater Chem A 5:31–55. https://doi.org/10.1039/c6ta07984a
Weil ED (2011) J Fire Sci 29:259–296. https://doi.org/10.1177/0734904110395469
Norouzi M, Zare Y, Kiany P (2015) Polym Rev 55:531–560. https://doi.org/10.1080/15583724.2014.980427
Malucelli G, Carosio F, Alongi J, Fina A, Frache A, Camino G (2014) Mater Sci Eng R Rep 84:1–20. https://doi.org/10.1016/j.mser.2014.08.001
Holder KM, Smith RJ, Grunlan JC (2017) J Mater Sci 52:12923–12959. https://doi.org/10.1007/s10853-017-1390-1
Qiu X, Li Z, Li X, Zhang Z (2018) Chem Eng J 334:108–117. https://doi.org/10.1016/j.cej.2017.09.194
Li YC, Schulz J, Grunlan JC (2009) ACS Appl Mater Interfaces 1:2338–2347. https://doi.org/10.1021/am900484q
An Q, Huang T, Shi F (2018) Chem Soc Rev 47:5529. https://doi.org/10.1039/c8cs90072h
Carosio F, Laufer G, Alongi J, Camino G, Grunlan JC (2011) Polym Degrad Stab 96:745–750. https://doi.org/10.1016/j.polymdegradstab.2011.02.019
Chang S, Slopek RP, Condon B, Grunlan JC (2014) Ind Eng Chem Res 53:3805–3812. https://doi.org/10.1021/ie403992x
Costes L, Laoutid F, Brohez S, Dubois P (2017) Mater Sci Eng R-Rep 117:1–25. https://doi.org/10.1016/j.mser.2017.04.001
Lin D, Zeng X, Li H, Lai X (2018) Cellulose 25:3135–3149. https://doi.org/10.1007/s10570-018-1748-9
Idumah CI, Hassan A, Affam AC (2015) Rev Chem Eng 31:149–177. https://doi.org/10.1515/revce-2014-0038
Liu L, Huang Z, Pan Y, Wang X, Song L, Hu Y (2018) Cellulose 25:4791–4803. https://doi.org/10.1007/s10570-018-1866-4
Li S, Ding F, Lin X, Li Z, Ren X (2019) Fibers Polym 20:538–544. https://doi.org/10.1007/s12221-019-8914-z
Zhang Y, Tian W, Liu L et al (2019) Chem Eng J 372:1077–1090. https://doi.org/10.1016/j.cej.2019.05.012
Dasari A, Yu Z-Z, Cai G-P, Mai Y-W (2013) Prog Polym Sci 38:1357–1387. https://doi.org/10.1016/j.progpolymsci.2013.06.006
Lim KS, Bee ST, Sin LT et al (2016) Compos Pt B-Eng 84:155–174. https://doi.org/10.1016/j.compositesb.2015.08.066
Li YC, Mannen S, Morgan AB et al (2011) Adv Mater 23:3926–3931. https://doi.org/10.1002/adma.201101871
Shi X-H, Xu Y-J, Long J-W et al (2018) Chem Eng J 353:550–558. https://doi.org/10.1016/j.cej.2018.07.146
Pan H, Wang W, Pan Y et al (2015) Cellulose 22:911–923. https://doi.org/10.1007/s10570-014-0536-4
Laufer G, Kirkland C, Cain AA, Grunlan JC (2012) ACS Appl Mater Interfaces 4:1643–1649. https://doi.org/10.1021/am2017915
Koklukaya O, Carosio F, Wagberg L (2017) ACS Appl Mater Interfaces 9:29082–29092. https://doi.org/10.1021/acsami.7b08018
Huang G, Yang J, Gao J, Wang X (2012) Ind Eng Chem Res 51:12355–12366. https://doi.org/10.1021/ie301911t
Chai B, Yan J, Wang C, Ren Z, Zhu Y (2017) Appl Surf Sci 391:376–383. https://doi.org/10.1016/j.apsusc.2016.06.180
Jiang L, Yuan X, Pan Y et al (2017) Appl Catal B 217:388–406. https://doi.org/10.1016/j.apcatb.2017.06.003
Zhang J, Chen X, Takanabe K et al (2010) Angew Chem 49:441–444. https://doi.org/10.1002/anie.200903886
Fan Y, Zhou J, Zhang J et al (2018) Chem Phys Lett 699:146–154. https://doi.org/10.1016/j.cplett.2018.03.048
Wang Y, Ding X, Zhang P et al (2019) Ind Eng Chem Res 58:3978–3987. https://doi.org/10.1021/acs.iecr.8b05509
Luo B, Song R, Jing D (2017) Int J Hydrog Energy 42:23427–23436. https://doi.org/10.1016/j.ijhydene.2017.03.001
Fang H-B, Zhang X-H, Wu J, Li N, Zheng Y-Z, Tao X (2018) Appl Catal B 225:397–405. https://doi.org/10.1016/j.apcatb.2017.11.080
Guo S, Deng Z, Li M et al (2016) Angew Chem 55:1830–1834. https://doi.org/10.1002/anie.201508505
Zhang W, Fu Y, Liu W, Lim L, Wang X, Yu A (2019) Nano Energy 57:48–56. https://doi.org/10.1016/j.nanoen.2018.12.005
Zhao ZW, Sun YJ, Dong F (2015) Nanoscale 7:15–37. https://doi.org/10.1039/c4nr03008g
Shi Y, Wang B, Duan L et al (2016) Ind Eng Chem Res 55:7646–7654. https://doi.org/10.1021/acs.iecr.6b01237
Li R, Ren Y, Zhao P, Wang J, Liu J, Zhang Y (2019) J Hazard Mater 365:606–614. https://doi.org/10.1016/j.jhazmat.2018.11.033
Shi Y, Long Z, Yu B et al (2015) J Mater Chem A 3:17064–17073. https://doi.org/10.1039/c5ta04349b
Shi Y, Xing W, Wang B et al (2016) Mater Chem Phys 177:283–292. https://doi.org/10.1016/j.matchemphys.2016.04.029
Shi Y, Gui Z, Yu B, Yuen RKK, Wang B, Hu Y (2015) Compos B Eng 79:277–284. https://doi.org/10.1016/j.compositesb.2015.04.046
Zhu B, Xia P, Ho W, Yu J (2015) Appl Surf Sci 344:188–195. https://doi.org/10.1016/j.apsusc.2015.03.086
Zhu J, Xiao P, Li H, Carabineiro SA (2014) ACS Appl Mater Interfaces 6:16449–16465. https://doi.org/10.1021/am502925j
Yuan Y-P, Cao S-W, Liao Y-S, Yin L-S, Xue C (2013) Appl Catal B 140–141:164–168. https://doi.org/10.1016/j.apcatb.2013.04.006
Carosio F, Fontaine G, Alongi J, Bourbigot S (2015) ACS Appl Mater Interfaces 7:12158–12167. https://doi.org/10.1021/acsami.5b02507
Carosio F, Alongi J, Malucelli G (2012) Carbohyd Polym 88:1460–1469. https://doi.org/10.1016/j.carbpol.2012.02.049
Wang Y, Ding X, Chen X et al (2017) Cellulose 24:4569–4580. https://doi.org/10.1007/s10570-017-1445-0
New J, Zope IS, Abdul Rahman SN, Yap XLW, Dasari A (2016) Mater Design 89:413–420. https://doi.org/10.1016/j.matdes.2015.10.006
Zhang T, Yan H, Shen L et al (2014) Ind Eng Chem Res 53:19199–19207. https://doi.org/10.1021/ie503421f
Xue B, Chen Y, Hong Y, Ma DY, Xu J, Li YX (2018) Chin J Catal 39:1263–1271. https://doi.org/10.1016/s1872-2067(18)63063-3
Pan Y, Liu L, Zhang Y et al (2019) Carbohyd Polym 206:396–402. https://doi.org/10.1016/j.carbpol.2018.11.037
Pan H, Wang W, Pan Y, Song L, Hu Y, Liew KM (2015) Carbohyd Polym 115:516–524. https://doi.org/10.1016/j.carbpol.2014.08.084
Wang W, Guo J, Liu X et al (2020) Cellulose 27:5377–5389. https://doi.org/10.1007/s10570-020-03140-7
Pan Y, Zhan J, Pan H et al (2016) ACS Sustain Chem Eng 4:1431–1438
Wang J, He J, Ma L et al (2020) Chem Eng J 390:124508
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This work is supported by the ministry of education of China and the Gansu Provincial Development and Reform Commission.
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Ma, Z., Zhang, Z. & Wang, Y. A novel efficient nonflammable coating containing g-C3N4 and intumescent flame retardant fabricated via layer-by-layer assembly on cotton fiber. J Mater Sci 56, 9678–9691 (2021). https://doi.org/10.1007/s10853-021-05877-3
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DOI: https://doi.org/10.1007/s10853-021-05877-3