Abstract
TiNbf/TiAl composite has enormous potential to serve on advanced aerospace equipment, but brittle reaction products limit the further improvement of overall toughness; meanwhile, the types and contents of interface reaction products remain controversial. This study is to clarify the evolution process of interface reaction structure in TiNbf/TiAl composite and explain it from the perspective of thermodynamics. This study discovered that brittle interface can transform into a relatively ductile interface containing two kinds of α2/γ lamella colonies above the transition temperature of 1200 °C. The relative sizes of γ and α2 lamella thickness varied in two different lamellar colonies. Above 1200 °C, recrystallization process at the boundary of original TiAl particles was completed and all defects were eliminated completely either. Gibbs free energy (ΔG) of every phase (γ, α2, β and other generated intermetallics) calculated based on element distribution model is consistent with the experiment results well. Micromechanical properties tested by nanoindentation suggest that the interface in the form of lamella colonies had relieved variation amplitudes of reduced modulus Er and hardness H across the interface region which may show beneficial influences on improving toughness of TiNbf/TiAl composite.
Similar content being viewed by others
References
Kartavykh AV, Kaloshkin SD, Cherdyntsev VV, Gorshenkov MV, Sviridova TA, Borisova YV, Senatov FS, Maksimkin AV (2013) Application of microstructured intermetallides in turbine manufacture part 1: present state and prospects (a review). Inorgan Mater Appl Res 4:12–20
Clemens H, Mayer S (2013) Design, processing, microstructure, properties, and applications of advanced intermetallic TiAl alloys. Adv Eng Mater 15(4):191–215
Zan X, He YH, Wang Y, Lu ZX, Xia YM (2010) Tensile impact behavior and deformation mechanism of duplex TiAl intermetallics at elevated temperatures. J Mater Sci 45:6446–6454. https://doi.org/10.1007/s10853-010-4730-y
Sun ZM, Kobayashi T, Fukumasu H, Yamamoto I, Shibue K (1998) Tensile properties and fracture toughness of a Ti-45Al-1.6Mn alloy at loading velocities of up to 12 m/s. Metall Mater Trans A 29:263–277
Kim YW, Kim SL (2018) Advances in gammalloy materials-processes-application technology: successes, dilemmas, and future. J Miner Met Mater Soc 70(4):553–560
Wang Q, Ding HS, Zhang HL, Chen RR, Guo JJ, Fu HZ (2018) Influence of Mn addition on the microstructure and mechanical properties of a directionally solidified γ-TiAl alloy. Mater Charact 137:133–141
Loretto MH, Wu Z, Chu MQ, Saage H, Hu D, Attallah MM (2012) Deformation of microstructurally refined cast Ti46Al8Nb and Ti46Al8Ta. Intermetallics 23:1–11
Chen G, Peng YB, Zheng GZ, Qi ZX, Wang MZ, Yu HC, Dong CL, Liu CT (2016) Polysynthetic twinned TiAl single crystals for high-temperature applications. Nat Mater 15:876–881
Yu WB, Zhu K, Aman Y, Guo ZP, Xiong SM (2016) Bio-inspired design of SiCf reinforced multi layered Ti intermetallic composite. Mater Des 101:102–108
Vecchio KS, Jiang FC (2016) Fracture toughness of Ceramic-fiber-reinforced metallic-intermetallic-laminate (CFR-MIL) composites. Mater Sci Eng A 649:407–416
Yu WB, Zhu K, Aman Y, Guo ZP, Xiong SM (2016) Bio-inspired design of SiCf-reinforced multi-layered Ti-intermetallic composite. Mater Des 101:102–108
Zhou Y, Wang Q, Han XL, Sun DL (2013) Fabrication and properties of continuous unidirectional Mo fiber reinforced TiAl composites by slurry casting and vacuum hot pressing. Compos Sci Technol 83:72–78
Zhou Y, Sun DL, Wang Q, Han XL (2013) Effect of fabrication parameters on the microstructure and mechanical properties of unidirectional Mo-fiber reinforced TiAl matrix composites. Mater Sci Eng A 575:21–29
Li JB, Liu B, Wang Y, Tang S, Liu Y, Lu XF (2018) A study on the Zener-Holloman parameter and fracture toughness of an Nb-particles-toughened TiAl–Nb alloy. Metals 8(287):1–13
Rao KTV, Ritchie RO (1992) Fatigue crack propagation resistance of ductile TiNb-reinforced γ-TiA1 intermetallic matrix composites. Mater Sci Eng A 153:479–485
Rao KTV, Ritchie RO (1998) High-temperature fracture and fatigue resistance of a ductile β-TiNb reinforced γ-TiAl intermetallic composite. Acta Mater 46:4167–4180
Zhu NX, Zhang TX, Cai XZ (1999) TiAl matrix composites toughened by Nb and TiNb continuous fibers. Rare Metal Mater Eng 28(1):56–59
Zhang ZB, Urbassek HM (2018) Indentation into an Al/Si composite: enhanced dislocation mobility at interface. J Mater Sci 53:799–813. https://doi.org/10.1007/s10853-017-1495-6
Chu JM, Claus B, Parab N, O’Brien D, Sun T, Fezzaa K, Chen W (2018) Visualization of dynamic fiber-matrix interfacial shear debonding. J Mater Sci 53:5845–5859. https://doi.org/10.1007/s10853-017-1759-1
Cao HC, Dalgleish BJ, Dève HE, Elliott C, Evans AG, Mehrabian R, Odette GR (1989) A test procedure for characterizing the toughening of brittle intermetallics by ductile reinforcements. Acta Metall 37(11):2969–2977
Schuster J, Palm M (2006) Reassessment of the binary Aluminum–Titanium phase diagram. J Phase Equilibr Diffus 27(3):255–277
Dève HE, Evans AG, Odette GR, Mehrabian R, Emiliani ML, Hecht RJ (1990) Ductile reinforcement toughening of γ-TiAl: Effects of debonding and ductility. Acta Metall Mater 38(8):1491–1502
Li Y, Chen C (2017) Polyaniline/carbon nanotubes-decorated activated carbon fiber felt as high-performance, free-standing and flexible supercapacitor electrodes. J Mater Sci 52:12348–12357. https://doi.org/10.1007/s10853-017-1291-3
Xiong SY, Qi WH, Huang BY, Wang MP, Li YJ (2010) Size and shape dependent Gibbs free energy and phase stability of titanium and zirconium nanoparticles. Mater Chem Phys 120(2–3):446–451
Witusiewicz VT, Bondar AA, Hecht U, Velikanova TY (2009) The Al–B–Nb–Ti system: IV experimental study and thermodynamic re-evaluation of the binary Al–Nb and ternary Al–Nb–Ti systems. J Alloys Comp 47:133–161
Jiang Y, Deng CP, He YH, Zhao Y, Xu NP, Zou J, Huang BY, Liu CT (2009) Reactive synthesis of microporous titanium-aluminide membranes. Mater Lett 63:22–24
Lyu SY, Sun YB, Ren L, Xiao WL, Ma CL (2017) Simultaneously achieving high tensile strength and fracture toughness of Ti/Ti-Al multilayered composites. Intermetallics 90:16–22
Appel F, Paul JDH, Oehring M, Fröbel U, Lorenz U (2003) Creep behavior of TiAl alloys with enhanced high-temperature capability. Metall Mater Trans A 34(10):2149–2164
Herzig C, Wilger T, Przeorski T, Hisker F, Divinski SV (2001) Titanium tracer diffusion in grain boundaries of α-Ti, α2-Ti3Al, and γ-TiAl and in α2/γ interphase boundaries. Intermetallics 9(5):431–442
Takeyama M, Ohmura Y, Kikuchi M, Matsuo T (1998) Phase equilibria and microstructural control of gamma TiAl based alloys. Intermetallics 6(7):643–646
Wang JN, Yang J, Wang Y (2005) Grain refinement of a Ti–47Al–8Nb–2Cr alloy through heat treatments. Scr Mater 52(4):329–334
Kartavykh AV, Asnis EA, Piskun NV, Statkevich II, Gorshenkov MV, Korotitskiy AV (2017) Room-temperature tensile properties of float-zone processed β-stabilized γ-TiAl (Nb, Cr, Zr) intermetallic. Mater Lett 188:88–91
Yan YQ, Zhang ZQ, Luo GZ, Wang KG, Zhou L (2000) Microstructures observation and hot compressing tests of TiAl based alloy containing high Nb. Mater Sci Eng A 280:187–191
Kaufman MJ, Konitzer DG, Shull RD, Fraser HL (1986) An analytical electron microscopy study of the recently reported “Ti2Al phase” in γ-TiAl alloys. Scr Metall 20(1):103–108
Vasudevan VK, Stucke MA, Court SA, Fraser HL (1989) The influence of second phase Ti3Al on the deformation mechanisms in TiAl. Philos Mag Lett 59(6):299–307
Acknowledgements
The authors acknowledge the sponsor of the National Natural Science Foundation of China (No. 51971176), the National Natural Science Foundation of China (No. 51774238) and the 2018 Joint Foundation of Ministry of Education for Equipment Pre-research (No. 6141A020332). We would like to thank the Analytical and Testing Center of Northwestern Polytechnical University for this paper.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflicts of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Li, J., Hu, R., Yang, J. et al. Evolution and micromechanical properties of interface structures in TiNbf/TiAl composites prepared by powder metallurgy. J Mater Sci 55, 12421–12433 (2020). https://doi.org/10.1007/s10853-020-04816-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-020-04816-y