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Boosting the performance of delafossite photocathode through constructing a CuFeO2/CuO heterojunction for photoelectrochemical water reduction

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Abstract

CuFeO2 is a promising photocathode material with favorable band gap and chemical stability in alkaline electrolytes. However, CuFeO2 is suffered from poor photoinduced electron–hole separation and collection. In this paper, we utilize a heterojunction strategy for inhibiting charge recombination and enhancing its photoelectrochemical performance. CuFeO2/CuO heterojunction photocathodes were prepared by a facile spin coating method, which were used for photoelectrochemical water reduction. A high photocurrent as much as 50 μA/cm2 after 600 s irradiation of white light at the potential of − 0.5 V versus Ag/AgCl electrode is observed, which is higher than those of the pure CuFeO2 and CuO photocathodes. The effect of the interfacial electric field on the behaviors of photoinduced charge carriers is studied. It is the interfacial electric field that extends the lifetime of photoinduced charge carriers and promotes the charge separation efficiency, which results high performance and good durability.

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References

  1. Grätzel M (2001) Photoelectrochemical cells. Nature 414:338

    Article  Google Scholar 

  2. Sivula K, van de Krol R (2016) Semiconducting materials for photoelectrochemical energy conversion. Nat Rev Mater 1:15010

    Article  CAS  Google Scholar 

  3. Tablero Crespo C (2018) Potentiality of CuFeO2-delafossite as a solar energy converter. Sol Energy 163:162–166. https://doi.org/10.1016/j.solener.2018.01.091

    Article  CAS  Google Scholar 

  4. Shannon RD, Prewitt CT, Rogers DB (1971) Chemistry of noble metal oxides. II. Crystal structures of platinum cobalt dioxide, palladium cobalt dioxide, copper iron dioxide, and silver iron dioxide. Inorg Chem 10:719–723. https://doi.org/10.1021/ic50098a012

    Article  CAS  Google Scholar 

  5. Kawazoe H, Yasukawa M, Hyodo H, Kurita M, Yanagi H, Hosono H (1997) P-type electrical conduction in transparent thin films of CuAlO2. Nature 389:939–942. https://doi.org/10.1038/40087

    Article  CAS  Google Scholar 

  6. Husek J, Cirri A, Biswas S, Asthagiri A, Baker LR (2018) Hole thermalization dynamics facilitate ultrafast spatial charge separation in CuFeO 2 solar photocathodes. J Phys Chem C 122:11300–11304. https://doi.org/10.1021/acs.jpcc.8b02996

    Article  CAS  Google Scholar 

  7. Hwang YJ, Boukai A, Yang P (2009) High density n-Si/n-TiO2 core/shell nanowire arrays with enhanced photoactivity. Nano Lett 9:410–415. https://doi.org/10.1021/nl8032763

    Article  CAS  Google Scholar 

  8. Zhang J, Song H, Xu R, Yan C, Wu Y (2018) The heterogeneous electrolyte of CuFeO2 nano-flakes composited with flower-shaped ZnO for advanced solid oxide fuel cells. China Eur Forum Adv Fuel Cell New Energy 43:12789–12796. https://doi.org/10.1016/j.ijhydene.2018.04.020

    Article  CAS  Google Scholar 

  9. Derbal A, Omeiri S, Bouguelia A, Trari M (2008) Characterization of new heterosystem CuFeO2/SnO2 application to visible-light induced hydrogen evolution. Int J Hydrog Energy 33:4274–4282. https://doi.org/10.1016/j.ijhydene.2008.05.067

    Article  CAS  Google Scholar 

  10. Oh Y, Yang W, Tan J, Lee H, Park J, Moon J (2018) Photoelectrodes based on 2D opals assembled from Cu-delafossite double-shelled microspheres for an enhanced photoelectrochemical response. Nanoscale 10:3720–3729. https://doi.org/10.1039/c7nr07351h

    Article  CAS  Google Scholar 

  11. Bera A, Deb K, Chattopadhyay KK, Thapa R, Saha B (2016) Mixed phase delafossite structured p type CuFeO2/CuO thin film on FTO coated glass and its Schottky diode characteristics. Microelectron Eng 162:23–26. https://doi.org/10.1016/j.mee.2016.04.020

    Article  CAS  Google Scholar 

  12. Kang U, Park H (2017) A facile synthesis of CuFeO2 and CuO composite photocatalyst films for the production of liquid formate from CO2 and water over a month. J Mater Chem A 5:2123–2131. https://doi.org/10.1039/c6ta09378g

    Article  CAS  Google Scholar 

  13. Prévot MS, Guijarro N, Sivula K (2015) Enhancing the performance of a robust sol–gel-processed p-type delafossite CuFeO2 photocathode for solar water reduction. Chemsuschem 8:1359–1367. https://doi.org/10.1002/cssc.201403146

    Article  CAS  Google Scholar 

  14. Kim M-G, Kim HS, Ha Y-G, He J, Kanatzidis MG, Facchetti A, Marks TJ (2010) High-performance solution-processed amorphous zinc–indium–tin oxide thin-film transistors. J Am Chem Soc 132:10352–10364. https://doi.org/10.1021/ja100615r

    Article  CAS  Google Scholar 

  15. Bisquert J (2002) Theory of the impedance of electron diffusion and recombination in a thin layer. J Phys Chem B 106:325–333. https://doi.org/10.1021/jp011941g

    Article  CAS  Google Scholar 

  16. Garcia-Belmonte G, Munar A, Barea EM, Bisquert J, Ugarte I, Pacios R (2008) Charge carrier mobility and lifetime of organic bulk heterojunctions analyzed by impedance spectroscopy. Org Electron 9:847–851. https://doi.org/10.1016/j.orgel.2008.06.007

    Article  CAS  Google Scholar 

  17. Ke W, Fang G, Wang J, Qin P, Tao H, Lei H, Liu Q, Dai X, Zhao X (2014) Perovskite solar cell with an efficient TiO2 compact film. ACS Appl Mater Interfaces 6:15959–15965. https://doi.org/10.1021/am503728d

    Article  CAS  Google Scholar 

  18. Liu Y, Sun X, Tai Q, Hu H, Chen B, Huang N, Sebo B, Zhao X (2011) Efficiency enhancement in dye-sensitized solar cells by interfacial modification of conducting glass/mesoporous TiO2 using a novel ZnO compact blocking film. J Power Sources 196:475–481. https://doi.org/10.1016/j.jpowsour.2010.07.031

    Article  CAS  Google Scholar 

  19. Duan S-F, Zhang Z-X, Geng Y-Y, Yao X-Q, Kan M, Zhao Y-X, Pan X-B, Kang X-W, Tao C-L, Qin D-D (2018) Brand new 1D branched CuO nanowire arrays for efficient photoelectrochemical water reduction. Dalton Trans 47:14566–14572. https://doi.org/10.1039/c8dt03013h

    Article  CAS  Google Scholar 

  20. Prevot MS, Li Y, Guijarro N, Sivula K (2016) Improving charge collection with delafossite photocathodes: a host-guest CuAlO2/CuFeO2 approach. J Mater Chem A 4:3018–3026. https://doi.org/10.1039/c5ta06336a

    Article  CAS  Google Scholar 

  21. Lin Y, Xu Y, Mayer MT, Simpson ZI, McMahon G, Zhou S, Wang D (2012) Growth of p-type hematite by atomic layer deposition and its utilization for improved solar water splitting. J Am Chem Soc 134:5508–5511. https://doi.org/10.1021/ja300319g

    Article  CAS  Google Scholar 

  22. Read CG, Park Y, Choi K-S (2012) Electrochemical synthesis of p-type CuFeO2 electrodes for use in a photoelectrochemical cell. J Phys Chem Lett 3:1872–1876. https://doi.org/10.1021/jz300709t

    Article  CAS  Google Scholar 

  23. Omeiri S, Bellal B, Bouguelia A, Bessekhouad Y, Trari M (2009) Electrochemical and photoelectrochemical characterization of CuFeO2 single crystal. J Solid State Electrochem 13:1395–1401. https://doi.org/10.1007/s10008-008-0703-3

    Article  CAS  Google Scholar 

  24. Paracchino A, Brauer JC, Moser J-E, Thimsen E, Graetzel M (2012) Synthesis and characterization of high-photoactivity electrodeposited Cu2O solar absorber by photoelectrochemistry and ultrafast spectroscopy. J Phys Chem C 116:7341–7350. https://doi.org/10.1021/jp301176y

    Article  CAS  Google Scholar 

  25. Das S, Saha S, Sen D, Ghorai UK, Banerjee D, Chattopadhyay KK (2014) Highly oriented cupric oxide nanoknife arrays on flexible carbon fabric as high performing cold cathode emitter. J Mater Chem C 2:1321–1330. https://doi.org/10.1039/c3tc31972e

    Article  CAS  Google Scholar 

  26. Ling T, Yan D-Y, Jiao Y, Wang H, Zheng Y, Zheng X, Mao J, Du X-W, Hu Z, Jaroniec M, Qiao S-Z (2016) Engineering surface atomic structure of single-crystal cobalt(II) oxide nanorods for superior electrocatalysis. Nat Commun 7:12876

    Article  CAS  Google Scholar 

  27. Wang D, Li R, Zhu J, Shi J, Han J, Zong X, Li C (2012) Photocatalytic water oxidation on BiVO4 with the electrocatalyst as an oxidation cocatalyst: essential relations between electrocatalyst and photocatalyst. J Phys Chem C 116:5082–5089. https://doi.org/10.1021/jp210584b

    Article  CAS  Google Scholar 

  28. Calva-Yáñez JC, de la Fuente MS, Ramírez-Vargas M, Rincón ME (2018) Photoelectrochemical performance and carrier lifetime of electrodes based on MWCNT-templated TiO2 nanoribbons. Mater Renew Sustain Energy 7:19. https://doi.org/10.1007/s40243-018-0126-8

    Article  Google Scholar 

  29. Sahare S, Salunkhe M, Ghoderao P, Bhave T (2018) Surfactant modified Bi2(S0.3Se0.7)3 nanoflakes for photo electrochemical cell application. J Mater Sci Mater Electron 29:9142–9154. https://doi.org/10.1007/s10854-018-8942-2

    Article  CAS  Google Scholar 

  30. Jiang C-M, Reyes-Lillo SE, Liang Y, Liu Y-S, Liu G, Toma FM, Prendergast D, Sharp ID, Cooper JK (2019) Electronic structure and performance bottlenecks of CuFeO2 photocathodes. Chem Mater 31:2524–2534. https://doi.org/10.1021/acs.chemmater.9b00009

    Article  CAS  Google Scholar 

  31. Sullivan I, Zoellner B, Maggard PA (2016) Copper(I)-based p-type oxides for photoelectrochemical and photovoltaic solar energy conversion. Chem Mater 28:5999–6016. https://doi.org/10.1021/acs.chemmater.6b00926

    Article  CAS  Google Scholar 

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Acknowledgements

For financial support, the authors are grateful to the National Natural Science Foundation of China (Grant No. 21673203), the Natural Science Foundation of Jiangsu Province (Grant No. BK20170486), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP).

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  1. School of Chemistry and Chemical Engineering, Yangzhou University, 180 Siwangting Road, Yangzhou, 225002, People’s Republic of China

    Tengfei Jiang, Yu Zhao & Huaiguo Xue

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  1. Tengfei Jiang
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  2. Yu Zhao
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  3. Huaiguo Xue
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Correspondence to Tengfei Jiang or Huaiguo Xue.

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Jiang, T., Zhao, Y. & Xue, H. Boosting the performance of delafossite photocathode through constructing a CuFeO2/CuO heterojunction for photoelectrochemical water reduction. J Mater Sci 54, 11951–11958 (2019). https://doi.org/10.1007/s10853-019-03747-7

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  • DOI: https://doi.org/10.1007/s10853-019-03747-7

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