Deposition-float-assembly formation mechanism of continuous hollow cylindrical carbon nanotube sock via floating catalyst chemical vapor deposition

Abstract

Hollow cylindrical carbon nanotube (CNT) sock was synthesized via floating catalyst chemical vapor deposition. The synthesis process was carried out in a horizontal furnace by injecting feedstock consisting of ethanol, ferrocene, thiophene, and deionized water into the alumina tube with argon as carrier gas. In order to investigate the formation mechanism of the hollow cylindrical CNT sock, the influence of the injection rate and C/Fe molar ratio of feedstock on the nucleation and growth of CNTs was discussed. The products were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and thermo-gravimetric analysis. The results showed that hollow cylindrical CNT sock was obtained when those two parameters were 30 ml h−1 and 523, respectively. A deposition-float-assembly (D-F-A) formation mechanism was proposed for the formation of CNTs sock. Firstly, the as-prepared CNTs were deposited on the inner surface of the alumina tube. Secondly, with the help of buoyant effect for Fe catalyst nanoparticles, CNTs floated in the alumina tube with longer length. The long CNTs were assembled into interconnected CNT membranes. The alumina tube was blocked by the accumulation of CNT membranes to form a self-closing system. The CNT sock was obtained by drawing out the block stably. The D-F-A formation mechanism is of great significance in the fabrication of the hollow cylindrical CNT sock.

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References

  1. 1

    Alemán B, Ranchal R, Reguero V, Mas B, Vilatela JJ (2017) Carbon nanotube fibers with martensite and austenite Fe residual catalyst: room temperature ferromagnetism and implications for CVD growth. J Mater Chem C 5:5544–5550

    Article  Google Scholar 

  2. 2

    Delord B, Neri W, Bertaux K, Derre A, Ly I, Mano N, Poulin P (2017) Carbon nanotube fiber mats for microbial fuel cell electrodes. Biores Technol 243:1227–1231

    Article  CAS  Google Scholar 

  3. 3

    Yuan Y, Liu Z, Zhang K, Han W, Chen J (2018) Nanoscale welding of multi-walled carbon nanotubes by 1064 nm fiber laser. Opt Laser Technol 103:327–329

    Article  CAS  Google Scholar 

  4. 4

    Zhang XS, Yang LW, Liu HT, Zu M (2018) Mechanical and electrical properties of direct spun carbon nanotube fibers exposed to ultrahigh temperatures in vacuum. J Nanosci Nanotechnol 18:4264–4269

    Article  CAS  Google Scholar 

  5. 5

    Zhang SC, Kang LX, Wang X, Tong LM, Yang LW, Wang ZQ, Qi K, Deng SB, Li QW, Bai XD, Ding F, Zhang J (2017) Arrays of horizontal carbon nanotubes of controlled chirality grown using designed catalysts. Nature 543:234–238

    Article  CAS  Google Scholar 

  6. 6

    Lee J, Oh E, Kim T, Sa JH, Lee SH, Park J, Moon D, Kang IS, Kim MJ, Kim SM, Lee KH (2015) The influence of boundary layer on the growth kinetics of carbon nanotube forests. Carbon 93:217–225

    Article  CAS  Google Scholar 

  7. 7

    Li QW, Zhang XF, DePaula RF, Zheng LX, Zhao YH, Stan L, Holesinger TG, Arendt PN, Peterson DE, Zhu YT (2006) Sustained growth of ultralong carbon nanotube arrays for fiber spinning. Adv Mater 18:3160–3163

    Article  CAS  Google Scholar 

  8. 8

    Lu Z, Chao Y, Ge Y, Foroughi J, Zhao Y, Wang C, Long H, Wallace GG (2017) High-performance hybrid carbon nanotube fibers for wearable energy storage. Nanoscale 9:5063–5071

    Article  CAS  Google Scholar 

  9. 9

    Kou L, Huang T, Zheng B, Han Y, Zhao X, Gopalsamy K, Sun H, Gao C (2014) Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics. Nat Commun 5:3754

    Article  CAS  Google Scholar 

  10. 10

    Allahbakhsh A, Bahramian AR (2015) Self-assembled and pyrolyzed carbon aerogels: an overview of their preparation mechanisms, properties and applications. Nanoscale 7:14139–14158

    Article  CAS  Google Scholar 

  11. 11

    Janas D, Koziol KK (2016) Carbon nanotube fibers and films: synthesis, applications and perspectives of the direct-spinning method. Nanoscale 8:19475–19490

    Article  CAS  Google Scholar 

  12. 12

    Xiang R, Hou B, Einarsson E, Zhao P, Harish S, Morimoto K, Miyauchi Y, Chiashi S, Tang Z, Maruyama S (2013) Carbon atoms in ethanol do not contribute equally to formation of single-walled carbon nanotubes. ACS Nano 7:3095–3103

    Article  CAS  Google Scholar 

  13. 13

    Ding F, Harutyunyan AR, Yakobson BI (2009) Dislocation theory of chirality-controlled nanotube growth. Proc Natl Acad Sci USA 106:2506–2509

    Article  Google Scholar 

  14. 14

    Liu B, Tang DM, Sun C, Liu C, Ren W, Li F, Yu WJ, Yin LC, Zhang L, Jiang C, Cheng HM (2011) Importance of oxygen in the metal-free catalytic growth of single-walled carbon nanotubes from SiO(x) by a vapor-solid-solid mechanism. J Am Chem Soc 133:197–199

    Article  CAS  Google Scholar 

  15. 15

    Mikhalchan A, Fan Z, Tran TQ, Liu P, Tan VBC, Tay T-E, Duong HM (2016) Continuous and scalable fabrication and multifunctional properties of carbon nanotube aerogels from the floating catalyst method. Carbon 102:409–418

    Article  CAS  Google Scholar 

  16. 16

    Wang S, Liu Q, Li M, Li T, Gu Y, Li Q, Zhang Z (2017) Property improvements of CNT films induced by wet-stretching and tension-heating post treatments. Compos A Appl Sci Manuf 103:106–112

    Article  CAS  Google Scholar 

  17. 17

    Wang YJ, Li M, Gu YZ, Zhang XH, Wang SK, Li QW, Zhang ZG (2015) Tuning carbon nanotube assembly for flexible, strong and conductive films. Nanoscale 7:3060–3066

    Article  CAS  Google Scholar 

  18. 18

    Wang JN, Luo XG, Wu T, Chen Y (2014) High-strength carbon nanotube fibre-like ribbon with high ductility and high electrical conductivity. Nat Commun 5:3848

    Article  CAS  Google Scholar 

  19. 19

    Liu P, Tan YF, Hu DCM, Jewell D, Duong HM (2016) Multi-property enhancement of aligned carbon nanotube thin films from floating catalyst method. Mater Des 108:754–760

    Article  CAS  Google Scholar 

  20. 20

    Hoecker C, Smail F, Pick M, Boies A (2017) The influence of carbon source and catalyst nanoparticles on CVD synthesis of CNT aerogel. Chem Eng J 314:388–395

    Article  CAS  Google Scholar 

  21. 21

    Li YL, Kinloch IA, Windle AH (2004) Direct spinning of carbon nanotube fibers from chemical vapor deposition synthesis. Science 304:276–278

    Article  CAS  Google Scholar 

  22. 22

    Gspann TS, Smail FR, Windle AH (2014) Spinning of carbon nanotube fibres using the floating catalyst high temperature route: purity issues and the critical role of sulphur. Faraday Discuss 173:47–65

    Article  CAS  Google Scholar 

  23. 23

    Motta MS, Moisala A, Kinloch IA, Windle AH (2008) The role of sulphur in the synthesis of carbon nanotubes by chemical vapour deposition at high temperatures. J Nanosci Nanotechnol 8:2442–2449

    Article  CAS  Google Scholar 

  24. 24

    Cheng HL, Koh KLP, Liu P, Thang TQ, Duong HM (2015) Continuous self-assembly of carbon nanotube thin films and their composites for supercapacitors. Colloids Surf A Physicochem Eng Asp 481:626–632

    Article  CAS  Google Scholar 

  25. 25

    Shah KA, Tali BA (2016) Synthesis of carbon nanotubes by catalytic chemical vapour deposition: a review on carbon sources, catalysts and substrates. Mater Sci Semicond Process 41:67–82

    Article  CAS  Google Scholar 

  26. 26

    Pattinson SW, Prehn K, Kinloch IA, Eder D, Koziol KKK, Schulte K, Windle AH (2012) The life and death of carbon nanotubes. RSC Adv 2:2909–2913

    Article  CAS  Google Scholar 

  27. 27

    Kang CS, Lee IJ, Seo MS, Kim SH, Baik DH (2017) Effect of purification method on the electrical properties of the carbon nanotube fibers. Fibers Polym 18:1580–1585

    Article  CAS  Google Scholar 

  28. 28

    Boncel S, Sundaram RM, Windle AH, Koziol KK (2011) Enhancement of the mechanical properties of directly spun CNT fibers by chemical treatment. ACS Nano 5:9339–9344

    Article  CAS  Google Scholar 

  29. 29

    Li YL, Zhang LH, Zhong XH, Windle AH (2007) Synthesis of high purity single-walled carbon nanotubes from ethanol by catalytic gas flow CVD reactions. Nanotechnology 18:225604

    Article  CAS  Google Scholar 

  30. 30

    Qiu J, Terrones J, Vilatela JJ, Vickers ME, Elliott JA, Windle AH (2013) Liquid infiltration into carbon nanotube fibers: effect on structure and electrical properties. ACS Nano 7:8412–8422

    Article  CAS  Google Scholar 

  31. 31

    Banks CE, Crossley A, Salter C, Wilkins SJ, Compton RG (2006) Carbon nanotubes contain metal impurities which are responsible for the “electrocatalysis” seen at some nanotube-modified electrodes. Angew Chem Int Ed 45:2533–2537

    Article  CAS  Google Scholar 

  32. 32

    Cheng HM, Li F, Su G, Pan HY, He LL, Sun X, Dresselhaus MS (1998) Large-scale and low-cost synthesis of single-walled carbon nanotubes by the catalytic pyrolysis of hydrocarbons. Appl Phys Lett 72:3282–3284

    Article  CAS  Google Scholar 

  33. 33

    Mercier G, Hérold C, Marêché J-F, Cahen S, Gleize J, Ghanbaja J, Lamura G, Bellouard C, Vigolo B (2013) Selective removal of metal impurities from single walled carbon nanotube samples. N J Chem 37:790

    Article  CAS  Google Scholar 

  34. 34

    Motta M, Moisala A, Kinloch IA, Windle AH (2007) High performance fibres from ‘dog bone’ carbon nanotubes. Adv Mater 19:3721–3726

    Article  CAS  Google Scholar 

  35. 35

    Cheng H, Koh KLP, Liu P, Thang TQ, Duong HM (2015) Continuous self-assembly of carbon nanotube thin films and their composites for supercapacitors. Colloids Surf A 481:626–632

    Article  CAS  Google Scholar 

  36. 36

    Jung Y, Song J, Huh W, Cho D, Jeong Y (2013) Controlling the crystalline quality of carbon nanotubes with processing parameters from chemical vapor deposition synthesis. Chem Eng J 228:1050–1056

    Article  CAS  Google Scholar 

  37. 37

    Cunha R, Paupitz R, Yoon K, Van Duin ACT, Elias AL, Carozo V, Dasgupta A, Fujisawa K, Lopez NP, Araujo PT, Terrones M (2018) Raman spectroscopy revealing noble gas adsorption on single-walled carbon nanotube bundles. Carbon 127:312–319

    Article  CAS  Google Scholar 

  38. 38

    Liu P, Fan Z, Mikhalchan A, Tran TQ, Jewell D, Duong HM, Marconnet AM (2016) Continuous carbon nanotube-based fibers and films for applications requiring enhanced heat dissipation. ACS Appl Mater Interfaces 8:17461–17471

    Article  CAS  Google Scholar 

  39. 39

    Gspann TS, Juckes SM, Niven JF, Johnson MB, Elliott JA, White MA, Windle AH (2017) High thermal conductivities of carbon nanotube films and micro-fibres and their dependence on morphology. Carbon 114:160–168

    Article  CAS  Google Scholar 

  40. 40

    Sundaram RM, Windle AH (2017) One-step purification of direct-spun CNT fibers by post-production sonication. Mater Des 126:85–90

    Article  CAS  Google Scholar 

  41. 41

    Hou GF, Chauhan D, Ng V, Xu CH, Yin ZZ, Paine M, Su RT, Shanov V, Mast D, Schulz M, Liu YJ (2017) Gas phase pyrolysis synthesis of carbon nanotubes at high temperature. Mater Des 132:112–118

    Article  CAS  Google Scholar 

  42. 42

    Lee SH, Park J, Kim HR, Lee J, Lee KH (2015) Synthesis of high-quality carbon nanotube fibers by controlling the effects of sulfur on the catalyst agglomeration during the direct spinning process. RSC Adv 5:41894–41900

    Article  CAS  Google Scholar 

  43. 43

    Sundaram RM, Koziol KK, Windle AH (2011) Continuous direct spinning of fibers of single-walled carbon nanotubes with metallic chirality. Adv Mater 23:5064–5068

    Article  CAS  Google Scholar 

  44. 44

    Tibbetts GG, Bernardo CA, Gorkiewicz DW, Alig RL (1994) Role of sulfur in the production of carbon fibers in the vapor phase. Carbon 32:569–576

    Article  CAS  Google Scholar 

  45. 45

    Kim MS, Rodriguez NM, Baker RTK (1993) The interplay between sulfur adsorption and carbon deposition on cobalt catalysts. J Catal 143:449–463

    Article  CAS  Google Scholar 

  46. 46

    Conroy D, Moisala A, Cardoso S, Windle A, Davidson J (2010) Carbon nanotube reactor: ferrocene decomposition, iron particle growth, nanotube aggregation and scale-up. Chem Eng Sci 65:2965–2977

    Article  CAS  Google Scholar 

  47. 47

    Zhang R, Zhang YY, Wei F (2017) Horizontally aligned carbon nanotube arrays: growth mechanism, controlled synthesis, characterization, properties and applications. Chem Soc Rev 46:3661–3715

    Article  CAS  Google Scholar 

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Acknowledgements

This work is supported by the National Nature Science Foundation of the People’s Republic of China (Nos. 51572243 and 51872262).

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Correspondence to Jianjun Chen.

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The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results.

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Jiang, M., Ou, G., Ma, R. et al. Deposition-float-assembly formation mechanism of continuous hollow cylindrical carbon nanotube sock via floating catalyst chemical vapor deposition. J Mater Sci 54, 6961–6970 (2019). https://doi.org/10.1007/s10853-019-03378-y

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