Skip to main content
Log in

3D gel printing of graded TiC-high manganese steel cermet

  • Composites
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A new solid freeform process, 3D gel printing (3DGP), was proposed for designing and manufacturing graded composites. As an example, TiC-high manganese steel cermet with a gradient distribution of TiC was successfully designed and fabricated by 3DGP. The rheological behavior and polymerization of slurries with different TiC content have been researched. The complex-shaped green bodies were printed accurately by depositing slurries layer by layer. The scanning electron microscopy and X-ray diffraction revealed the gradient distribution and morphology of the TiC particles within a sintered sample. The density, hardness, abrasion wear resistance, transverse rupture strength and impact toughness of the 3D gel-printed TiC-high manganese steel cermet appeared graded distribution corresponding to its gradient structure. Gradient distribution of the composition, microstructure and mechanical properties of the 3D gel-printed part are consistent with the design concept. Results indicated that 3DGP is a promising approach for high-throughput design and fabrication of complex-shaped graded composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9

Similar content being viewed by others

References

  1. Hui PM, Zhang X, Markworth AJ, Stroud D (1999) Thermal conductivity of graded composites: numerical simulations and an effective medium approximation. J Mater Sci 34:5497–5503. https://doi.org/10.1023/A:1004760427981

    Article  CAS  Google Scholar 

  2. Put S, Anné G, Vleugels J, Van der Biest O (2004) Advanced symmetrically graded ceramic and ceramic-metal composites. J Mater Sci 39:881–888. https://doi.org/10.1023/B:JMSC.0000012917.51982.9d

    Article  CAS  Google Scholar 

  3. Simchi A, Rota A, Imgrund P (2006) An investigation on the sintering behavior of 316L and 17-4PH stainless steel powders for graded composites. Mater Sci Eng, A 424:282–289

    Article  Google Scholar 

  4. Firouzdor V, Simchi A, Kokabi AH (2008) An investigation of the densification and microstructural evolution of M2/316L stepwise graded composite during co-sintering. J Mater Sci 43:55–63. https://doi.org/10.1007/s10853-007-2077-9

    Article  CAS  Google Scholar 

  5. Markworth AJ, Ramesh KS, Parks WP Jr (1995) Modelling studies applied to functionally graded materials. J Mater Sci 30:2183–2193. https://doi.org/10.1007/BF01184560

    Article  CAS  Google Scholar 

  6. Tammas-Williams S, Todd I (2017) Design for additive manufacturing with site-specific properties in metals and alloys. Scripta Mater 135:105–110

    Article  CAS  Google Scholar 

  7. Chung H, Das S (2006) Processing and properties of glass bead particulate-filled functionally graded Nylon-11 composites produced by selective laser sintering. Mater Sci Eng, A 437:226–234

    Article  Google Scholar 

  8. Balla VK, DeVasConCellos PD, Xue W, Bose S, Bandyopadhyay A (2009) Fabrication of compositionally and structurally graded Ti–TiO2 structures using laser engineered net shaping (LENS). Acta Biomater 5:1831–1837

    Article  CAS  Google Scholar 

  9. Tan X, Kok Y, Tan YJ, Descoins M, Mangelinck D, Tor SB, Leong KF, Chua CK (2015) Graded microstructure and mechanical properties of additive manufactured Ti–6Al–4 V via electron beam melting. Acta Mater 97:1–16

    Article  CAS  Google Scholar 

  10. Zhong W, Li F, Zhang Z, Song L, Li Z (2001) Short fiber reinforced composites for fused deposition modeling. Mater Sci Eng, A 301:125–130

    Article  Google Scholar 

  11. Levy A, Miriyev A, Elliott A, Babu SS, Frage N (2017) Additive manufacturing of complex-shaped graded TiC/steel composites. Mater Des 118:198–203

    Article  CAS  Google Scholar 

  12. Moon J, Caballero AC, Hozer L, Chiang Y, Cima MJ (2001) Fabrication of functionally graded reaction infiltrated SiC–Si composite by three-dimensional printing (3DP™) process. Mater Sci Eng, A 298:110–119

    Article  Google Scholar 

  13. Ren X, Shao H, Lin T, Zheng H (2016) 3D gel-printing: an additive manufacturing method for producing complex shape parts. Mater Des 101:80–87

    Article  CAS  Google Scholar 

  14. Shao H, Zhao D, Lin T, He J, Wu J (2017) 3D gel-printing of zirconia ceramic parts. Ceram Int 43:13938–13942

    Article  CAS  Google Scholar 

  15. Zhang X, Guo Z, Chen C, Yang W (2018) Additive manufacturing of WC-20Co components by 3D gel-printing. Int J Refract Met Hard Mater 70:215–223

    Article  CAS  Google Scholar 

  16. Young AC, Omatete OO, Janney MA, Menchhofer PA (1991) Gelcasting of alumina. J Am Ceram Soc 74(3):612–618

    Article  CAS  Google Scholar 

  17. Omatete OO, Janney MA, Nunn DS (1997) Gelcasting: from laboratory development toward industrial production. J Eur Ceram Soc 17:407–413

    Article  Google Scholar 

  18. Bryant FD, Sui G, Leu MC (2003) A study on effects of process parameters in rapid freeze prototyping. Rapid Prototyping J 9(1):19–23

    Article  Google Scholar 

  19. Lalehpour A, Barari A (2018) A more accurate analytical formulation of surface roughness in layer-based additive manufacturing to enhance the product’s precision. Int J Adv Manuf Technol 96:3793–3804

    Article  Google Scholar 

  20. Yu HZ, Jones ME, Brady GW, Griffiths RJ, Garcia D, Rauch HA, Cox CD, Hardwick N (2018) Non-beam-based metal additive manufacturing enabled by additive friction stir deposition. Scripta Mater 153:122–131

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the Fundamental Research Funds for the Central Universities (No. FRF-TP-16-017A1) and the State Key Lab of Advanced Metals and Materials (No. 2016-ZD02).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Fang Yang or Zhimeng Guo.

Ethics declarations

Conflict of interest

The authors claim no conflicts of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, X., Guo, L., Yang, F. et al. 3D gel printing of graded TiC-high manganese steel cermet. J Mater Sci 54, 2122–2132 (2019). https://doi.org/10.1007/s10853-018-2945-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-018-2945-5

Keywords

Navigation