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Journal of Materials Science

, Volume 52, Issue 5, pp 2591–2604 | Cite as

Environmentally acceptable sorbents of chemical warfare agent simulants

  • Dragutin Tušek
  • Danijela Ašperger
  • Ivana Bačić
  • Lidija Ćurković
  • Jelena Macan
Original Paper

Abstract

Development of environmentally acceptable decontaminants of chemical weapons and other highly toxic chemicals is important because of security, economical, health, political, and environmental reasons. The efficiency of natural zeolite (clinoptilolite) and synthetic zeolite, metal oxides, and their mixtures as chemical and physical sorbents of chemical warfare agents (CWA) was investigated. Commonly studied chemical warfare agent simulants dimethyl methylphosphonate (DMMP) and 2-chloroethyl ethyl sulfide (2-CEES) were included in this study. Organic solutions of DMMP and 2-CEES were passed through a column filled with natural and synthetic zeolites and their mixtures with metal oxides. After passing through the column filled with different sorbents, all eluents were filtered and centrifuged before the gas chromatography–mass spectroscopy (GC–MS) analysis. The efficiency of investigated adsorbents was estimated based on the obtained data. All investigated sorbents exhibited absorption efficiency for both simulants of chemical warfare agents. Infrared spectroscopy was used for the detection of DMMP and 2-CEES adsorbed to the investigated adsorbents. Since GC–MS analysis results indicate very good sorption properties of both simulants, the detection of adsorbed CWA simulants was a matter of routine.

Keywords

Zeolite Breakthrough Curve Zinc Oxide Clinoptilolite Sulfur Mustard 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Compliance with ethical standards

Conflicts of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Dragutin Tušek
    • 1
  • Danijela Ašperger
    • 2
  • Ivana Bačić
    • 3
  • Lidija Ćurković
    • 4
  • Jelena Macan
    • 5
  1. 1.Croatian Defence AcademyCroatian Armed Forces, Ministry of Defence of the Republic of CroatiaZagrebCroatia
  2. 2.Department of Analytical Chemistry, Faculty of Chemical Engineering and TechnologyUniversity of ZagrebZagrebCroatia
  3. 3.Forensic Science Centre „Ivan Vučetić“Ministry of the InteriorZagrebCroatia
  4. 4.Department of Materials, Faculty of Mechanical Engineering and Naval ArchitectureUniversity of ZagrebZagrebCroatia
  5. 5.Department of Physical Chemistry, Faculty of Chemical Engineering and TechnologyUniversity of ZagrebZagrebCroatia

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