Journal of Materials Science

, Volume 52, Issue 7, pp 3622–3629 | Cite as

3D chrysanthemum-like ReS2 microspheres composed of curly few-layered nanosheets with enhanced electrochemical properties for lithium-ion batteries

  • Fei Qi
  • Yuanfu Chen
  • Binjie Zheng
  • Jiarui He
  • Qian Li
  • Xinqiang Wang
  • Bo Yu
  • Jie Lin
  • Jinhao Zhou
  • Pingjian Li
  • Wanli Zhang
Batteries and Supercapacitors


As a new member of the transition metal dichalcogenides (TMDs) family, rhenium disulfide (ReS2) is attracting more and more attention because of its many distinctive characteristics, such as extremely weak interlayer coupling and anisotropic electronic, optical, and mechanical properties. The studies on synthesis method and electrochemical properties of ReS2 are still rare. For the first time, three-dimensional (3D) chrysanthemum-like microspheres composed of curly ReS2 nanosheets have been synthesized through a facile hydrothermal method. The high-resolution TEM image indicates that the ReS2 nanosheet is highly crystalline with a thickness of few monolayers. As anode for lithium-ion battery, the as-synthesized 3D chrysanthemum-like ReS2 (C-ReS2) microspheres deliver a large initial discharge capacity of 843.0 mAh g−1 and remain 421.1 mAh g−1 after 30 cycles. These values are much higher than that of commercial ReS2. The significant enhancement in electrochemical performance can be attributed to its porous and chrysanthemum-like microsphere structure constructed by few-layered curly ReS2 nanosheets. This unique architecture can allow for easy electrolyte infiltration, efficient electron transfer, and ionic diffusion. The facile synthesis approach can be extended to synthesize other two-dimensional TMDs semiconductors. The study renders ReS2 a promising future in lithium-ion batteries.


MoS2 Electrochemical Impedance Spectroscopy Electrochemical Performance ReS2 Transition Metal Dichalcogenides 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



This research was supported by the National Natural Science Foundation of China (Grant Nos. 51202022, 51372033 and 61378028), the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20120185120011), the National High Technology Research and Development Program of China (Grant No. 2015AA034202), the 111 Project (Grant No. B13042), Sichuan Youth Science and Technology Innovation Research Team Funding (Grant No. 2011JTD0006), and the International Science and Technology Cooperation Program of China (Grant No. 2012DFA51430).

Supplementary material

10853_2016_500_MOESM1_ESM.docx (513 kb)
Supplementary material 1 (DOCX 512 kb)


  1. 1.
    Wang J, Liu J, Chao D, Yan J, Lin J, Shen ZX (2014) Self-assembly of honeycomb-like MoS2 nanoarchitectures anchored into graphene foam for enhanced lithium-ion storage. Adv Mater 26:7162–7169CrossRefGoogle Scholar
  2. 2.
    Wang P, Sun H, Ji Y, Li W, Wang X (2014) Three-dimensional assembly of single-layered MoS2. Adv Mater 26:964–969CrossRefGoogle Scholar
  3. 3.
    He J, Chen Y, Li P, Fu F, Wang Z, Zhang W (2015) Three-dimensional CNT/graphene-sulfur hybrid sponges with high sulfur loading as superior-capacity cathodes for lithium-sulfur batteries. J Mater Chem A 3:18605–18610CrossRefGoogle Scholar
  4. 4.
    He J, Chen Y, Lv W, Wen K, Li P, Wang Z, Zhang W, Qin W, He W (2016) Three-dimensional hierarchical graphene-CNT@Se: a highly efficient freestanding cathode for Li–Se batteries. ACS Energy Lett 1:16–20CrossRefGoogle Scholar
  5. 5.
    He J, Chen Y, Li P, Fu F, Wang Z, Zhang W (2015) Self-assembled CoS2 nanoparticles wrapped by CoS2-quantum-dots-anchored graphene nanosheets as superior-capability anode for lithium-ion batteries. Electrochim Acta 182:424–429CrossRefGoogle Scholar
  6. 6.
    Chang K, Chen W (2011) L-cysteine-assisted synthesis of layered MoS2/graphene composites with excellent electrochemical performances for lithium ion batteries. ACS Nano 5:4720–4728CrossRefGoogle Scholar
  7. 7.
    Khalil A, Lalia BS, Hashaikeh R (2016) Nickel oxide nanocrystals as a lithium-ion battery anode: structure-performance relationship. J Mater Sci 51:6624–6638. doi: 10.1007/s10853-016-9946-z CrossRefGoogle Scholar
  8. 8.
    Cao X, Shi Y, Shi W, Rui X, Yan Q, Kong J, Zhang H (2013) Preparation of MoS2-coated three-dimensional graphene networks for high-performance anode material in lithium-ion batteries. Small 9:3433–3438CrossRefGoogle Scholar
  9. 9.
    Chen G, Wang S, Yi R, Tan L, Li H, Zhou M, Yan L, Jiang Y, Tan S, Wang D, Deng S, Meng X, Luo H (2016) Facile synthesis of hierarchical MoS2-carbon microspheres as a robust anode for lithium ion batteries. J Mater Chem A 24:9653–9660CrossRefGoogle Scholar
  10. 10.
    Qu G, Cheng J, Wang Z, Wang B, Ye S (2016) Self-templated formation of tremella-like MoS2 with expanded spacing of (002) crystal planes for Li-ion batteries. J Mater Sci 51:4739–4747. doi: 10.1007/s10853-015-9421-2 CrossRefGoogle Scholar
  11. 11.
    Huang F, Jian J, Wu R (2016) Few-layer thick WS2 nanosheets produced by intercalation/exfoliation route. J Mater Sci 51:10160–10165. doi: 10.1007/s10853-016-0243-7 CrossRefGoogle Scholar
  12. 12.
    Tongay S, Sahin H, Ko C, Luce A, Fan W, Liu K, Zhou J, Huang Y, Ho C, Yan J, Ogletree DF, Aloni S, Ji J, Li S, Li J, Peeters FM, Wu J (2014) Monolayer behaviour in bulk ReS2 due to electronic and vibrational decoupling. Nat Commun 5:3252CrossRefGoogle Scholar
  13. 13.
    Corbet CM, McClellan C, Rai A, Sonde SS, Tutuc E, Banerjee SK (2015) Field effect transistors with current saturation and voltage gain in ultrathin ReS2. ACS Nano 9:363–370CrossRefGoogle Scholar
  14. 14.
    Liu F, Zheng S, He X, Chaturvedi A, He J, Chow WL, Mion TR, Wang X, Zhou J, Fu Q, Fan HJ, Tay BK, Song L, He R, Kloc C, Ajayan PM, Liu Z (2016) Highly sensitive detection of polarized light using anisotropic 2D ReS2. Adv Funct Mater 26:1169–1177CrossRefGoogle Scholar
  15. 15.
    Liu E, Fu Y, Wang Y, Feng Y, Liu H, Wan X, Zhou W, Wang B, Shao L, Ho C, Huang Y, Cao Z, Wang L, Li A, Zeng J, Song F, Wang X, Shi Y, Yuan H, Hwang HY, Cui Y, Miao F, Xing D (2015) Integrated digital inverters based on two-dimensional anisotropic ReS2 field-effect transistors. Nat Commun 6:6991–6997CrossRefGoogle Scholar
  16. 16.
    Fujita T, Ito Y, Tan Y, Yamaguchi H, Hojo D, Hirata A, Voiry D, Chhowalla M, Chen M (2014) Chemically exfoliated ReS2 nanosheets. Nanoscale 6:12458–12462CrossRefGoogle Scholar
  17. 17.
    Zhang Q, Tan S, Mendes RG, Sun Z, Chen Y, Kong X, Xue Y, Ruemmeli MH, Wu X, Chen S, Fu L (2016) Extremely weak van der Waals coupling in vertical ReS2 nanowalls for high-current-density lithium-ion batteries. Adv Mater 28:2616–2623CrossRefGoogle Scholar
  18. 18.
    Fu F, Chen Y, Li P, He J, Wang Z, Lin W, Zhang W (2015) Three-dimensional CoS2/RGO hierarchical architecture as superior-capability anode for lithium ion batteries. RSC Adv 5:71790–71795CrossRefGoogle Scholar
  19. 19.
    Xiao J, Choi D, Cosimbescu L, Koech P, Liu J, Lemmon JP (2010) Exfoliated MoS2 nanocomposite as an anode material for lithium ion batteries. Chem Mater 22:4522–4524CrossRefGoogle Scholar
  20. 20.
    Chen R, Zhao T, Wu W, Wu F, Li L, Qian J, Xu R, Wu H, Albishri HM, Al-Bogami AS, El-Hady DA, Lu J, Amine K (2014) Free-standing hierarchically sandwich-type tungsten disulfide nanotubes/graphene anode for lithium-ion batteries. Nano Lett 14:5899–5904CrossRefGoogle Scholar
  21. 21.
    Hu X, Zhang W, Liu X, Mei Y, Huang Y (2015) Nanostructured Mo-based electrode materials for electrochemical energy storage. Chem Soc Rev 44:2376–2404CrossRefGoogle Scholar
  22. 22.
    Das SK, Mallavajula R, Jayaprakash N, Archer LA (2012) Self-assembled MoS2-carbon nanostructures: influence of nanostructuring and carbon on lithium battery performance. J Mater Chem 22:12988–12992CrossRefGoogle Scholar
  23. 23.
    Seo J, Jun Y, Park S, Nah H, Moon T, Park B, Kim J, Kim YJ, Cheon J (2007) Two-dimensional nanosheet crystals. Angew Chem Int Ed 46:8828–8831CrossRefGoogle Scholar
  24. 24.
    Chang K, Chen W, Ma L, Li H, Li H, Huang F, Xu Z, Zhang Q, Lee J (2011) Graphene-like MoS2/amorphous carbon composites with high capacity and excellent stability as anode materials for lithium ion batteries. J Mater Chem 21:6251–6257CrossRefGoogle Scholar
  25. 25.
    Liu H, Su X, Duan C, Dong X, Zhu Z (2014) A novel hydrogen peroxide biosensor based on immobilized hemoglobin in 3D flower-like MoS2 microspheres structure. Mater Lett 122:182–185CrossRefGoogle Scholar
  26. 26.
    Wang X, Shen L, Deng W, Yan M, Liu H, Ge S, Yu J, Song X (2016) A sensitive electrochemiluminescent immunosensor based on 3D-flower-like MoS2 microspheres and using AuPt nanoparticles for signal amplification. RSC Adv 6:23411–23419CrossRefGoogle Scholar
  27. 27.
    Brorson M, Hansen TW, Jacobsen CJH (2002) Rhenium(IV) sulfide nanotubes. J Am Chem Soc 124:11582–11583CrossRefGoogle Scholar
  28. 28.
    Qi F, Chen Y, Zheng B, Zhou J, Wang X, Li P, Zhang W (2016) Facile growth of large-area and high-quality few-layer ReS2 by physical vapour deposition. Mater Lett 184:324–327CrossRefGoogle Scholar
  29. 29.
    Hwang H, Kim H, Cho J (2011) MoS2 nanoplates consisting of disordered graphene-like layers for high rate lithium battery anode materials. Nano Lett 11:4826–4830CrossRefGoogle Scholar
  30. 30.
    Wang X, Zhang Z, Chen Y, Qu Y, Lai Y, Li J (2014) Morphology-controlled synthesis of MoS2 nanostructures with different lithium storage properties. J Alloy Compd 600:84–90CrossRefGoogle Scholar
  31. 31.
    Li H, Li W, Ma L, Chen W, Wang J (2009) Electrochemical lithiation/delithiation performances of 3D flowerlike MoS2 powders prepared by ionic liquid assisted hydrothermal route. J Alloy Compd 471:442–447CrossRefGoogle Scholar
  32. 32.
    Ding S, Zhang D, Chen JS, Lou XWD (2012) Facile synthesis of hierarchical MoS2 microspheres composed of few-layered nanosheets and their lithium storage properties. Nanoscale 4:95–98CrossRefGoogle Scholar
  33. 33.
    Wang M, Li G, Xu H, Qian Y, Yang J (2013) Enhanced lithium storage performances of hierarchical hollow MoS2 nanoparticles assembled from nanosheets. ACS Appl Mater Interfaces 5:1003–1008CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Fei Qi
    • 1
  • Yuanfu Chen
    • 1
  • Binjie Zheng
    • 1
  • Jiarui He
    • 1
  • Qian Li
    • 1
  • Xinqiang Wang
    • 1
  • Bo Yu
    • 1
  • Jie Lin
    • 1
  • Jinhao Zhou
    • 1
  • Pingjian Li
    • 1
  • Wanli Zhang
    • 1
  1. 1.State Key Laboratory of Electronic Thin Films and Integrated DevicesUniversity of Electronic Science and Technology of ChinaChengduPeople’s Republic of China

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