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Journal of Materials Science

, Volume 51, Issue 16, pp 7636–7651 | Cite as

Magnetic, magnetocaloric properties, and critical behavior in a layered perovskite La1.4(Sr0.95Ca0.05)1.6Mn2O7

  • Arwa Belkahla
  • K. Cherif
  • J. Dhahri
  • E. K. Hlil
Original Paper

Abstract

We report the results of magnetic, magnetocaloric properties, and critical behavior investigation of the double-layered perovskite manganite La1.4(Sr0.95Ca0.05)1.6Mn2O7. The compounds exhibits a paramagnetic (PM) to ferromagnetic (FM) transition at the Curie temperature T C = 248 K, a Neel transition at T N = 180 K, and a spin glass behavior below 150 K. To probe the magnetic interactions responsible for the magnetic transitions, we performed a critical exponent analysis in the vicinity of the FM–PM transition range. Magnetic entropy change (−∆S M) was estimated from isothermal magnetization data. The critical exponents β and γ, determined by analyzing the Arrott plots, are found to be T C = 248 K, β = 0.594, γ = 1.048, and δ = 2.764. These values for the critical exponents are close to the mean-field values. In order to estimate the spontaneous magnetization M S(T) at a given temperature, we use a process based on the analysis, in the mean-field theory, of the magnetic entropy change (−∆S M) versus the magnetization data. An excellent agreement is found between the spontaneous magnetization determined from the entropy change [(−∆S M) vs. M 2] and the classical extrapolation from the Arrott curves (µ0H/M vs. M 2), thus confirming that the magnetic entropy is a valid approach to estimate the spontaneous magnetization in this system and in other compounds as well.

Keywords

Mn2O7 Manganite Critical Exponent Magnetic Phase Transition Spontaneous Magnetization 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Compliance with ethical standards

Conflict of interest

The authors (Arwa. Belkahla, K. Cherif, J. Dhahri, E. K. Hlil) declare that they have no conflict of interest.

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© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Arwa Belkahla
    • 1
  • K. Cherif
    • 1
  • J. Dhahri
    • 1
  • E. K. Hlil
    • 2
  1. 1.Département de Physique, Faculté des Sciences de MonastirLaboratoire de la matière condensée et des nanosciencesMonastirTunisia
  2. 2.Institut NeelCNRS et Université Joseph FourierGrenobleFrance

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