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Journal of Materials Science

, Volume 51, Issue 1, pp 126–137 | Cite as

Stabilization of the high-temperature and high-pressure cubic phase of ZnO by temperature-controlled milling

  • C. S. Tiwary
  • D. Vishnu
  • A. K. Kole
  • J. Brahmanandam
  • D. R. Mahapatra
  • P. Kumbhakar
  • K. Chattopadhyay
50th Anniversary

Abstract

The reversible transition of wurtzite to rock salt phase under pressure is well reported in literature. The cubic phase is unstable under ambient conditions both in the bulk and in nanoparticles. This paper reports defect-induced stabilization of cubic ZnO phase in sub 20 nm ZnO particles and explores their optical properties. The size reduction was achieved by ball milling in a specially designed mill which allows a control of the milling temperature. The process of synthesis involved both variation of milling temperature (including low temperature ~150 K) and impact pressure. We show that these have profound influence in the introduction of defects and stabilization of the cubic phase. A molecular dynamics simulation is presented to explain the observed results. The measured optical properties have further supported the observations of defect-induced stabilization of cubic ZnO and reduction in particle size.

Keywords

Milling Radial Distribution Function Rock Salt Simulation Cell Atomic Configuration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

The authors would like to acknowledge the electron microscopy facilities available at the Advanced Facility for Microscopy and Microanalysis, Indian Institute of Science (IISc), Bangalore, India. The authors are grateful to UGC-NRCM, IISc, Bangalore for the partial financial support.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • C. S. Tiwary
    • 1
  • D. Vishnu
    • 2
  • A. K. Kole
    • 2
  • J. Brahmanandam
    • 3
  • D. R. Mahapatra
    • 3
  • P. Kumbhakar
    • 2
  • K. Chattopadhyay
    • 1
  1. 1.Department of Materials EngineeringIndian Institute of ScienceBangaloreIndia
  2. 2.Nanoscience Laboratory, Department of PhysicsNational Institute of TechnologyDurgapurIndia
  3. 3.Department of Aerospace EngineeringIndian Institute of ScienceBangaloreIndia

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