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Journal of Materials Science

, Volume 50, Issue 13, pp 4576–4585 | Cite as

Towards UV-curable inkjet printing of biodegradable poly (lactic acid) fabrics

  • Mohammad Nazmul Karim
  • Shaila Afroj
  • Muriel Rigout
  • Stephen G. Yeates
  • Chris Carr
Original Paper

Abstract

There has been growing interest in using poly (lactic acid) (PLA) fibres because of its natural-based origin and good biodegradability; however, its adoption within the textile industry has been limited to lower temperature wet and dry processing, because of its relatively lower glass transition temperature (T g) and melting point (T m). Here we report for the first time inkjet printing of heat-sensitive PLA fabrics using ambient temperature UV-curable inks as a way of overcoming the potential degradation at higher temperature. The UV cured inkjet printed PLA fabrics exhibited good performance characteristics such as acceptable colour fastness, relatively high colour strength, K/S, and comparable colour difference, ΔE, after washing to the thermally cured ink system, without affecting the physical and mechanical properties of the fabrics. In contrast thermally cured inkjet printed PLA fabrics exhibited significantly reduced bursting strength and stiffer handle attributed to the thermal degradation and lower fibre flexibility imparted at the higher temperature. Investigation of the radiation-cured printing approach indicates UV-curable inkjet printing may be considered as an alternative to conventional thermally cured pigment printing of heat-sensitive biodegradable PLA-based fabrics.

Keywords

Inkjet Printing Thermal Cure Colour Strength Colour Fastness Safety Data Sheet 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

The authors kindly acknowledge the support of The University of Manchester Research Impact Scholarship for the PhD study of first author and also like to thank Dr Andy Hancock, Technical Director, Mexar Inkjet Solutions and Hybrid UK for the help with inkjet pigment printing and UV-curable inkjet printing, respectively.

References

  1. 1.
    Dawson T, Hawkyard C (2000) A new millennium of textile printing. Rev Prog Color Relat Top 30(1):7–20CrossRefGoogle Scholar
  2. 2.
    Lin L, Bai X (2004) Ink-jet technology: status quo and future–relevance to surface coatings. Pigment Resin Technol 33(4):238–244CrossRefGoogle Scholar
  3. 3.
    Zhang Y, Westland S, Cheung V, Burkinshaw SM, Blackburn RS (2009) A custom ink-jet printing system using a novel pretreatment method. Color Technol 125(6):357–365CrossRefGoogle Scholar
  4. 4.
    Mochizuki M (2005) Properties and application of aliphatic polyester products, in biopolymers online. Wiley-VCH Verlag GmbH & Co KGaA, WeinheimGoogle Scholar
  5. 5.
    Mochizuki M, Hirami M (1995) Biodegradable fibers made from truly-biodegradable thermoplastics. In: Prasad P, Mark J, Fai T (eds) Polymers and other advanced materials. Springer, Berlin, pp 589–596CrossRefGoogle Scholar
  6. 6.
    Gupta B, Revagade N, Hilborn J (2007) Poly (lactic acid) fiber: an overview. Prog Polym Sci 32(4):455–482CrossRefGoogle Scholar
  7. 7.
    Mochizuki M (2010) Textie application. In: Auras RA et al (eds) Poly (lactic acid): synthesis, structures, properties, processing, and applications. Wiley, New JerseyGoogle Scholar
  8. 8.
    Avinc O, Khoddami A (2009) Overview of poly(lactic acid) (PLA) fibre. Fibre Chem 41(6):391–401CrossRefGoogle Scholar
  9. 9.
    Reddy N, Nama D, Yang Y (2008) Polylactic acid/polypropylene polyblend fibers for better resistance to degradation. Polym Degrad Stab 93(1):233–241CrossRefGoogle Scholar
  10. 10.
    Karim MN, Rigout M, Yeates SG, Carr C (2014) Surface chemical analysis of the effect of curing conditions on the properties of thermally-cured pigment printed poly (lactic acid) fabrics. Dyes Pigm 103:168–174CrossRefGoogle Scholar
  11. 11.
    Edison SE (2010) Formulating UV curable inkjet inks. In: Magdassi S (ed) The chemistry of inkjet inks. World Scientific Publishing Company Pvt Ltd, Singapore, pp 161–176Google Scholar
  12. 12.
    Hancock A, Lin L (2004) Challenges of UV curable ink-jet printing inks-a formulators perspective. Pigm Resin Technol 33(5):280–286CrossRefGoogle Scholar
  13. 13.
    Li S, Boyter H, Stewart N (2004) Ultraviolet (UV) curing for textile coloration. AATCC Rev 4(8):44–49Google Scholar
  14. 14.
    Loutz JM, Peeters S, Lindekens L (1993) Radiation-curable waterborne systems. J Coated Fabr 22:298Google Scholar
  15. 15.
    BSI, BS EN ISO 105-C06: 2010 textiles (2010) Tests for colour fastness. Colour fastness to domestic and commercial laundering. BSI, LondonGoogle Scholar
  16. 16.
    Fischer E, Sterzel HJ, Wegner G (1973) Investigation of the structure of solution grown crystals of lactide copolymers by means of chemical reactions. Kolloid-Zeitschrift und Zeitschrift für Polymere 251(11):980–990CrossRefGoogle Scholar
  17. 17.
    Anderson K (2008) Curing inkjet printed pigments with ultraviolet light. In: TC2 Google Scholar
  18. 18.
    Mikuž M, Turk SŠ, Tavčer PF (2010) Properties of ink-jet printed, ultraviolet cured pigment prints in comparison with screen printed, thermo cured pigment prints. Color Technol 126(5):249–255CrossRefGoogle Scholar
  19. 19.
    Neral B, Šostar-Turk S, Vončina B (2006) Properties of UV-cured pigment prints on textile fabric. Dyes Pigm 68(2):143–150CrossRefGoogle Scholar
  20. 20.
    Hutchinson I (2010) Raw materials for UV curable inks. In: Magdassi S (ed) The chemistry of inkjet inks. World Scientific Publishing Company Pvt Ltd, Singapore, pp 177–200Google Scholar
  21. 21.
    Xue C-H, Shi M-M, Chen H-Z, Wu G, Wang M (2006) Preparation and application of nanoscale microemulsion as binder for fabric inkjet printing. Colloids Surf A 287(1–3):147–152CrossRefGoogle Scholar
  22. 22.
    Miles LWC (2010) Textile printing, 2nd edn. SDC, Bradford. ISBN 0901956333Google Scholar
  23. 23.
    Nishida H (2010) Thermal degradation. In: Auras RA et al (eds) poly (lactic acid): synthesis, structures, properties, processing, and applications. Wiley, New Jersey, pp 401–412CrossRefGoogle Scholar
  24. 24.
    Yang QB, Sun YJ (2011) The mechanical property of PLA fibers under heat treatment. Adv Mater Res 321:184–187CrossRefGoogle Scholar
  25. 25.
    Mondal S, Gupta B, Singh H (2003) Coating of polypropylene nonwovens with acrylic copolymers. J Ind Text 33(1):33–41CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Mohammad Nazmul Karim
    • 1
  • Shaila Afroj
    • 2
  • Muriel Rigout
    • 3
  • Stephen G. Yeates
    • 2
  • Chris Carr
    • 3
  1. 1.School of MaterialsUniversity of ManchesterManchesterUK
  2. 2.School of ChemistryUniversity of ManchesterManchesterUK
  3. 3.School of DesignUniversity of LeedsLeedsUK

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