Journal of Materials Science

, Volume 49, Issue 15, pp 5246–5255 | Cite as

H-bonding driven assembly of colloidal Au nanoparticles on nanostructured poly(styrene-b-ethylene oxide) block copolymer templates

  • A. Evelyn Di Mauro
  • Vincenzo Villone
  • Chiara Ingrosso
  • Michela Corricelli
  • Lorea Oria
  • Francesc Pérez-Murano
  • Angela Agostiano
  • Marinella Striccoli
  • M. L. Curri


A facile, cost-effective, and general solution-based “bottom-up” method for nanopatterning dense arrays of colloidal Au nanoparticles (NPs) has been developed. The organization of the NPs has been successfully achieved onto a microphase-separated poly(styrene-block-ethylene oxide) (PS-b-PEO) block copolymer (BCP) thin film which acts as structural template. The NP assembly process occurs by incubating the BCP films in dispersions of the ex situ synthesized Au NPs, not requiring any chemical pre-treatment or activation step of the copolymer surface, and has demonstrated to be distinctively controlled by multiple, cooperative, and selective hydrogen bonding interactions between hydroxyl functionalities of the capping molecules coating the Au NP surface and the hydrophilic PEO block. The effect of incubation time and concentration of NPs on the selectivity of the assembly has been investigated by atomic force and scanning electron microscopy. The results show that the BCP pattern is preserved after decoration with the Au NPs. The fabricated nanopatterns are good candidates for nanostructure integration in sensing and optoelectronic applications, as well as in memory devices and photonic systems. Moreover, the proposed immobilization protocol represents a model system that can be extended to other NPs having different compositions and surface chemistries.


Diblock Copolymer Copolymer Film Phosphonium Chloride Copolymer Template Topography Micrographs 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



This work was supported by the National Sens&Micro LAB Project (POFESR 2007-2013), by the Italian National Consortium for Material Science and Technology (INSTM), by the FIRB—Futuro in Ricerca (RBFR122HFZ) funding program, by the project MAT2011-15159-E, and by the Prin Project (2013–2016, 20128ZZS2H).

Supplementary material

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Supplementary material 1 (PDF 898 kb)


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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • A. Evelyn Di Mauro
    • 1
  • Vincenzo Villone
    • 1
    • 2
  • Chiara Ingrosso
    • 1
  • Michela Corricelli
    • 2
  • Lorea Oria
    • 3
  • Francesc Pérez-Murano
    • 3
  • Angela Agostiano
    • 1
    • 2
  • Marinella Striccoli
    • 1
  • M. L. Curri
    • 1
  1. 1.CNR-IPCF Bari-Division c/o Chemistry DepartmentUniversity “Aldo Moro” of BariBariItaly
  2. 2.Chemistry DepartmentUniversity “Aldo Moro” of BariBariItaly
  3. 3.Microelectronic Institute of Barcelona (IMB-CNM, CSIC)BarcelonaSpain

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