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POSS-based luminescent hybrid material for enhanced photo-emitting properties

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Abstract

In this present work, we have developed a novel POSS type monomer ligand “2,6-pyridinediamine-bis-(propanylheptaisobutyl POSS)” (PDC-POSS) and utilized in the preparation of potential luminescent hybrid complex Eu-PDC-POSS with an inner transition metal ion Eu3+. The solubility and photo-emitting properties of new Eu-PDC-POSS hybrid material were studied. The precursor PDC-POSS was synthesized by treating (3-aminopropyl)heptaisobutyl POSS with PDC (2,6-pyridinedicarboxylic acid chloride), and then coordinated with Eu3+ using europium nitrate to afford Eu-PDC-POSS hybrid material. The europium-doped hybrid material was characterized using fourier transform infrared spectroscopy, and scanning electron microscopy along with energy dispersive X-ray analysis. The photo emitting properties were studied using a fluorescence spectrophotometer in which, the results showed enhancement in red emission peak at 618 nm for Eu-PDC-POSS, when compared to that of a known solgel-based material Eu-PDC-solgel.

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Acknowledgements

This work was supported by Grants from the Ministry of Environment of Korea (KME, 412-111-008), National Research Foundation of Korea (NRF-2010-0029634), and Ministry of Knowledge Economy of Korea (MKE, R0000495).

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Authors and Affiliations

  1. Department of Chemistry, Changwon National University, 9, Sarim-dong, Gyeongsangnam-do, Changwon, 641-773, South Korea

    B. Prem Kumar, B. V. D. Vijaykumar, S. J. Harshavardhan & Dong-Soo Shin

  2. Department of Physics, Changwon National University, Gyeongsangnam-do, Changwon, 641-773, South Korea

    C. M. Raghavan, Sakthivel Gandhi & Kiwan Jang

  3. Department of Electronic Materials Engineering, Silla University, Busan, 617-736, South Korea

    Soung-Soo Yi

  4. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing, 100083, China

    Jianzhuang Jiang

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  1. B. Prem Kumar
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Correspondence to Dong-Soo Shin.

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Prem Kumar, B., Vijaykumar, B.V.D., Raghavan, C.M. et al. POSS-based luminescent hybrid material for enhanced photo-emitting properties. J Mater Sci 48, 7533–7539 (2013). https://doi.org/10.1007/s10853-013-7568-2

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  • DOI: https://doi.org/10.1007/s10853-013-7568-2

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