Abstract
Magnetic polyurethane elastomer nanocomposites were prepared by incorporating pure and thiodiglycolic acid (TDGA) surface-modified Fe3O4 nanoparticles into polyurethane matrix using in situ polymerization method. Surface modification of Fe3O4 nanoparticles was carried out to enhance the dispersion of the nanoparticles in polyurethane matrix. Pure and TDGA surface-modified Fe3O4 nanoparticles were synthesized by coprecipitation method and characterized by Fourier Transform Infrared Spectroscopy, X-ray diffraction, and Vibrating Sample Magnetometer. The morphology and dispersion of the nanoparticles in the magnetic polyurethane elastomer nanocomposites were studied by Scanning Electron Microscope. It was observed that surface modification of Fe3O4 nanoparticles with TDGA enhanced the dispersion of the nanoparticles in polyurethane matrices. Furthermore, effect of surface modification of Fe3O4 nanoparticles on thermal and mechanical properties of magnetic polyurethane elastomer nanocomposite was investigated by thermogravimetric analysis, dynamic mechanical thermal analysis, and an Instron type Tensile Tester. It was concluded that surface modification of Fe3O4 nanoparticles allowed preparation of the magnetic nanocomposites with better mechanical properties. Moreover, study of fibroblast cells interaction with magnetic nanocomposites showed that the products can be a good candidate for biomedical application due to their in vitro biocompatibility and non-toxicity.
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Bulte JWM, Douglas T, Witwer B, Zhang SC, Strable E, Lewis BK, Zywicke H, Miller B, van Gelderen P, Moskowitz BM (2001) Nat Biotechnol 19:1141
Qu J, Liu G, Wang Y, Hong R (2010) Adv Powder Technol 21:461
Lu AH, Salabas EL, Schüth F (2007) Angew Chem Int Edit 46:1222
Rossi LM, Silva FP, Vono LLR, Kiyohara PK, Duarte EL, Itri R, Landers R, Machado G (2007) Green Chem 9:379
Lee JH, Jun Y, Yeon SI, Shin JS, Cheon J (2006) Angew Chem Int Edit 118:8340
Mohapatra S, Pramanik, Mukherjee S, Ghosh SK, Pramanik P (2007) J Mater Sci 42:7566. doi:10.1007/s10853-007-1597-7
Wu W, He Q, Jiang C (2008) Nanoscale Res Lett 3:397
Dietrich S, Chandra S, Georgi C, Thomas S, Makarov D, Schulze S, Hietschold M, Albrecht M, Bahadur D, Lang H (2012) Mater Chem Phys 132:292
Yan H, Zhang J, You C, Song Z, Yu B, Shen Y (2009) Mater Chem Phys 113:46
Sindhu S, Jegadesan S, Parthiban A, Valiyaveettil S (2006) J Magn Magn Mater 296:104
Mai Y, Yu Z (2006) Polymer Nanocomposites. Woodhead Publishing, Cambridge
Sláma J, Grusková A, Vícen R, Vícenová S, Dosoudil R, Franek J (2003) J Magn Magn Mater 254:642
Pant R, Krishna R, Negi P, Ravat K, Dhawan U, Gupta S, Suri D (1995) J Magn Magn Mater 149:10
Zhou L, Li G, An T, Li Y (2010) Res Chem Intermediat 36:277
Xu XX, Zheng YF (2006) Key Eng Mater 324:659
Razzaq MY, Anhalt M, Frormann L, Weidenfeller B (2007) Mat Sci Eng A 444:227
Pirmoradi FN, Cheng L, Chiao M (2009) J Micromech Microeng 20:015032
Phang SW, Tadokoro M, Watanabe J, Kuramoto N (2009) Polym Advan Technol 20:550
Huang X, Lu M, Zhang X, Wen G, Zhou Y, Fei L (2012) Scripta Mater 67:613
Mammeri F, Le Bourhis E, Rozes L, Sanchez C (2005) J Mater Chem 15:3787
Lau AKT (2010) Multifunctional polymer nanocomposites. CRC PressI, Boca Raton
Marutani E, Yamamoto S, Ninjbadgar T, Tsujii Y, Fukuda T, Takano M (2004) Polymer 45:2231
Santerre J, Woodhouse K, Laroche G, Labow R (2005) Biomaterials 26:7457
Yeganeh H, Barikani M, Noei Khodabadi F (2000) Eur Polym J 36:2207
Kuan HC, Chuang WP, Ma CCM, Chiang CL, Wu HL (2005) J Mater Sci 40:179. doi:10.1080/02844310600763725
Gogolewski S (1997) Colloid Polym Sci 267:1865
Ashjari M, Mahdavian AR, Ebrahimi NG, Mosleh Y (2010) J Inorg Organomet Polym 20:213
Guo Z, Park S, Hahn HT, Wei S, Moldovan M, Karki AB, Young DP (2007) J Appl Phys 101:511
Papaphilippou P, Christodoulou M, Marinica OM, Taculescu A, Vekas L, Chrissafis K, Krasia-Christoforou T (2012) ACS Appl Mater Inter 4:2139
Khalafalla S, Reimers G (1980) Magn, IEEE Trans Magn 16:178
Barikani M, Hepburn C (1986) Isocyanurate crosslinking as a means of producing thermally stable polyurethane elastomers. Cell Polym 5:169
Vaidyanathan G, Sendhilnathan S, Arulmurugan R (2007) J Magn Magn Mater 313:293
Drygas M, Janik JF (2012) Mater Chem Phys 133(2–3):932
Shamim N, Hong L, Hidajat K, Uddin M (2007) Colloids Surf B 55:51
Nyquist RA, Kagel RO (1971) Handbook of infrared and raman spectra of inorganic compounds and organic salts: infrared spectra of inorganic compounds. Academic Press, New York
Cheng FY, Su CH, Yang YS, Yeh CS, Tsai CY, Wu CL, Wu MT, Shieh DB (2005) Biomaterials 26:729
Chantrell R, Popplewell J, Charles S (1978) Magn IEEE Trans Magn 14:975
Zaitsev VS, Filimonov DS, Presnyakov IA, Gambino RJ, Chu B (1999) J Colloid Interf Sci 212:49
Shafi KVPM, Gedanken A, Prozorov R, Balogh J (1998) Chem Mater 10:3445
Lin CR, Chu YM, Wang SC (2006) Mater Lett 60:447
Goya G, Berquo T, Fonseca F, Morales M (2003) J Appl Phys 94:3520
Massart R (1981) IEEE Trans Magn 17:1247
Wang D, Zhang G, Zhang Y, Gao Y, Zhao Y, Zhou C, Zhang Q, Wang X (2007) J Appl Polym Sci 103:417
Menard KP (1999) Dynamic mechanical analysis. CRC Press, Boca Raton
Yeganeh H, Jamshidi H, Jamshidi S (2007) Polym Int 56:41
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This study was supported by Iran polymer and petrochemical institute (IPPI).
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Mohammadi, A., Barikani, M. & Barmar, M. Effect of surface modification of Fe3O4 nanoparticles on thermal and mechanical properties of magnetic polyurethane elastomer nanocomposites. J Mater Sci 48, 7493–7502 (2013). https://doi.org/10.1007/s10853-013-7563-7
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DOI: https://doi.org/10.1007/s10853-013-7563-7