Abstract
An advanced cation-exchange nano-composite poly-o-toluidine Ce(IV) phosphate was synthesized by sol–gel technique by incorporating Ce(IV) phosphate precipitate with the matrix of poly-o-toluidine. The material showed good ion-exchange behavior and used successfully in separation of metal ions. The conductivity of the composite was found within the range of 10−2 to 10−3 S/cm−1; measured by four-in-line probe DC electrical conductivity measuring technique. The conductivity is at the border of metallic and semiconductor region. Ion-exchange kinetics for few divalent metal ions was evaluated by particle diffusion-controlled ion-exchange phenomenon at four different temperatures. The particle diffusion mechanism is confirmed by the linear τ (dimensionless time parameter) versus t (time) plots. The exchange processes thus controlled by the diffusion within the exchanger particle for the systems studies herein. Some physical parameters like self-diffusion coefficient (D 0), energy of activation (E a), and entropy of activation (∆S°) have been evaluated under conditions favoring a particle diffusion-controlled mechanism.
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References
Khan AA, Niwas R (1998) J Chem Environ Res 7(3 & 4)
Khan AA, Alam MM, Mohammad F (2003) Electrochim Acta 48:2463
Khan AA, Alam MM (2003) J React Funct Polym 55:277
Khan AA, Khan A (2007) Talanta 73:850
Khan AA, Inamuddin, Alam MM (2005) J Mater Res Bull 40:289
Khan AA, Inamuddin (2006) Sens Actuat B 120:10
Khan AA, Inamuddin (2006) J React Funct Polym 66:1649
Khan AA, Inamuddin, Alam MM (2005) React Funct Polym 63:119
Khan AA, Alam MM (2003) Anal Chim Acta 504:253
Khan AA, Inamuddin, Akhtar T (2008) Anal Sci 24:881
Nabi SA, Alam Z, Inamuddin (2010) Desalination 250:515
Khan AA, Paquiza L, Khan A (2010) J Mater Sci 45:3610. doi:10.1007/s10853-010-4407-6
Khan AA, Khan A (2010) Cent Eur J Chem 8:396
Khan AA, Akhtar T (2011) Solid State Sci 13:559
Corce F, Gerace G, Dautzenberg G, Passerini GP, Appetecchi, Scrosati B (1994) Electrochim Acta 39:2187
Skotheim T (ed) (1986) Handbook of conducting polymers. Marcel Dekker, New York
MacDiarmid AG, Eptein A (1989) J Chem Soc 88:317
MacDiarmid AG, Eptein AJ, (1993) Conducting polymers, science and technology. Second Brazilian polymer conference, Plenum Publishing Corp, Brazil
Roth S, Graupner W (1993) Synth Met 57:3623
Xin-Guili, Hung Mei-Rong, Liu Rui (2005) React Funct Polym 2:285
Khan AA, Inamuddin, Alam MM (2005) Mater Res Bull 40:289
Reilly CN, Schmidt RW, Sadek FS (1959) J Chem Educ 36:555
Instruction Manual (2000) Scientific Equipment and Services, Roorkee
Mohammad F (2000) In: Nalwa HS (ed) Handbook of advanced electronic and photonic materials and devices. Academic Press, New York, p 321
Vermeulen T (1953) Eng Chem 45:1664
Helfferich F, Plesset MS (1958) J Chem Phys 28:418
Plesset MS, Helfferich F, Franklin JN (1958) J Chem Phys 29:1064
Barrer RM, Bertholomew RF, Rees LVC (1961) Phys Chem Solids 21:12
Acknowledgements
The authors are thankful to the Chairman, Department of Applied Chemistry, Z.H. College of Engineering and Technology, A.M.U. (Aligarh) and also to the U.G.C. funded research project for providing financial assistance.
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Khan, A.A., Akhtar, T. Cation-exchange kinetic studies on poly-o-toluidine Ce(IV) phosphate: a nano-composite and electrical conducting material. J Mater Sci 47, 3241–3247 (2012). https://doi.org/10.1007/s10853-011-6162-8
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DOI: https://doi.org/10.1007/s10853-011-6162-8