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Effect of electrophoretically deposited carbon nanotubes on the interface of carbon fiber reinforced epoxy composite

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Abstract

The interface between reinforcing fiber and matrix is a crucial element in composite performance. Homogeneous and interconnected carbon nanotubes (CNTs) were deposited onto the surface of carbon fibers to produce multiscale reinforcement by electrophoretic deposition (EPD). Single fiber tensile tests showed that the tensile strength and Weibull modulus of the resulting multiscale materials were increased by 16 and 41%, respectively. Compared with as-received carbon fibers, CNTs-deposited carbon fibers provided the decreased surface energy by 20% and the increased adhesion work by 22% using modified Wilhelmy method. Results from single fiber pull-out testing showed that a significant improvement (up to 68.8%) of interfacial shear strength was obtained for the composites containing by CNTs/Carbon fiber multiscale reinforcement. All results strongly suggest that EPD process can provide a feasible platform for improving interface properties of advanced composites.

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References

  1. Chand S (2000) J Mater Sci 35:1303. doi:10.1023/A:1004780301489

    Article  CAS  Google Scholar 

  2. Paiva M, Zhou B, Fernando K, Lin Y, Kennedy J, Sun YP (2004) Carbon 42:2849

    Article  CAS  Google Scholar 

  3. Liao L, Wang X, Fang P, Liew KM, Pan C (2011) ACS Appl Mater Inter 3:534

    Article  CAS  Google Scholar 

  4. Thostenson ET, Li C, Chou W (2005) Compos Sci Technol 65:491

    Article  CAS  Google Scholar 

  5. Qian H, Greenhalgh ES, Shaffer MSP, Bismarck A (2010) J Mater Chem 20:4751

    Article  CAS  Google Scholar 

  6. Thostenson ET, Li W, Wang D, Ren Z, Chou TW (2002) J Appl Phys 91:6034

    Article  CAS  Google Scholar 

  7. Naito K, Yang JM, Tanaka Y, Kagawa Y (2008) Appl Phys Lett 92:231912

    Article  Google Scholar 

  8. Zhang FH, Wang RG, He XD, Wang C, Ren LN (2009) J Mater Sci 44:3574. doi:10.1007/s10853-009-3484-x

    Article  CAS  Google Scholar 

  9. Vivet A, Doudou BB, Poilâne C, Chen J, Ayachi MH (2011) J Mater Sci 46:1322. doi:10.1007/s10853-010-4919-0

    Article  CAS  Google Scholar 

  10. Boccaccini AR, Cho J, Roether JA, Thomas BJC, Minay EJ, Shaffer MSP (2006) Carbon 44:3149

    Article  CAS  Google Scholar 

  11. Bekyarova E, Thostenson ET, Yu A, Kim H, Gao J, Tang J, Hahn HT, Chou TW, Itkis ME, Haddon RC (2007) Langmuir 23:3970

    Article  CAS  Google Scholar 

  12. Rodriguez AJ, Guzman ME, Lim CS, Minaie B (2010) Carbon 48:3256

    Article  CAS  Google Scholar 

  13. Schaefer JD, Rodriguez AJ, Guzman ME, Lim CS, Minaie B (2011) Carbon 49:2750

    Article  CAS  Google Scholar 

  14. Lee W, Lee SB, Choi O, Yi JW, Um MK, Byun JH, Thostenson ET, Chou TW (2010) J Mater Sci 46:2359. doi:10.1007/s10853-010-5082-3

    Article  Google Scholar 

  15. Zhang J, Zhuang R, Liu J, Mäder E, Heinrich G, Gao S (2010) Carbon 48:2273

    Article  CAS  Google Scholar 

  16. Shaffer MSP, Fan X, Windle A (1998) Carbon 36:1603

    Article  CAS  Google Scholar 

  17. Hu H, Yu A, Kim E, Zhao B, Itkis ME, Bekyarova E, Haddon RC (2005) J Phys Chem B 109:11520

    Article  CAS  Google Scholar 

  18. Naito K, Tanaka Y, Yang JM, Kagawa Y (2008) Carbon 46:189

    Article  CAS  Google Scholar 

  19. Miller B, Muri P, Rebenfeld L (1987) Compos Sci Technol 28:17

    Article  CAS  Google Scholar 

  20. Laachachi A, Vivet A, Nouet G, Doudou BB, Poilâne C, Chen J (2008) Mater Lett 62:394

    Article  CAS  Google Scholar 

  21. Zhao ZG, Ci LJ, Cheng HM, Bai JB (2005) Carbon 43:651

    Article  Google Scholar 

  22. Qian H, Bismarck A, Greenhalgh ES, Shaffer MSP (2010) Carbon 48:277

    Article  CAS  Google Scholar 

  23. Zhao F, Huang Y (2011) J Mater Chem 21:2867

    Article  CAS  Google Scholar 

  24. Qian H, Bismarck A, Greenhalgh ES, Shaffer MSP (2010) Compos Sci Technol 70:393

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This study was supported by the carbon company-SGL Group (2011WT104). The authors thank Dr. Liu Li (Harbin Institute of Technology) for her assistance on the single fiber pull-out testing and valuable discussions.

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Correspondence to Chunxiang Lu.

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Guo, J., Lu, C. & An, F. Effect of electrophoretically deposited carbon nanotubes on the interface of carbon fiber reinforced epoxy composite. J Mater Sci 47, 2831–2836 (2012). https://doi.org/10.1007/s10853-011-6112-5

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  • DOI: https://doi.org/10.1007/s10853-011-6112-5

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