Journal of Materials Science

, Volume 46, Issue 12, pp 4349–4353 | Cite as

Inversed solid-phase grain boundary wetting in the Al–Zn system

  • S. G. Protasova
  • O. A. Kogtenkova
  • B. B. Straumal
  • P. Zięba
  • B. Baretzky
IIB 2010


The microstructure of binary Al–10 at% Zn and Al–15 at% Zn alloys after long anneals (800–4000 h) was studied between 190 and 258 °C. The contact angles between (Zn) particles and (Al)/(Al) grain boundaries (GBs) were measured. They decrease with decreasing temperature. First (Al)/(Al) GBs completely wetted by the second solid phase (Zn) appear below T wsAl0% = 205 ± 5 °C. Above T wsAl0% = 205 ± 5 °C all (Al)/(Al) GBs are incompletely wetted by (Zn) solid phase. The extrapolation of the maximal contact angle θ to zero permits to obtain the T wsAl100% = 125 ± 10 °C. Below this line all (Al)/(Al) GBs has to be completely wetted by (Zn) solid phase.


Contact Angle Triple Junction Transmission Electron Microcopy Bulk Phase Diagram Metastable Liquid Phase 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



Authors thank the Russian Foundation for Basic Research (contract 09-03-92481) and Israel Ministry of Science (project 3-5790) and the Program of bilateral cooperation between Russian and Polish Academies of Sciences for the financial support. Authors cordially thank Prof. E. Rabkin, Prof. R. Valiev, Prof. T. Langdon and Dr. A. Mazilkin for stimulating discussions, Mr. A. Nekrasov for the help with SEM and EPMA measurements.


  1. 1.
    Cahn JW (1977) J Chem Phys 66:3667CrossRefGoogle Scholar
  2. 2.
    Ebner C, Saam WF (1977) Phys Rev Lett 38:1486CrossRefGoogle Scholar
  3. 3.
    Eustathopoulos N (1983) Int Met Rev 28:189Google Scholar
  4. 4.
    Straumal B, Muschik T, Gust W, Predel B (1992) Acta Metal Mater 40:939CrossRefGoogle Scholar
  5. 5.
    Straumal B, Molodov D, Gust W (1995) Interface Sci 3:127CrossRefGoogle Scholar
  6. 6.
    Straumal BB (2003) Grain boundary phase transitions. Nauka, Moscow (in Russian)Google Scholar
  7. 7.
    López GA, Mittemeijer EJ, Straumal BB (2004) Acta Mater 52:4537CrossRefGoogle Scholar
  8. 8.
    Straumal BB, Baretzky B, Kogtenkova OA et al (2010) J Mater Sci 45:2057. doi: 10.1007/s10853-009-4014-6 CrossRefGoogle Scholar
  9. 9.
    Straumal BB, Kogtenkova OA, Straumal AB et al (2010) J Mater Sci 45:4271. doi: 10.1007/s10853-010-4377-8 CrossRefGoogle Scholar
  10. 10.
    Rabkin EI, Semenov VN, Shvindlerman LS et al (1991) Acta Metall Mater 39:627CrossRefGoogle Scholar
  11. 11.
    Noskovich OI, Rabkin EI, Semenov VN et al (1991) Acta Metall Mater 39:3091CrossRefGoogle Scholar
  12. 12.
    Straumal BB, Noskovich OI, Semenov VN et al (1992) Acta Metall Mater 40:795CrossRefGoogle Scholar
  13. 13.
    Straumal B, Rabkin E, Lojkowski W et al (1997) Acta Mater 45:1931CrossRefGoogle Scholar
  14. 14.
    Straumal BB, Gornakova AS, Kogtenkova OA et al (2008) Phys Rev B 78:054202CrossRefGoogle Scholar
  15. 15.
    Straumal B, Valiev R, Kogtenkova O et al (2008) Acta Mater 56:6123CrossRefGoogle Scholar
  16. 16.
    Straumal BB, Kogtenkova O, Zięba P (2008) Acta Mater 56:925CrossRefGoogle Scholar
  17. 17.
    Straumal B, Kogtenkova O, Protasova S et al (2008) Mater Sci Eng A 495:126CrossRefGoogle Scholar
  18. 18.
    Valiev RZ, Murashkin MY, Kilmametov A et al (2010) J Mater Sci 45:4718. doi: 10.1007/s10853-010-4588-z CrossRefGoogle Scholar
  19. 19.
    Massalski TB (ed) (1990) Binary alloy phase diagrams, 2nd edn. ASM International, Materials Park, p 238Google Scholar
  20. 20.
    Straumal B, López G, Gust W, Mittemeijer E (2004) In: Zehetbauer MJ, Valiev RZ (eds) Nanomaterials by severe plastic deformation. Fundamentals–processing–applications. Wiley, VCH Weinheim, p 642Google Scholar
  21. 21.
    Wynblatt P, Saul A, Chatain D (1998) Acta Mater 46:2337CrossRefGoogle Scholar
  22. 22.
    Wynblatt P, Chatain D (2008) Mater Sci Eng A 495:119CrossRefGoogle Scholar
  23. 23.
    Bishop CM, Tang M, Cannon RM, Carter WC (2006) Mater Sci Eng A 422:102CrossRefGoogle Scholar
  24. 24.
    Luo J (2008) Curr Opin Sol State Mater Sci 12:81CrossRefGoogle Scholar
  25. 25.
    Gupta VK, Yoon DH, Meyer HM et al (2007) Acta Mater 55:3131CrossRefGoogle Scholar
  26. 26.
    Luo J, Gupta VK, Yoon DH et al (2005) Appl Phys Lett 87:231902CrossRefGoogle Scholar
  27. 27.
    Luo J, Chiang Y-M (2008) Ann Rev Mater Res 38:227CrossRefGoogle Scholar
  28. 28.
    Luo J, Dillon SJ, Harmer MP (2009) Microsc Today 17:22CrossRefGoogle Scholar
  29. 29.
    Cho J, Wang CM, Chan HM, Rickman JM, Harmer MP (2002) J Mater Sci 37:59. doi: 10.1023/A:1013185506017 CrossRefGoogle Scholar
  30. 30.
    Dillon SJ, Tang M, Carter WC, Harmer MP (2007) Acta Mater 55:6208CrossRefGoogle Scholar
  31. 31.
    Dillon SJ, Harmer MP (2007) Acta Mater 55:5247CrossRefGoogle Scholar
  32. 32.
    Dillon SJ, Harmer MP (2008) J Eur Cer Soc 28:1485CrossRefGoogle Scholar
  33. 33.
    Baram M, Kaplan WD (2006) J Mater Sci 41:7775. doi: 10.1007/s10853-006-0897-7 CrossRefGoogle Scholar
  34. 34.
    Sadan H, Kaplan WD (2006) J Mater Sci 41:5099. doi: 10.1007/s10853-006-0437-5 CrossRefGoogle Scholar
  35. 35.
    Levi G, Kaplan WD (2006) J Mater Sci 41:817. doi: 10.1007/s10853-006-6565-0 CrossRefGoogle Scholar
  36. 36.
    Straumal BB, Mazilkin AA, Kogtenkova OA et al (2007) Phil Mag Lett 87:423CrossRefGoogle Scholar
  37. 37.
    Straumal B, Valiev R, Kogtenkova O et al (2008) Acta Mater 56:6123CrossRefGoogle Scholar
  38. 38.
    Divinski SV, Lohmann M, Chr Herzig et al (2005) Phys Rev B 71:104104CrossRefGoogle Scholar
  39. 39.
    Chang L-S, Rabkin E, Straumal BB et al (1999) Acta Mater 47:4041CrossRefGoogle Scholar
  40. 40.
    Straumal BB, Polyakov SA, Chang L-S et al (2007) Int J Mater Res 98:451Google Scholar
  41. 41.
    Straumal B, Prokofjev SI, Chang L-S et al (2001) Def Diff Forum 194:1343CrossRefGoogle Scholar
  42. 42.
    Molodov DA, Czubayko U, Gottstein G et al (1995) Phil Mag Lett 72:361CrossRefGoogle Scholar
  43. 43.
    Schölhammer J, Baretzky B, Gust W et al (2001) Interf Sci 9:43CrossRefGoogle Scholar
  44. 44.
    Straumal B, Sluchanko NE, Gust W (2001) Def Diff Forum 188:185CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • S. G. Protasova
    • 1
    • 2
  • O. A. Kogtenkova
    • 1
  • B. B. Straumal
    • 1
    • 2
    • 4
  • P. Zięba
    • 3
  • B. Baretzky
    • 4
  1. 1.Institute of Solid State Physics Russian Academy of SciencesChernogolovkaRussia
  2. 2.Max-Planck Institut für MetallforschungStuttgartGermany
  3. 3.Institute of Metallurgy and Materials Science, Polish Academy of SciencesCracowPoland
  4. 4.Karlsruher Institut für Technologie (KIT), Institut für NanotechnologieEggenstein-LeopoldshafenGermany

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