Abstract
A new type of paper with superhydrophobic surface was prepared by addition of modified nano-TiO2 to cellulose pulp. Nano-TiO2 powder was first dispersed with a high-speed homogenizer, followed by surface modification with the coupling agent, 3-(trimethoxysilyl) propyl methacrylate (MPS). The superhydrophobic and opaque paper was obtained by adding the modified nano-TiO2 to plant fiber to change its characteristics from hydrophilic to hydrophobic. The effects of the initial content of the coupling agent MPS used, on the weight percentage of MPS attached on the surface of nano-TiO2 were studied. The obtained paper was characterized by contact angle measurements and SEM. The results showed that the water contact angles for the modified paper ranged from 126.5 to 154.2°, and the sliding angle was <3°. Moreover, many well-dispersed nano-TiO2 protuberances were observed on the surface of the paper, which further confirmed that the obtained paper was superhydrophobic on account of its nanostructure. Comparative optical studies performed on the paper handsheets revealed a much higher opacity for the sample with the MPS-modified-TiO2 nanoparticles.
Similar content being viewed by others
References
Sjostrom E (1993) Wood chemistry—fundamentals and applications. Academic Press, London
Klemm D, Heublein B, Fink HP, Bohn A (2005) Angew Chem Int Ed Engl 44:3358
Balu B, Kim JS, Breedveld V, Hess DW (2009) J Adhes Sci Technol 20:361
Balu B, Breedveld V, Hess DW (2008) Langmuir 24:4785
Balu B, Berry AD, Hess DW, Breedveld V (2009) Lab Chip 9:3066
Can Q, Werner O, Lars W, Charlotta T (2009) J Supercrit Fluid 49:117
Zou JH, Chen H, Anindarupa C, Yu Y, Huo Q, Lei Z (2008) Adv Mater 20:3337
Hu ZS, Zen XY, Gong J, Deng Y (2009) Colloid Surf A 351:65
Oskar W, Can Q, Charlotta T, Bert P, Lars W (2010) Cellulose 17:187
Bruzewicz DA, Meital R, George MW (2008) Anal Chem 80:3387
Yang H (2008) J Colloid Interf Sci 325:588
Roberts JC (1996) Paper chemistry, 2nd edn. Backi Academic and Professional, Glasgow
Neimo L (ed) (1999) Papermaking science technology: papermaking chemistry. Fapet Oy, Helsinki
Rong Y, Chen HZ, Wu G, Wang M (2005) Mater Chem Phys 91:370
Bedri E, Hunsicker RA, Simmons GW, Sudol ED, Dimonie VL, El-Aasser MS (2001) Langmuir 17:2269
Bauer F, Glasel HJ, Decker U, Ernst H, Freyer A, Hartmann E, Sauerland V, Mehnert R (2003) Prog Org Coat 47:147
Erhan S (2009) J Biomech 3:19
Tsafack MJ, Levalois-Grutzmacher J (2006) Surf Coat Technol 200:3503
Nitta SV, Pisupatti V, Jain A, Wayner PC Jr, Gill WN, Plawsky JL (1999) J Vac Sci Technol B 17(1):205
Antonow D, Graebin CS, Eifler-Lima VL (2004) J Braz Chem Soc 5:782
Matos MC, Ilharco LM, Almeida RM (1992) J Non-Cryst Solids 147:232
Guerra RM, Duran P, Ortiz (2008) J Oral Rehabil 23:632
Rueggeberg F, Hashinger DT, Fairhurst CW (1990) Dent Mater 6:241
Primeau N, Vautey C, Langlet M (1997) Thin Solid Films 310:47
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Huang, L., Chen, K., Lin, C. et al. Fabrication and characterization of superhydrophobic high opacity paper with titanium dioxide nanoparticles. J Mater Sci 46, 2600–2605 (2011). https://doi.org/10.1007/s10853-010-5112-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-010-5112-1