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Journal of Materials Science

, Volume 45, Issue 23, pp 6467–6473 | Cite as

Synthesis, phase transition, and magnetic property of iron oxide materials: effect of sodium hydroxide concentrations

  • Xiaohui Guo
  • Shengliang Zhong
  • Ji Zhang
  • Wanv Wang
  • JianJiang Mao
  • Gang Xie
Article

Abstract

In this paper, a class of novel iron oxide particles has been fabricated through surfactant-directed structure approach in hydrothermal reaction. The obtained iron oxide nanostructures with distinct morphologies, such as rhombohedra, octahedral, plate-like, as well as dendritic, can be obtained by gradually increasing the concentrations of NaOH. The as-prepared iron oxide particles were characterized utilizing scanning electronic microscopy (SEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Results reveal that the as-made particles, such as rhombohedra and octahedral, can be indexed as pure rhombohedral phase of hematite and show better single crystalline feature. In contrast, when NaOH concentrations are 1.05 and 6 M, respectively, we accordingly can obtain novel flake-like and dendrtic superstructure that possess a mean arm length of ~1.5 μm; both the as-made two samples can be easily indexed as a mixture of hematite and maghemite based on their XRD and TEM results. Additionally, it was found that the obtained iron oxide samples at different NaOH concentrations show obviously morphologies-dependent feature. Namely, the as-made samples can undergo transition from typical ferromagnetic to ferrimagnetic behavior when the NaOH concentrations are gradually increased. In general, the presented synthesis approach could be extended to prepare other metal oxides with specific morphology and structure.

Keywords

Iron Oxide Hematite Maghemite Iron Oxide Particle Sodium Hydroxide Concentration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

This work was supported by China Postdoctoral Scientific Fund (No. 20070420085), Research startup fund of northwest University (No. PR09047), Education committee of Shanxi Province (Grant No. 09JS089), and the National base Science cultivate Foundation of China (No. J0830417).

Supplementary material

10853_2010_4733_MOESM1_ESM.doc (2 mb)
Supplementary material 1 (DOC 2074 kb)

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Xiaohui Guo
    • 1
  • Shengliang Zhong
    • 2
  • Ji Zhang
    • 1
  • Wanv Wang
    • 1
  • JianJiang Mao
    • 3
  • Gang Xie
    • 1
  1. 1.Key Lab of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, The College of Chemical & Materials ScienceNorthwest University of ChinaXi’anPeople’s Republic of China
  2. 2.The College of Chemistry & ChemicalJiangxi Normal UniversityNanchang CityChina
  3. 3.Department of ChemistryFudan UniversityShanghaiPeople’s Republic of China

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