Journal of Materials Science

, Volume 45, Issue 23, pp 6417–6423 | Cite as

Synthesis and photoluminescence of Eu-doped Zn/Al layered double hydroxides



Eu-doped ZnAl-layered double hydroxides (ZnAl–LDHs) with various Zn2+/(Al3++Eu3+) molar ratios from 1:1, 2:1, 3:1, to 4:1 were first synthesized by the coprecipitation method at room temperature and the Eu3+/Al3+ molar ratio of 0.06 was almost maintained. The obtained solids were characterized by powder X-ray diffraction (XRD), photoluminescent spectrum (PL), scanning electron microscope (SEM), infrared spectroscopy (IR), and thermogravimetric (TG) analysis. XRD results show that the crystallinity of the Eu-doped products gradually was improved when the Zn2+/(Al3++Eu3+) molar ratio was higher than 2. The photoluminescent spectra of the Eu-doped ZnAl–LDHs are described by the well-known 5 D 07 F J transition (J = 1, 2, 3, 4) of Eu3+ ions with the strongest emission for J = 2.


Layered Double Hydroxide Hydrotalcite Coprecipitation Method Interlayer Water EuCl3 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



The Project Supported by the National Natural Science Foundation of China (50902067), the Natural Science Foundation of Jiangxi Province (2007GZC1727 and 2008GQH0046), and Program for Innovative Research Team in University of Jiangxi Province.


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© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  1. 1.Department of ChemistryNanchang UniversityNanchangChina
  2. 2.Institute of Polymers Nanchang UniversityNanchangChina

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