Abstract
The electrochemical corrosion behavior of finemet alloy at various heat treatment temperatures was investigated. Thermal behavior and structural changes were studied using differential scanning calorimetry and X-ray diffractometry, respectively. The electrochemical corrosion of amorphous and annealed samples was investigated in 0.10 M NaOH solution using electrochemical impedance spectroscopy and linear sweep voltammetery. Changes in morphology of the samples before and after corrosion were characterized using optical microscope. The results showed that structural relaxation and nanocrystallization during the heat treatment improved corrosion behavior of the alloy. The heat-treated alloy at 650 °C showed a corrosion rate of 1.37 × 10−8 A cm−2 and a positive shift of +417 mV in the corrosion potential compared to the amorphous alloy. Also, the heat-treated alloy at 650 °C showed a higher charge transfer resistance up to 50 kΩ due to corrosion resistance, compared with amorphous sample that showed a charge transfer resistance of 0.5 kΩ.
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Cheng JB, Liang XB, Xu BS, Wu YX (2009) J Mater Sci 44:3356. doi:https://doi.org/10.1007/s10853-009-3436-5
Fujii H, Yardley VA, Matsuzaki T, Tsurekawa S (2008) J Mater Sci 43:3837. doi:https://doi.org/10.1007/s10853-007-2220-7
Zhang YR, Ramanujan RV (2006) J Mater Sci 41:5292. doi:https://doi.org/10.1007/s10853-006-0263-9
Yoshizawa Y, Oguma S, Yamauchi K (1988) J Appl Phys 64:6044
McHenry ME, Willard MA, Laughlin DE (1999) Prog Mater Sci 44:291
Herzer G (1996) J Magn Magn Mater 157–158:133
Herzer G (1997) Handbook of magnetic materials, vol 10. Elsevier, Amsterdam, pp 417–461
Souza CAC, Politi FS, May JE, Kuri SE, Kiminami CS (1999) J Non-Cryst Solids 247:69
May JE, Souza CAC, Morelli CL, Mariano NA, Kuri SE (2005) J Alloys Compd 390:106
Mariano NA, Souza CAC, May JE, Kuri SE (2003) Mater Sci Eng 354:1–5
Petzold J (2002) J Magn Magn Mater 242–245:84
Hasegawa R (2006) J Magn Magn Mater 304:187
Altube A et al (2003) Corros Sci 45:685
Vara G et al (2007) J Non-Cryst Solids 353:1008
Marzo FF et al (2007) J Non-Cryst Solids 353:875
Marzo FF et al (2002) Electrochim Acta 47:2265
Altube A, Pierna AR (2004) Electrochim Acta 49:303
Rammelt U, Reinhard G (1988) Electrochim Acta 35–6:L199
Park JR, Macdonald DD (1983) Corros Sci 23:295
Garcia JA et al (2006) J Non-Cryst Solids 352:5118
Fiorillo F (2004) Measurement and characterization of magnetic materials. Elsevier, Amsterdam, pp 51–60
Kaevitser EV (2004) Mater Sci Eng A 375–377:683
Macdonald DD, Mckubre MCH (1982) Modern aspects of electrochemistry, vol 14. Plenum Press, New York, p 61
Miguel C, Kaloshkin S, Gonzalez J, Zhukov A (2003) J Non-Cryst Solids 329:63
Lovas A, Kiss LF, Balogh I (2000) J Magn Magn Mater 215–216:463
Poole CP (2003) Introduction to nanotechnology. Wiley, Hoboken, NJ, p 147
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Shivaee, H.A., Golikand, A.N., Hosseini, H.R.M. et al. Influence of annealing on the electrochemical behavior of finemet amorphous and nanocrystalline alloy. J Mater Sci 45, 546–551 (2010). https://doi.org/10.1007/s10853-009-3972-z
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DOI: https://doi.org/10.1007/s10853-009-3972-z