Abstract
Some typical worm-like mesoporous non-silica oxides, titania, zirconia, and dopants-incorporated zirconia oxides, with homogeneous nanocrystalline framework and narrow pore-size distribution have been synthesized via a facile process templated from composite surfactant of a long chain poly block copolymer combined with non-ionic alkyl-PEO surfactant (Brij56) under the hydrothermal condition. Bi- or even multi-component zirconia-based composites with further addition of other oxide compositions can also be obtained with well-defined mesoporous structure and nanocrystalline framework. These mesostructured oxides/composite oxides show high surface area, well-crystallization framework, and high thermal stability. XRD, nitrogen adsorption analysis, TEM, and EDX were used for the structural characterizations. The use of non-ionic block-copolymer surfactant is believed to be responsible for the crystallization of mesoporous framework and high thermal stability at high temperature without structural collapse.
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Acknowledgements
We gratefully acknowledge the financial support from the National Natural Science Foundation of China with Contract 50872140, the State Scientific & Technological Supporting Project (2007BAJ03B01), and Shanghai standard project (08DZ05020000).
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Chen, H., Yan, J., Ye, Z. et al. One pot synthesis of mesostructured non-silica oxides nanocrystallites. J Mater Sci 44, 6531–6537 (2009). https://doi.org/10.1007/s10853-009-3598-1
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DOI: https://doi.org/10.1007/s10853-009-3598-1