Abstract
A new class of ionomer was developed through sulfonation of the metallocene-based poly(ethylene–octene) elastomer, followed by its neutralization with zinc acetate. Ionomeric products were characterized through Fourier transform infrared (FT-IR) spectroscopy, small angle X-ray scattering (SAXS), and transmission electron microscopy (TEM) studies. The effect of pendant chain length on the ionomeric modification was also studied through the variation of the comonomer. The impact of these ionomeric modifications on various physico-mechanical properties was thoroughly investigated by using differential scanning calorimetry, mechanical, dynamic mechanical, and thermogravimetric analysis. The resultant properties were correlated with structures of the modified elastomers. Ionomerisation of the base elastomers causes a significant improvement in the stress–strain, as well as the thermal properties compared to the corresponding pristine elastomer.
Similar content being viewed by others
References
Meister JJ (2000) Polymer modification—principles, techniques and applications. CRC Press, New York
Wakabayashi K, Register RA (2006) Macromolecules 39:1079
Lantman CW, MacKnight WJ, Lundberg RD (1989) Annu Rev Mater Sci 19:295
Eisenberg A, King M (1977) Ion-containing polymers: physical properties and structure. Academic Press, New York
Wilson AD (1983) Developments in ionic polymers. Applied Science, London
Hwang YC, Chum S, Sehanobish K (1994) ANTEC 94:3414
Singh RP (1992) Prog Polym Sci 17:251
Biswas A, Bandyopadhyay A, Singha NK, Bhowmick AK (2008) J Polym Sci A: Polym Chem 46:8023
Wouters MEL (2000) Ionomeric Thermoplastic Elastomers based on Ethylene-Propylene Copolymers. Thesis, Technische Universiteit Eindhoven, Eindhoven, p 28, ISBN 90-386-3051-4
Socrates G (1980) Infrared characteristic group frequencies. Wiley, New York, p 112
Kar KK, Bhowmick AK (2001) In: Bhowmick AK, Stephens HL (eds) Handbook of elastomers—new developments & technology. Marcel Dekker Inc., New York
Socrates G (1980) Infrared characteristic group frequencies. Wiley, New York, p 116
Wouters MEL (2000) Ionomeric Thermoplastic Elastomers based on Ethylene-Propylene Copolymers. Thesis, Technische Universiteit Eindhoven, Eindhoven, p 58, ISBN 90–386-3051–4
Yarusso DJ, Cooper SL (1983) Macromolecules 16:1871
Ghosh SK, De PP, Khasgir D, De SK (2000) J Appl Polym Sci 77:816
Author information
Authors and Affiliations
Corresponding author
Additional information
Anjan Biswas is on leave from Government College of Engineering and Leather Technology, LB Block, Sector III, Saltlake City, Kolkata-700098, India.
Rights and permissions
About this article
Cite this article
Biswas, A., Bandyopadhyay, A., Singha, N.K. et al. Ionomeric modification of metallocene-based polyolefinic elastomers with varied pendant chain length and its influence on physico-mechanical properties. J Mater Sci 44, 3125–3134 (2009). https://doi.org/10.1007/s10853-009-3415-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-009-3415-x