SiC nanofibers by pyrolysis of electrospun preceramic polymers
- 700 Downloads
Silicon carbide (SiC) nanofibers of diameters as low as 20 nm are reported. The fibers were produced through the electrostatic spinning of the preceramic poly(carbomethylsilane) with pyrolysis to ceramic. A new technique was used where the preceramic was blended with polystyrene and, subsequent to electrospinning, was exposed to UV to crosslink the PS and prevent fiber flowing during pyrolysis. Electrospun SiC fibers were characterized by Fourier transform infrared spectroscopy, thermo gravimetric analysis-differential thermal analysis, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and electron diffraction. Fibers were shown to be polycrystalline and nanograined with β-SiC 4H polytype being dominant, where commercial methods produce α-SiC 3C. Pyrolysis of the bulk polymer blend to SiC produced α-SiC 15R as the dominant polytype with larger grains showing that electrospinning nanofibers affects resultant crystallinity. Fibers produced were shown to have a core–shell structure of an oxide scale that was variable by pyrolysis conditions.
KeywordsPyrolysis Field Emission Scan Electron Microscopy Fiber Diameter Electrospun Fiber Electrospinning Process
This study was partially supported by the Air Force Office of Scientific Research Grant #F49620-04-NA-153 and the National Science Foundation through the Graduate Assistantship in Areas of National Need. The authors would also like to thank Kent Van Every for help with the FESEM and Prof. Eric Stach with help with TEM.
- 2.Formhals A (1934) US Patent 1975504Google Scholar
- 12.Jaeger R, Bergshoef MM, Batlle CMI, Schonherr H, Vancso GJ (1998) Macromol Symp 127:141Google Scholar
- 15.Krauthauser C, Deitzel JM, Wetze ED, O’Brien D (2003) Abstr Pap Am Chem Soc 226:U442Google Scholar
- 24.Li J, Zhang Y, Zhong X, Yang K, Meng J, Cao X (2007) Nanotechnology 18Google Scholar
- 32.Odian G (2004) Principles of polymerization, 4th edn. Wiley, Hoboken, NJ, p 174Google Scholar
- 34.JCPDS Card File Number 75–2078Google Scholar
- 35.Sandlin MS (1991) Master of Science. Purdue University, West Lafayette, INGoogle Scholar
- 36.JCPDS Card File Number 29–1127Google Scholar
- 37.Chiang YM, Smyth IP, Terwilliger CD, Petuskey WT, Eastman JA (1992) Nanostruct Mater 1:235Google Scholar