Abstract
Mixed oxides in the binary Y2O3–CeO2 (YC) and ternary Y2O3–CeO2–TiO2 (YCT) systems as well as the corresponding Ni cermets were evaluated in terms of application as anodes in solid oxide fuel cells (SOFCs) between 650 and 900 °C. X-ray diffraction (XRD) analysis of the YCT powders calcined up to 1,400 °C showed the cubic fluorite structure of YC and also the formation of an additional phase with pyrochlore structure. The thermal expansion of the ceramics measured in air and Ar/4% H2 showed no significant differences in the temperature range of 25–800 °C. The absolute values of the total electrical conductivity of the ceramics measured between 450 and 900 °C in Ar/4% H2 increased by about 1–2 orders of magnitude compared to those measured in air. Ni/Y0.20Ce0.80O1.9 and Ni/Y0.20C0.75Ti0.05O1.9 cermets with 40 vol% Ni exhibited improved long-term stability regarding their electrical conductivity after annealing at 1,000 °C. The diffusion coefficient of Ce in the 8YSZ electrolyte was measured by compatibility tests. Electrochemical measurements on single SOFCs showed high polarization resistance at the anode/electrolyte interface.
Similar content being viewed by others
References
Uchida H, Suzuki H, Watanabe M (1998) J Electrochem Soc 145:615
Marina OA, Primdahl S, Bagger C, Mogensen M (1997) In: Stimming U et al (eds) Proceedings of the 5th International Symposium on SOFC, The Electrochemical Society, vol 18, p 540
Mitsuyasu H, Nonaka Y, Eguchi K (1998) Solid State Ionics 113–115:279
Shannon RD (1976) Acta Crystalogr A32:751
Tietz F, Jungen W, Lersch P, Figaj M, Becker KD, Skarmoutsos D (2002) Chem Mater 14:2252
Armstrong TR, Stevenson JW, Pederson LR, Raney PE (1996) J Electrochem Soc 143:2919
Mantzouris X, Zouvelou N, Haanappel VAC, Tietz F, Nikolopoulos P (2007) J Mater Sci 42:10152. doi:https://doi.org/10.1007/s10853-007-2099-3
Mertens J, Haanappel VAC, Tropartz C, Herzhof W, Buchkremer HP (2006) J Fuel Cell Sci Technol 3:125
Zhang TS, Ma J, Huang HT, Hing P, Xia ZT, Chan SH, Kilner JA (2003) Solid State Sci 5:1505
Longo V, Podda L (1981) J Mater Sci Lett 16:839
Uematsu K, Shinozaki K, Sakurai O, Mizutani N, Kato M (1979) J Am Ceram Soc 62:219
Skarmoutsos D, Tietz F, Nikolopoulos P (2001) Fuel Cells 1:243
Sigalovsky J, Haggerty J, Sheehan J, Reynolds G (1996) Ceram Eng Sci Proc 17:322
Mogensen G, Mogensen M (1993) Thermochim Acta 214:47
Skarmoutsos D, Nikolopoulos P, Tietz F, Vinke IC (2004) Solid State Ionics 170:153
Tuller HL, Nowick AS (1975) J Electrochem Soc 122:255
Yamaguchi S, Kobayashi K, Abe K, Yamazaki S, Iguchi Y (1998) Solid State Ionics 113–115:393
Yahiro H, Eguchi K, Arai H (1986) Solid State Ionics 21:37
Eguchi K, Setoguchi T, Inoue T, Arai H (1992) Solid State Ionics 52:165
Yahiro H, Baba Y, Eguchi K, Arai H (1988) J Electrochem Soc 135:2077
Van Herle J, Horita T, Kawada T, Sakai N, Yokokawa H, Dokiya M (1996) Solid State Ionics 86–88:1255
Peng R, Xia C, Liu X, Peng D, Meng G (2002) Solid State Ionics 152–153:561
Tianshu Z, Hing P, Huang H, Kilner J (2002) Solid State Ionics 148:567
Tuller HL, Nowick AS (1977) J Phys Chem Solids 38:859
Levy M, Fouletier J, Kleitz M (1980) J de Physique Colloque C6 41:335
Arai H, Kunisaki T, Shimizu Y, Seiyama T (1986) Solid State Ionics 20:241
Wang S, Kobayashi T, Dokiya M, Hashimoto T (2000) J Electrochem Soc 147:3606
Zouvelou N, Mantzouris X, Nikolopoulos P (2007) Int J Adhes Adhes 27:380
Mantzouris X, Zouvelou N, Skarmoutsos D, Nikolopoulos P, Tietz F (2005) J Mater Sci 40:2471. doi:https://doi.org/10.1007/s10853-005-1977-9
Eustathopoulos N, Drevet B (1998) Mater Sci Eng A249:176
Mogensen M, Lindegaard T, Hansen UR, Mogensen G (1994) J Electrochem Soc 141:2122
Tsoga A, Naoumidis A, Stöver D (2000) Solid State Ionics 135:403
Mai A, Haanappel VAC, Tietz F, Stöver D (2006) Solid State Ionics 177:2103
Bekale VM, Legros C, Sattonnay G, Huntz AM, Lesage B, Argirusis C, Jomard F (2006) Defect Diffus Forum 258–260:46
Tietz F, Wessel E (2002) In: Huijsmans J (ed) Proceedings of the 5th European SOFC Forum, European Fuel Cell Forum, Oberrohrdorf, Switzerland, vol 2, p 814
Acknowledgement
Financial support from the European Commission within the EU Integrated Project REALSOFC (Project No. SES6-CT-2003-50261) is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mantzouris, X., Triantafyllou, G., Tietz, F. et al. Physical characterization of Y2O3–CeO2–TiO2 (YCT) mixed oxides and Ni/YCT cermets as anodes in solid oxide fuel cells. J Mater Sci 43, 7057–7065 (2008). https://doi.org/10.1007/s10853-008-3063-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-008-3063-6