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Spectroscopic and quantum chemical investigation of the 4Bi2O3 · B2O3 glass structure

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Abstract

The structural properties of the 4Bi2O3 · B2O3 glass were investigated by FT-IR spectroscopy and quantum chemical calculations. The main results reveal that the coordination polyhedrons of the bismuth ion from the [BiO6] structural units and of the boron ion from the [BO4] groups are irregular. Accordingly, the [BiO6] and [BO4] structural units in the studied glass matrix have a complex structural role that makes possible the formation of the vitreous system.

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Authors and Affiliations

  1. Department of Physics, Technical University of Cluj-Napoca, 400641, Cluj-Napoca, Romania

    S. Rada, E. Culea & V. Rus

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  1. S. Rada
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  2. E. Culea
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  3. V. Rus
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Correspondence to S. Rada.

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Rada, S., Culea, E. & Rus, V. Spectroscopic and quantum chemical investigation of the 4Bi2O3 · B2O3 glass structure. J Mater Sci 43, 6094–6098 (2008). https://doi.org/10.1007/s10853-008-2949-7

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  • DOI: https://doi.org/10.1007/s10853-008-2949-7

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