Abstract
The mechanical properties of metals with bcc structure, such as niobium and its alloys, have changed significantly with the introduction of heavy interstitial elements. These interstitial elements (nitrogen, for example), present in the alloy, occupy octahedral sites and constitute an elastic dipole of tetragonal symmetry and might produce anelastic relaxation. This article presents the effect of nitrogen on the anelastic properties of Nb-1.0 wt% Zr alloys, measured by means of mechanical spectroscopy using a torsion pendulum. The results showed complex anelastic relaxation structures, which were resolved into their constituent peaks, representing each relaxation process. These processes are due to stress-induced ordering of the interstitial elements around the niobium and zirconium of the alloy.
Similar content being viewed by others
References
Nowick AS, Berry BS (1972) Anelastic relaxation in crystalline solids. Academic Press, New York
Snoek JL (1939) Physica 6:591
Szkopiak ZC, Smith JT (1975) J Phys D 8:1273
Weller M (1995) J Phys IV 5:199
Schaller R, Fantozzi G, Gremaud G (2001) Mechanical spectroscopy. Trans Tech Publications, Lausanne
Raymond JF, Rex BM (1978) Mat Sci Eng 33:113
Haneczok G, Rasek J (2001) Defect Diff Forum 3:188
Bunn PM, Cummings DG, Leavenworth HW Jr (1962) J Appl Phys 33:3009
Hasson DF, Arsenault RJ (1972) Treatise on materials science. Academic Press, New York
Botta Fo WJ, Grandini CR, Florêncio O, Tejima H, Jordão JAR (1990) Acta Metall Mater 38:391
Florêncio O, Silva Jr PS, Botta Fo WJ, Grandini CR (2003) Mat Res 6:541
Grandini CR (2002) Rev Bras Apl Vácuo 19:13
Florêncio O, Freitas WA, Botta Fo WJ, Grandini CR, Jordão JAR (1996) J Phys IV 6:123
Fast JD (1976) Gases in metals. Philips Technical Library, New York
Van Torne LI, Thomas G (1963) Acta Metall 11:881
Swartz JG (1969) Acta Metall 17:1511
Ahmad MS, Szkopiak ZC (1972) J Mat Sci 7:701
Mosher D, Dollins C, Wert C (1970) Acta Metall 18:797
Haneczok G, Weller M, Diehl J (1992) Phys Status Solidi B 172:557
Weller M, Li GY, Zhang JX, Kê TS, Diehl J (1881) Acta Metall 29:1047
Hasson DF, Arsenaut RJ (1971) Scr Mater 5:75
Szkopiak ZC (1976) Nuovo Cimento 33:293
Miura E, Ota K, Yoshimi K, Hanada S (2003) Phil Mag 83:2343
Ahmad MS, Szkopiak ZC (1970) J Phys Chem Solids 31:1799
Weller M, Haneczok G, Diehl J (1992) Phys Status Solidi B 172:145
Florêncio O, Grandini CR, Botta Fo WJ, Guedes PR, Silva Jr PS (2004) Mat Sci Eng. A 370:131
Almeida LH, Grandini CR, Machado JPB, Rodrigues Jr D (2006) submitted to Mat Sci Eng A
Cantelli R, Szkopiak ZC (1976) Appl Phys 9:153
Almeida LH, Niemeyer TC, Pires KCC, Grandini CR, Pintão CAF, Florêncio O (2004) Mat Sci Eng A 370:96
Acknowledegements
The authors wish to thank Prof. Dr. Durval Rodrigues Júnior (USP-EEL) for the samples, the Universidade Estadual de Mato Grosso do Sul (UEMS) and the Brazilian CNPq and FAPESP agencies for their financial support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
de Souza, A.C., Grandini, C.R. & Florêncio, O. Effect of heavy interstitials on anelastic properties of Nb-1.0 wt% Zr alloys. J Mater Sci 43, 1593–1598 (2008). https://doi.org/10.1007/s10853-007-2324-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-007-2324-0