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Natural ageing in magnesium alloys and alloying with Ti

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Abstract

This article reports on a remarkable natural ageing response observed for the first time in this work in Mg–Zn-based alloys. In these alloys, hardness in the naturally aged condition, generally, almost equals that in the artificially aged condition. The time to maximal hardness in the naturally aged condition can be dramatically reduced from several months needed for a binary Mg–Zn alloy, to a practical duration of a few weeks when some additional alloying elements that act as accelerants are added. Examples of such elements presented here are Cu and Ti. Strengthening in the naturally aged condition of these alloys is achieved through the formation of a very high density of Guinier-Preston (GP) zone-type precipitates. Both Cu and Ti also enhance the artificial ageing response by increasing the number density of the strengthening precipitates. Unlike Cu, Ti is not detrimental to the corrosion resistance and the current results indicate that it also has a very pronounced grain-refining effect on the Mg–Zn-based alloys.

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References

  1. Lorimer GW (1986) Magnesium technology. Institute of Metals, London, p 47

    Google Scholar 

  2. Clark JB (1965) Acta Metall 13:1281

    Article  CAS  Google Scholar 

  3. Gao X, Nie JF (2007) Scripta Mater 56:645

    Article  CAS  Google Scholar 

  4. King JF, Unsworth W (1980) US Patent 4239535

  5. Unsworth V (1987) Light Metal Age 8:10

    Google Scholar 

  6. Mima G, Tanaka Y (1971) Trans JIM 12:71

    Article  Google Scholar 

  7. Takahashi T, Kojima Y, Takahashi K (1973) Jpn J Inst Light Metals 23:376

    Article  CAS  Google Scholar 

  8. Polmear IJ (1995) Light alloys: metallurgy of the light metals, 3rd edn. Arnold, London, p 204

    Google Scholar 

  9. ASM Specialty Handbook (1998) Magnesium and magnesium alloys. ASM International, p 27

  10. Hansen M (1958) Constitution of binary alloys, 2nd edn., written in cooperation with Anderko K. McGraw-Hill Book Co., New York, p 924

  11. Wei LY, Dunlop GL, Westengen GL (1995) Metall Mater Trans A 26A:1947

    Article  CAS  Google Scholar 

  12. Kelly A, Nicholson RB (1963) Prog Mater Sci 10:151

    Article  Google Scholar 

  13. Lomer WM (1958) Inst Metals Monogr Rep Ser 23:79

    Google Scholar 

  14. Embury JD, Nicholson RB (1965) Acta Metall 13:403

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The author wishes to acknowledge the financial support of the Japanese Society for the Promotion of Science (JSPS) in the form of a JSPS Postdoctoral Fellowship.

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Correspondence to Joka Buha.

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Buha, J. Natural ageing in magnesium alloys and alloying with Ti. J Mater Sci 43, 1220–1227 (2008). https://doi.org/10.1007/s10853-007-2250-1

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  • DOI: https://doi.org/10.1007/s10853-007-2250-1

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