Characterization and dielectric properties of β-SiC nanofibres
- 603 Downloads
SiC nanofibres produced by chemical vapour reaction technique are investigated using scanning and transmission electron microscopy. The nanofibres have been found to have a crystalline core of β-SiC sheathed with thorn-like turbostratic carbon or amorphous Si/O/C, respectively. For this material, real and imaginary part of relative permittivity is measured in a frequency range of 1–18 GHz at room temperature. The results reveal that the permittivity and dielectric loss in the SiC nanofibres are a magnitude higher compared with sub-microcrystalline SiC powder. Composition and nanostructure are held responsible for the difference in dielectric properties. The mechanisms of dielectric loss in the SiC nanofibres are discussed based on interfacial polarization, lattice defects in the SiC nanofibre cores and conduction loss of turbostratic carbon in the thorn-like sheath of SiC nanofibres.
KeywordsDielectric Loss Loss Tangent Relative Permittivity Crystalline Core Permittivity Measurement
We would like to thank the Swedish Defence Nanotechnology Program for the financial support, and University Claude Bernard, Laboratoire des Multimatériaux et Interfaces (LMI) in Lyon, France, for the supply of the materials. We would also like to thank Jan Fagerström (Swedish Defence Research Agency) for helpful discussions.
- 17.Starck HC (2006) Home page: http://www.hcstarck.com. Accessed 01 Nov 2006
- 19.Kassiba A (2003) In: Legrand AP, Sénémaud Ch (eds) Nanostructured silicon-based powders and composites. Taylor & Francis Group, London and New York, p 227Google Scholar
- 20.Kingery WD, Boven HK, Uhlmann DR (1976) Introduction to ceramics. John Wiley & Sons, New York, p 921Google Scholar
- 21.Raju GG (2003) Dielectrics in electric fields. Marcel Dekker, Inc., New York, Basel. http://www.engnetbase.com. Accessed 6 Dec 2006
- 22.Kassiba A, Charpentier S (2003) In: Legrand AP, Sénémaud C (eds) Nanostructured silicon-based powders and composites. Taylor & Francis, London and New York, p 211Google Scholar
- 28.Priou A (1992) Dielectric properties of heterogeneous materials, Pier 6 progress in electromagnetics research. Elsevier, New York, p 14Google Scholar