Skip to main content
SpringerLink
Log in

Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

It was demonstrated that brookite-type titanium oxide can be directly synthesized by the hydrothermal treatment of novel water-soluble titanium complexes under basic conditions in the presence of an additive. In particular, single-phase brookite was synthesized from the titanium–glycolate complex at a pH of about 10 in the presence of excess NH3 aqueous solution or ethylenediamine, and powder thus obtained consisted of rod-like nanosized particles. It was suggested that the structures of titanium complexes are important for the formation of brookite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Kominami H, Ishi Y, Kohno M, Honishi S, Kera Y, Ohtani B (2003) Catal Lett 91(1–2):41

    Article  CAS  Google Scholar 

  2. Yin S, Fujishiro Y, Wu J, Aki M, Sato T (2003) J Mater Pro Tech 137:45

    Article  CAS  Google Scholar 

  3. Yin S, Sato T (2004) J Photochem Photobio A Chem 163:1

    Article  CAS  Google Scholar 

  4. Yamoto T, Wada Y, Yin H, Sakata T, Mori H, Yanagida S (2002) Chem Lett 31(10):96

    Google Scholar 

  5. Yin S, Li R, He Q, Sato T (2002) Mater Chem Phys 75:76

    Article  CAS  Google Scholar 

  6. Cheng H, Zhenguo JM, Qi L (1995) Chem Mater 7:663

    Article  CAS  Google Scholar 

  7. Li X, Xiong Y, Li Z, Xie Y (2006) Inorg Chem 45(9):3493

    Article  CAS  Google Scholar 

  8. Music S, Gotic M, Ivanda M, Popovic S, Turkovic A, Trojko R, Sukulic A, Furic K (1997) Mater Sci Eng B 47:33

    Article  Google Scholar 

  9. Zhang YH, Chan CK, Porter J, Guo W (1998) J Mater Res 13:2602

    Article  CAS  Google Scholar 

  10. Potter A, Chnèac C, Trone E, Mazerolles L, Jolivet J-P (2001) J Mater Chem 11:1116

    Article  Google Scholar 

  11. Ye X, Sha J, Jiao Z, Zhang L (1997) Nano Struct Mater 8(7):919

    Article  CAS  Google Scholar 

  12. Nagase T, Ebina T, Iwasaki T, Hayashi H, Onodera Y, Chatterjee M (1999) Chem Lett 28(9):911

    Article  Google Scholar 

  13. Zheng Y, Shi E, Cui S, Li W, Hu X (2000) J Am Ceram Soc 83(10):2634

    Article  CAS  Google Scholar 

  14. Zheng Y, Shi E, Cui S, Li W, Hu X (2000) J Mater Sci Lett 19:1445

    Article  Google Scholar 

  15. Mitsuhashi T, Watanabe M (1978) Mineral J 9:236

    Article  CAS  Google Scholar 

  16. Kominami H, Kohno M, Kera Y (2000) J Mater Chem 10:1151

    Article  CAS  Google Scholar 

  17. Kakihana M, Tada M, Shiro M, Petrykin V, Osada M, Nakamura Y (2001) Inorg Chem 40:891

    Article  CAS  Google Scholar 

  18. Kakihana M, Tomita K, Petrykin V, Tada M, Sasaki S, Nakamura Y (2004) Inorg Chem 43:4546

    Article  CAS  Google Scholar 

  19. Tomita K, Petrykin V, Kobayashi M, Shiro M, Yoshimura M, Kakihana M (2006) Angew Chem Int Ed 45:2378

    Article  CAS  Google Scholar 

  20. Tompsett GA, Bowmaker GA, Cooney RP, Metson JB, Rodgers KA, Seakins JM (1995) J Raman Spectrosc 26:57

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We are grateful for support by a CREST/JST grant. Part of this work was also supported by a Grant in Aid for Science Research, No. 18206069 from the Ministry of Education, Science and Culture, Japan.

Author information

Authors and Affiliations

  1. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi, 980-8577, Japan

    Makoto Kobayashi, Koji Tomita, Valery Petrykin & Masato Kakihana

  2. Department of Chemistry, School of Science, Tokai University, 1117 Kitakaname, Hiratsuka, Kanagawa, 259-1292, Japan

    Koji Tomita

  3. Materials and Structures Laboratory (Center for Materials Design), Tokyo Institute of Technology, 4529 Nagatsuta, Midori-ku, Yokohama, Kanagawa, 226-8503, Japan

    Masahiro Yoshimura

Authors
  1. Makoto Kobayashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Koji Tomita
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Valery Petrykin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Masahiro Yoshimura
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Masato Kakihana
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Masato Kakihana.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kobayashi, M., Tomita, K., Petrykin, V. et al. Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes. J Mater Sci 43, 2158–2162 (2008). https://doi.org/10.1007/s10853-007-1912-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-007-1912-3

Keywords

Search

Navigation