Abstract
The recent discovery of melt-processable poly(tetrafluoroethylene) (PTFE) allows for common thermoplastic-polymer processing technologies to be applied to this unique polymer, which heretofore was considered to be highly intractable. In this paper, we report simple melt-spinning of monofilaments of a set of melt-processable (modified) PTFE grades with weight-average molar masses (M w) ranging from 77 to 292 kg/mol. Fibers were spun at 380 °C at draw-down ratios of up to 2,750, yielding filaments of linear densities as low as 0.8 tex, corresponding to a diameter of ∼20 μm. The maximum Young’s modulus and tensile strength of as-spun fibers produced in this study were 91.7 cN/tex (1,972 MPa) and 12.0 cN/tex (258 MPa), respectively, accompanied by a strain to break of 24%.
Similar content being viewed by others
References
Scheirs J (1997) Modern fluoropolymers. John Wiley and Sons, NY
Berry KL (1951) US Patent 2,559,750
Monocrieff RW (1966) Man-made fibers. John Wiley and Sons, NY, p 512
Uno T, Miyata S, Shirai H (2002) J Appl Polym Sci 84:2366
Endo R, Kanamoto T (2001) J Polym Sci Polym Phys Ed 39:1995
Shimizu M, Ikeda C, Matsuo M (1996) Macromolecules 29:6724
Smith P, Visjager J, Bastiaansen C, Tervoort T, US Patent 6,531,559 (2003); US Patent 6,548,612 (2003); US Patent 6,737,165 (2004)
Tervoort T, Visjager J, Graf B, Smith P (2000) Macromolecules 33:6460
Goessi M, Tervoort T, Smith P, Characterization of Melt-processable Poly(tetrafluoroethylene) (to be published)
Bro MI, Sandt BW (1960) US Patent 2,946,763
Harris JF, McCane DI (1964) US Patent 3,132,123
Long SD, Ward IM (1991) J Appl Polym Sci 42:1911
Kilian HG, Jenkel E (1959) Z Elektrochem 63:308
Starkweather HW Jr, Clark ES (1962) J Appl Polym Sci 24:41
Bulters MJH, Meijer HEH (1990) J Non-Newton Fluid Mech 38:43
Crawford SM, Kolsky H (1951) Proc Phys Soc B 64:119
Grün F, Kuhn W (1942) Kolloid Z 101:248
Ward IM (1997) Structure and properties of oriented polymers, 2nd edn. John Wiley and Sons, NY, p 37
Irvine PA, Smith P (1986) Macromolecules 19:240
Heffner GW, Uy WC, Wagner MG (2001) US Patent 6,207,275
Acknowledgments
Samples were provided by Dr. F. Kloos and Dr. G. Löhr (Dyneon, Germany). The authors are grateful for stimulating discussions with Prof. Dr. Ir. H.E.H. Meijer (Eindhoven University of Technology, The Netherlands), as well as for the experimental assistance of Messrs. Marco Sigrist and Raphael Heeb (ETH Zürich).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Goessi, M., Tervoort, T. & Smith, P. Melt-spun poly(tetrafluoroethylene) fibers. J Mater Sci 42, 7983–7990 (2007). https://doi.org/10.1007/s10853-006-1266-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-1266-2