Abstract
A novel method by combining NAC-FAS (NAnometer-sized Crystal Formation in Alcoholic Solutions) method and mechanical milling treatment was successfully applied for dispersing perovskite type oxide LaMnO3 finely on carbon support. Microscopic observation revealed that nano-sized oxide particles were dispersed fairly well in the carbon support. The gas diffusion-type electrode prepared by means of reducing number and quantity of chemicals exhibited more excellent oxygen reduction activity than the electrodes containing LaMnO3 prepared by RHP (Reverse Homogeneous Precipitation) method. It allowed current density as high as 300 mA cm−2 at −80 mV (vs. Hg/HgO) in 8 M KOH at 60 °C under air flow.
Similar content being viewed by others
References
Motoo S, Watanabe M, Furuya N (1984) J Electroanal Chem 160:351
Sugawara M, Ohno M, Matsuki K (1991) Chem Lett 1465
Miura N, Horiuchi H, Shimizu Y, Yamazoe N (1987) Nippon Kagaku Kaish 1987:617
Watanabe M, Tomikawa M, Motoo S (1985) J Electroanal Chem 195:81
Aikawa H (1996) Soda & Chorine 93
Zhang HM, Teraoka Y, Yamazoe N (1987) Chem Lett 4:665
Matsuda Y, Yamashita K, Takatsu Y (1983) Denki Kagaku 51:925
King WJ, Tseung ACC (1974) Electrochem Acta 19:485
Zen JM, Goodenough JB, Manoharam R (1992) J Appl Electrochem 22:140
Shimizu Y, Uemura K, Matsuda H, Miura N, Yamazoev N (1990) J Electrochem Soc 137:3430
Hyodo T, Shimizu Y, Miura N, Yamazoe N (1994) Denki Kagaku 62:158
Hayashi M, Uemura H, Shimanoe K, Miura N, Yamazoev (1998) Electrochem Solid-State Lett 1:268
Miura N, Hayashi M, Hyodo T, Yamazoe N (1999) Mat Sci Forum 315–317:562
Hyodo T, Hayashi M, Mitsutake S, Miura N, Yamazoe N (1997) J Appl Electrochem 27:745
Hyodo T, Hayashi M, Miura N, Yamazoe N (1996) J Electrochem Soc 143:L266
Teraoka Y, Nanri S, Moriguchi I, Kagawa S, Shimanoe K, Yamazoe N (2000) Chem Lett 1202
Teraoka Y, Taura Y, Moriguchi I, Kagawa S (1995) Kagaku Kagaku Ronbunshu 21:1032
Imaizumi S, Shimanoe K, Teraoka Y, Miura N, Yamazoe N (2004) J Electrochem Soc 151:A1559
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lukaszewicz, J.P., Imaizumi, S., Yuasa, M. et al. New approach towards preparation of efficient gas diffusion-type oxygen reduction electrode. J Mater Sci 41, 6215–6220 (2006). https://doi.org/10.1007/s10853-006-0723-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-0723-2