Journal of Materials Science

, Volume 42, Issue 12, pp 4270–4275 | Cite as

Dielectric, ferroelectric and piezoelectric properties of (1 − x)[Pb0.91La0.09(Zr0.60Ti0.40)O3]–x[Pb(Mg1/3Nb2/3)O3], 0 ≤ x ≤ 1

  • Benudhar Sahoo
  • Prasanta Kumar PandaEmail author


The dielectric, ferroelectric, and piezoelectric properties of ceramic materials of compositions (1 − x)[Pb0.91La0.09(Zr0.60Ti0.40)O3]–x[Pb(Mg1/3Nb2/3)O3], x = (0, 0.2, 0.4, 0.6, 0.8, and 1.0) were studied. The above compositions were prepared by mixing the individual Pb0.91La0.09(Zr0.60Ti0.40)O3 (PLZT) and Pb(Mg1/3Nb2/3)O3 (PMN) powders in order to design materials with different combination of piezo and dielectric properties. The powders were calcined at 850 °C for 4 h. The presence of various phases in the calcined powders was characterized by X-ray diffraction (XRD) technique. The compacts were prepared by uniaxial pressing and were sintered at 1250 °C for 2 h. The sintered compacts were electroded, poled at 2 kV/mm dc voltage and their dielectric, ferroelectric, and piezoelectric properties were measured. In general, it was observed that the dielectric constant, loss factor and the slimness of the ferroelectric curves increase with the PMN content while the remnant polarization, saturation polarization, and the coercive fields were decreased. It is now possible to design materials with a wide combination of d33, K, and loss factor by varying PLZT and PMN ratio.


Piezoelectric Property Remnant Polarization Zirconium Oxychloride Saturation Polarization Niobium Pentoxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



The authors are very grateful to Dr. S. Usha Devi for XRD patterns. The authors also gratefully acknowledge Head, Materials Science Division and Director, NAL for providing necessary encouragement during the course of this study. One of the authors, Mr. B. Sahoo also thanks CSIR, New Delhi for the research fellowship.


  1. 1.
    Crawley EF, De Luis J (1987) AIAA J 25:1373CrossRefGoogle Scholar
  2. 2.
    Sugawara Y, Onitsuka K, Yoshikawa S, Xu Q, Newnham RE, Uchino K (1992) J Am Ceram Soc 75:996CrossRefGoogle Scholar
  3. 3.
    Newnham RE, Ruschau GR (1996) Am Ceram Soc Bull 75:51Google Scholar
  4. 4.
    Tressler JF, Alkoy S, Newnham RE (1998) J Electroceram 2:257CrossRefGoogle Scholar
  5. 5.
    Newnham RE (1998) In: Majumdar SK, Tressler RE, Miller EW (eds) The era of materials. The Pennsylvania Academy of Science, p. 159Google Scholar
  6. 6.
    Newnham RE, Bowen LJ, Klicker KA, Cross LE (1980) Mater Eng 2:93Google Scholar
  7. 7.
    Wallaschek J (1995) J Intell Mat Syst Struct 6:71CrossRefGoogle Scholar
  8. 8.
    Chang SH, Wang HC (1990) Sens Actuators A 24:239CrossRefGoogle Scholar
  9. 9.
    Swartz SL, Shrout TR, Schulze WA, Cross LE (1984) J Am Ceram Soc 67:311CrossRefGoogle Scholar
  10. 10.
    Nomura S, Uchino K (1982) Ferroelectrics 41:117CrossRefGoogle Scholar
  11. 11.
    Uchino K (1986) Am Ceram Soc Bull 65:647Google Scholar
  12. 12.
    Shrout TR, Halliyal A (1987) Am Ceram Soc Bull 66:704Google Scholar
  13. 13.
    Chen J, Harmer MP (1990) J Am Ceram Soc 73:68CrossRefGoogle Scholar
  14. 14.
    Koval V, Alemany C, Briancin J, Brunckova H, Saksl K (2003) J Eur Ceram Soc 23:1157CrossRefGoogle Scholar
  15. 15.
    Tsotsorin AN, Gridnev SA, Rogova SP, Luchaninov AG (1999) Ferroelectrics 235:171CrossRefGoogle Scholar
  16. 16.
    Buchanan RC (ed) (1991) Ceramic materials for electronics, processing, properties and applications, p 175 (2nd ed)Google Scholar
  17. 17.
    Ouchi H, Nagano K, Hayakawa S (1965) J Am Ceram Soc 48:T26CrossRefGoogle Scholar
  18. 18.
    Villegas M, Jurado JR, Moure C, Duran P (1995) J Mater Sci 30:1391CrossRefGoogle Scholar
  19. 19.
    Haertling GH (1999) J Am Ceram Soc 82:797CrossRefGoogle Scholar
  20. 20.
    Wang HC, Schulze WA (1990) J Am Ceram Soc 73:825CrossRefGoogle Scholar
  21. 21.
    Yimnirun R, Ananta S, Laoratanakul P (2005) J Eur Ceram Soc 25:3235CrossRefGoogle Scholar
  22. 22.
    De Mathan N, Husson E, Calvarin G, Gavarri JR, Hewat AW, Morell A (1991) J Phys Condens Matter 3:8159CrossRefGoogle Scholar
  23. 23.
    Fanning DM (2000) Structure property relations in ferroelectric materials. PhD Thesis, University of Illinois, Urbana-ChampaignGoogle Scholar
  24. 24.
    Sunder V, Newnham RE (1992) Ferroelectrics 135:431CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  1. 1.Materials Science DivisionNational Aerospace LaboratoriesBangaloreIndia

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