Abstract
Zinc oxide nanoparticles were coated with titania/polydimethylsiloxane hybrid by co-hydrolysis and co-condensation of the sols prepared from titanium tetraisopropoxide and methoxy-functionalized polydimethylsiloxane to synthesize a new class of hierarchically designed composite materials. The successful formation of the shell, which is composed of titania/polydimethylsiloxane hybrid, was evidenced by SEM, TEM, IR, EDS and zeta potential data. The hydrophobicity and the dispersibility in decamethylcyclopentasiloxane changed dramatically by the shell formation.
Similar content being viewed by others
References
Ogawa M (1998) Roy Soc Chem Annu Rep Part C 94:209
Schmidt G (2004) Nanoparticles: theory to application. Wiley-VCH, Weinheim
Caruso F (2001) Adv Mater 13:11
Davies R, Schurr GA, Meenan P, Nelson RD, Bergna HE, Brevett CAS, Goldbaum RH (1998) Adv Mater 10:1264
Caruso F, Möhwald H (1999) Langmuir 15:8276
Yoshida W, Castro RP, Jou J-D, Cohen Y (2001) langmuir 17:5882
Caruso RA, Antonietti M, (2001) Chem Mater 13:3272
Ocaña M, Hsu WP, Matijević E (1991) Langmuir 7:2911
Iwasaki T, Satoh M, Masuda T, Fujita T (2000) J Mater Sci 35:4025
Türkoğlu M, Yener S (1997) Int J Cosmet Sci 19:193
Mitchnick MA, Fairhurst D, Pinnell SR (1999) J Am Acad Dermatol 40:85
Grasset F, Saito N, Li D, Park D, Sakaguchi I, Ohashi N, Haneda H, Roisnel T, Mornet S, Duguet E (2003) J Alloys Compd 360:298
Fangli Y, Peng H, Chunlei Y, Shulan H, Jinlin L (2003) J Mater Chem 13:634
Special issue on ‘Organic–inorganic nanocomposite materials’ (2001) Chem Mater 13
Novak BM (1993) Adv Mater 5:422
Schmidt H (1994) J Non-Cryst Solids 178:302
Wen J, Wilkes GL (1996) Chem Mater 8:1667
Yamada N, Yoshinaga I, Katayama S (1997) J Mater Chem 7:1491
Nakade M, Kameyama K, Ogawa M (2004) J Mater Sci 39:4131
Wang B , Wilkes GL (1991) J Polym Sci Part A Polym Chem 29:905
Kobayashi T, Terada T, Ikeda S (1989) Shikizai 62:524 (in Japanese)
(a) Smith AL (1960) Spectrochim Acta 16:87; (b) Smith AL (1963) Spectrochim Acta 19:849; (c) Smith AL (1984) Analysis of silicones. Krieger Publishing Company, Florida
Nakade M, Ichihashi K, Ogawa M (2005) J Sol-Gel Sci Tech 36:257
Bahnemann DW, Kormann C, Hoffmann MR (1987) J Phys Chem 91:3789
Degen A, Kosec M (2000) J Eur Ceram Soc 20:667
Barringer EA, Bowen HK (1985) Langmuir 1:420
Kirby BJ, Hasselbrink Jr EF (2004) Electrophoresis 25:203
Barton AFM (1983) RC handbook of solubility parameters and other cohesion parameters. CRC Press, Boca Raton
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Nakade, M., Ogawa, M. Synthesis and characterization of zinc oxide fine particles coated with titania/PDMS hybrid. J Mater Sci 42, 4254–4259 (2007). https://doi.org/10.1007/s10853-006-0672-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-0672-9